, Volume 9, Issue 2, pp 129-139

Triple ion formation in solutions of alkaline sulfocyanides

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Through the infrared and Raman spectra of alkaline sulfocyanides in high-and low-polarity media, nitromethane (CH3NO2) and tetrahydrofuran (THF), triple cations and triple anions may be characterized. The formation of these species at the expense of ion pairs or more aggregated species such as dimers is discussed taking into account cation solvation, anion solvation, and the influence of cation-anion interaction.