Rheologica Acta

, Volume 35, Issue 5, pp 433–445

Nonlinear rheological behavior of a concentrated spherical silica suspension


  • Hiroshi Watanabe
    • Institute for Chemical Research Kyoto University
  • Ming-Long Yao
    • Rheometric Scientific
  • Atsuko Yamagishi
    • Rheometric Scientific
  • Kunihiro Osaki
    • Institute for Chemical Research Kyoto University
  • Toshiyuki Shitata
    • Department of Macromolecular ScienceOsaka University
  • Hirokazu Niwa
    • Department of Macromolecular ScienceOsaka University
  • Yotaro Morishima
    • Department of Macromolecular ScienceOsaka University
Original Contribution

DOI: 10.1007/BF00368994

Cite this article as:
Watanabe, H., Yao, M., Yamagishi, A. et al. Rheola Acta (1996) 35: 433. doi:10.1007/BF00368994


Linear and nonlinear viscoelastic properties were examined for a 50 wt% suspension of spherical silica particles (with radius of 40 nm) in a viscous medium, 2.27/1 (wt/wt) ethylene glycol/glycerol mixture. The effective volume fraction of the particles evaluated from zero-shear viscosities of the suspension and medium was 0.53. At a quiescent state the particles had a liquid-like, isotropic spatial distribution in the medium. Dynamic moduli G* obtained for small oscillatory strain (in the linear viscoelastic regime) exhibited a relaxation process that reflected the equilibrium Brownian motion of those particles. In the stress relaxation experiments, the linear relaxation modulus G(t) was obtained for small step strain γ(≤0.2) while the nonlinear relaxation modulus G(t, γ) characterizing strong stress damping behavior was obtained for large γ(>0.2). G(t, γ) obeyed the time-strain separability at long time scales, and the damping function h(γ) (−G(t, γ)/G(t)) was determined. Steady flow measurements revealed shear-thinning of the steady state viscosity η(γ) for small shear rates γ(< τ −1; τ = linear viscoelastic relaxation time) and shear-thickening for larger γ (>τ−1). Corresponding changes were observed also for the viscosity growth and decay functions on start up and cessation of flow, η + (t, γ) and η (t, γ). In the shear-thinning regime, the γ and τ dependence of η+(t,γ) and η(t,γ) as well as the γ dependence of η(γ) were well described by a BKZ-type constitutive equation using the G(t) and h(γ) data. On the other hand, this equation completely failed in describing the behavior in the shear-thickening regime. These applicabilities of the BKZ equation were utilized to discuss the shearthinning and shear-thickening mechanisms in relation to shear effects on the structure (spatial distribution) and motion of the suspended particles.

Key words

SuspensionBrownian motionhydrodynamic interactionstress relaxationdamping functionshear-thinningshear-thickeningBKZ constitutive equation

Copyright information

© Steinkopff Verlag 1996