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Grafting of polyester onto carbon black

4. Copolymerization of epoxide with phthalic anhydride initiated by COOK groups on carbon black surface

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Summary

The grafting of polyesters by the ring-opening copolymerization of epoxides with phthalic anhydride (PhAn) was carried out at 120°C by using carbon black that contained COOK groups as the initiating site of copolymerization. The copolymerization was easily initiated by COOK groups and polyester was effectively grafted onto carbon black: the grafting ratio of polyester obtained from PhAn and glycidyl methacrylate was increased up to about 63% with the increase in conversion. The polyester-grafted carbon black gave a stable colloidal dispersion in chloroform.

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Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Niigata University, Ikarashi 2-8050, 950-21, Niigata, Japan

    Norio Tsubokawa, Akihiro Yamada & Yasuo Sone

Authors
  1. Norio Tsubokawa
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  2. Akihiro Yamada
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  3. Yasuo Sone
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Tsubokawa, N., Yamada, A. & Sone, Y. Grafting of polyester onto carbon black. Polymer Bulletin 10, 63–69 (1983). https://doi.org/10.1007/BF00263240

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  • DOI: https://doi.org/10.1007/BF00263240

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