, Volume 10, Issue 10, pp 1671-1677

The concept of one polymer composites modelled with high density polyethylene

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Abstract

One polymer composite materials have been prepared using a difference in melting points between the components. This depends on the fact that aligned and extended chains provide thermodynamically more stable crystals, which thus will have higher melting points than conventionally crystallized melts. The growth of transcrystalline regions in the melt matrix at the interface plus an observed partial melting between fibre and matrix are indications of a strong and intimate interfacial bond with a gradient in morphologies for the system studied, high-density polyethylene. The pull-out test is a simple and adequate method for evaluating the interfacial shear strength of one polymer composites. The value for the high-density polyethylene composite falls between the strengths for glass-reinforced polyester and epoxy resins. However, the interfacial strength in the polyethylene composites is due mainly to the unique epitaxial bonding rather than the radial forces from compressive shrinkage. The low critical aspect ratio for the filaments in these polyethylene composites suggests possible advantageous uses as short fibrereinforced materials where the interfacial strength is a controlling factor.

On leave from Universidad Nacional Del Sur, Planta Piloto de Ingenieria Quimica, Bahia Blanca, Argentina.