Journal of Solution Chemistry

, Volume 9, Issue 2, pp 129–139

Triple ion formation in solutions of alkaline sulfocyanides

  • P. Bacelon
  • J. Corset
  • C. de Loze
Article

DOI: 10.1007/BF00644484

Cite this article as:
Bacelon, P., Corset, J. & de Loze, C. J Solution Chem (1980) 9: 129. doi:10.1007/BF00644484

Abstract

Through the infrared and Raman spectra of alkaline sulfocyanides in high-and low-polarity media, nitromethane (CH3NO2) and tetrahydrofuran (THF), triple cations and triple anions may be characterized. The formation of these species at the expense of ion pairs or more aggregated species such as dimers is discussed taking into account cation solvation, anion solvation, and the influence of cation-anion interaction.

Key words

Infrared-Raman studyionic association-solutiontriple ionsaprotic solventsnitromethanetetrahydrofuranalkaline and tetraalkylammonium sulfocyanides

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • P. Bacelon
    • 1
  • J. Corset
    • 1
  • C. de Loze
    • 1
  1. 1.Laboratoire de Spectrochimie Infrarouge et RamanCNRSThiaisFrance