Abstract
Three mono- or tris-hydroxylated quaternary ammonium salts bearing various polar heads were synthesized and investigated as protective agents of rhodium(0) colloidal suspensions. The influence of the hydroxylated polar head on the micellar behaviour, size and morphology of the nanospecies was studied through surface tension measurements, dynamic light scattering and TEM experiments. Finally, the obtained surfactant-stabilized nanocatalysts were compared in the hydrogenation of benzene and its derivatives under very mild conditions (1 bar of H2, 20 °C) and in neat water.
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Liu S, Xiao J (2007) J Mol Catal A 270:1–43
Sheldon RA (2008) Chem Commun 29:3352–3365
Beletskaya IP, Kustov LM (2010) Russ Chem Rev 79:441–461
Uozumi Y (2010) Synlett:1988-1989
Li CJ, Chen L (2006) Chem Soc Rev 35:68–82
Lindstrom UM (2002) Chem Rev 102:2751–2772
Li CJ, Chan TH (1997) Comprehensive organic reaction in aqueous media. Wiley, New-York
Cornils B, Hermann WA (2005) Aqueous-phase organometallic catalysis: concepts and applications, 2nd edn. Wiley-VCH Verlag GmbH & Co, KGaA, Weinheim
Joó F (2002) Acc Chem Res 35:738–745
Shaughnessy KH (2009) Chem Rev 109:643–710
Roucoux A, Schulz J, Patin H (2002) Chem Rev 102:3757–3778
Gual A, Godard C, Castillon S, Claver C (2010) Dalton Trans 39:11499–11512
Roucoux A, Philippot K (2007) In: deVries JG, Elsevier CJ (eds) The handbook of homogeneous hydrogenation, vol 1. Wiley-VCH Verlag GmbH & Co, KGaA, Weinheim, pp 217–256
Fihri A, Bouhrara M, Nekoueishahraki B, Basset J-M, Polshettiwar V (2011) Chem Soc Rev 40:5181–5203
Balanta A, Godard C, Claver C (2011) Chem Soc Rev 40:4973–4985
Polshettiwar V, Varma RS (2010) Green Chem 12:743–754
Yan N, Xiao CX, Kou Y (2010) Coord Chem Rev 254:1179–1218
Zahmakran M, Ozkar S (2011) Nanoscale 3:3462–3481
Mori K, Yamashita H (2010) Phys Chem Chem Phys 12:14420–14432
Somorjai GA, Park JY (2008) Angew Chem Int Ed 47:9212–9228
Denicourt-Nowicki A, Roucoux A (2013) In: Serp P, Philippot K (eds) Nanomaterials in catalysis. Wiley-VCH Verlag GmbH & Co, KGaA, Weinheim, pp 55–95
Schulz J, Roucoux A, Patin H (2000) Chem Eur J 6:618–624
Mevellec V, Roucoux A, Ramirez E, Philippot K, Chaudret B (2004) Adv Synth Catal 346:72–76
Denicourt-Nowicki A, Romagné M-L, Roucoux A (2008) Catal Comm 10:68–70
Nowicki A, Le Boulaire V, Roucoux A (2007) Adv Synth Catal 349:2326–2330
Mévellec V, Mattioda C, Schulz J, Rolland J-P, Roucoux A (2004) J Catal 225:1–6
Roucoux A, Schulz J, Patin H (2003) Adv Synth Catal 345:222–229
Guyonnet Bilé E, Sassine R, Denicourt-Nowicki A, Launay F, Roucoux A (2011) Dalton Trans 40:6524–6531
Hubert C, Denicourt-Nowicki A, Guegan JP, Roucoux A (2009) Dalton Trans 36:7356–7358
Omar A, Abdel-Khalek NA (1998) J Chem Eng Data 43:117–120
Nagarajan R (2001) Langmuir 18:31–38
Asai Y (2003) Chem Phys Lipids 124:103–109
Garofalakis G, Murray BS, Sarney DB (2000) J Colloid Interface Sci 229:391–398
Umpierre AP, de Jesús E, Dupont J (2011) ChemCatChem 3:1413–1418
Redel E, Krämer J, Thomann R, Janiak C (2009) J Organomet Chem 694:1069–1075
Smith HA, Stump BL (1961) J Am Chem Soc 83:2739
Fonseca GS, Silveira ET, Gelesky MA, Dupont J (2005) Adv Synth Catal 347:847–853
Matsumoto M, Inomoto Y, Kondo K (2005) J Membr Sci 246:77–81
Barthe L, Denicourt-Nowicki A, Roucoux A, Philippot K, Chaudret B, Hemati M (2009) Catal Commun 10:1235–1239
Chen C-W, Yu H, Huang M-Y, Jiang Y–Y (1995) React Polym 24:255–260
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The authors are grateful to the Région Bretagne (PhD fellowships– MAGFOCAT and PARTICAT programs) for financial supports.
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Pélisson, CH., Hubert, C., Denicourt-Nowicki, A. et al. From Hydroxyalkylammonium Salts to Protected-Rh(0) Nanoparticles for Catalysis in Water: Comparative Studies of the Polar Heads. Top Catal 56, 1220–1227 (2013). https://doi.org/10.1007/s11244-013-0088-0
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DOI: https://doi.org/10.1007/s11244-013-0088-0