Journal of Materials Science

, Volume 28, Issue 8, pp 2129–2134

Structure of B6O boron-suboxide by Rietveld refinement

  • M. Kobayashi
  • I. Higashi
  • C. Brodhag
  • F. Thévenot
Papers

DOI: 10.1007/BF00367573

Cite this article as:
Kobayashi, M., Higashi, I., Brodhag, C. et al. Journal of Materials Science (1993) 28: 2129. doi:10.1007/BF00367573

Abstract

The structures of the B6O samples prepared by oxidizing boron with ZnO at temperatures of 1350–1500°C in an argon atmosphere have been refined by the Rietveld method. The B6O samples were found to contain an amorphous phase from their X-ray diffraction profiles in addition to B6O diffraction peaks. The results indicate that the B6O samples, space group R¯3m, no.166, ahex = 0.5367(1) nm and chex = 1.2328(2) nm in the hexagonal unit cell, have oxygen deficiencies with 0.76(6) oxygen occupancy. A radial distribution function method applied to an extracted portion of the amorphous phase, suggests that each amorphous phase has nearly similar short-range order structure to that of the α-tetragonal boron type rather than to those of any other related boron phases.

Copyright information

© Chapman & Hall 1993

Authors and Affiliations

  • M. Kobayashi
    • 1
  • I. Higashi
    • 1
  • C. Brodhag
    • 2
  • F. Thévenot
    • 2
  1. 1.The Institute of Physical and Chemical Research (RIKEN)SaitamaJapan
  2. 2.Ecole Nationale Supérieur des Mines de Saint-EtienneSaint-Etienne Cédex 2France