Abstract
Monolithic carbons with uniform and spherical mesopores can be easily obtained by filling the pores of colloidal silica monoliths with carbon precursors followed by carbonization and silica dissolution. In this study three different phenolic resin blends: resorcinol and crotonaldehyde (MC-RC), phenol and paraformaldehyde (MC-PP), and resorcinol and furfural (MC-RF) were used as carbon precursors. Subsequent heating and carbonization of the resulting silica–phenolic resin nanocomposites followed by silica dissolution afforded monolithic carbons with spherical mesopores matching the size of the silica colloids used. Development of microporosity in these carbons was achieved by post-synthesis KOH activation. This study shows that the combination of colloidal templating with post-synthesis activation affords monolithic micro–mesoporous carbons with large specific surface area and well-developed accessible porosity for adsorption, catalysis, environmental and energy-related applications.
Similar content being viewed by others
References
Ryoo R, Joo SH, Jun S (1999) J Phys Chem B 103:7743
Ryoo R, Joo SH, Kruk M, Jaroniec M (2001) Adv Mater 13:677
Lee J, Han S, Hyeon T (2004) J Mater Chem 14:478
Yang HF, Zhao DY (2005) J Mater Chem 15:1217
Lee J, Kim J, Hyeon T (2006) Adv Mater 18:2073
Vinu A, Mori T, Ariga K (2006) Sci Tech Adv Mater 7:753
Lu AH, Schuth F (2006) Adv Mater 18:1793
Lee J, Kim J, Hyeon T (2006) Int J Nanotech 3:253
Stein A, Wang ZY, Fierke MA (2009) Adv Mater 21:265
Kyotani T (2006) Bull Chem Soc Jpn 79:1322
Liang C, Li Z, Dai S (2008) Angew Chem Int Ed 47:3696
Wan Y, Shi YF, Zhao DY (2008) Chem Mater 20:932
Liang C, Dai S (2006) J Am Chem Soc 128:5316
Wang X, Liang C, Dai S (2008) Langmuir 24:7500
Zhang FQ, Meng Y, Gu D, Yan Y, Yu CZ, Tu B, Zhao DY (2005) J Am Chem Soc 127:13508
Bock V, Emmerling A, Fricke J (1998) J Non-Cryst Solids 225:69
Horikawa T, Hayashi J, Muroyama K (2004) Carbon 42:1625
Jaroniec M, Choma J, Gorka J, Zawislak A (2008) Chem Mater 20:1069
Frackowiak E, Beguin F (2001) Carbon 39:937
Moreno-Castilla C, Maldonado-Hodar FJ (2006) Carbon 43:455
Marie J, Berthon-Fabry S, Chatenet M, Chainet E, Pirard R, Cornet N, Achard P (2007) J Appl Electrochem 31:147
Long D, Zhang J, Yang J, Hu Z, Cheng G, Liu X, Zhang R, Zhan L, Qiao W, Ling L (2008) Carbon 46:1259
Jun S, Joo SH, Ryoo R, Kruk M, Jaroniec M, Liu Z, Ohsuna T, Terasaki O (2000) J Am Chem Soc 122:10712
Zakhidov AA, Baughaman RH, Iqbal Z, Cui C, Khayrullin I, Dantas SO, Marti J, Rachenko VG (1998) Science 282:897
Stein A, Li F, Denny NR (2008) Chem Mater 20:649
Yoon SB, Chai GS, Kang SK, Yu JS, Gierszal KP, Jaroniec M (2005) J Am Chem Soc 127:4188
Johnson SA, Ollivier PJ, Mallouk TE (1999) Science 283:963
Han S, Hyeon T (1999) Carbon 37:1645
Han S, Hyeon T (1999) Chem Commun 19:1955
Gierszal KP, Yoon SB, Yu JS, Jaroniec M (2006) J Mater Chem 16:2819
Li Z, Jaroniec M (2001) J Am Chem Soc 123:9208
Li Z, Jaroniec M (2003) Chem Mater 15:1327
Li Z, Jaroniec M (2004) Anal Chem 76:5479
Gierszal KP, Jaroniec M (2006) J Am Chem Soc 128:10026
Gierszal KP, Jaroniec M (2007) J Phys Chem C 111:9742
Jaroniec M, Gorka J, Choma J, Zawislak A (2009) Carbon 47:3034
Xia K, Gao Q, Wu C, Song S, Ruan M (2007) Carbon 45:1989
Xia KS, Gao QM, Song SQ, Wu CD, Jiang JH, Hu J, Gao L (2008) Int J Hydrogen Energy 33:116
Xia KS, Gao QM, Jiang JH, Hu J (2008) Carbon 46:1718
Armandi M, Bonelli B, Karaindrou EI, Arean CO, Garrone E (2008) Catal Today 138:244
Choi M, Ryoo R (2007) J Mater Chem 17:4204
Gorka J, Zawislak A, Choma J, Jaroniec M (2008) Carbon 46:1159
Xing W, Huang CC, Zhuo SP, Yuan X, Wang GQ, Hulicova-Jurcakova D, Yan ZF, Lu GQ (2009) Carbon 47:1715
Xing W, Zhuo SP, Gao XL (2009) Mater Lett 63:1311
Yan Y, Wei J, Zhang FQ, Meng Y, Tu B, Zhao DY (2008) Microporous Mesoporous Mater 113:305
Wu D, Liang Y, Yang XQ, Zou C, Li ZH, Lv GF, Zeng XH, Fu R (2008) Langmuir 24:2967
Liu R, Shi Y, Wan Y, Meng Y, Zhang F, Gu D, Chen Z, Tu B, Zhao D (2006) J Am Chem Soc 128:11652
Deng Y, Yu T, Wan Y, Shi Y, Meng Y, Gu D, Zhang L, Huang Y, Liu C, Wu X, Zhao D (2007) J Am Chem Soc 129:1690
Lin HP, Chang-Chien CY, Tang CY, Lin CY (2006) Microporous Mesoporous Mater 93:344
Brunauer S, Emmett PH, Teller E (1938) J Am Chem Soc 60:309
Kruk M, Jaroniec M (2001) Chem Mater 13:3169
Gregg SJ, Sing KSW (1982) Adsorption, surface area and porosity, 2nd edn. Academic Press, New York
Jaroniec M, Kaneko K (1997) Langmuir 13:6589
Kruk M, Jaroniec M, Choma J (1998) Carbon 36:1447
Kruk M, Jaroniec M, Gadkaree KP (1997) J Colloid Interface Sci 192:250
Barrett EP, Joyner LG, Halenda PP (1951) J Am Chem Soc 73:373
Choma J, Jaroniec M, Kloske M (2002) Adsorption Sci Technol 20:307
Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T (1985) Pure Appl Chem 57:603
Lillo-Rodenas MA, Juan-Juan J, Cazorla-Amoros D, Linares-Solano A (2004) Carbon 42:1371
Chunlan L, Shaoping X, Yixiong G, Shuqin L, Changhou L (2005) Carbon 43:2295
Park SJ, Jung WY (2002) J Colloid Interface Sci 250:196
Matos J, Labady M, Albornoz A, Laine J, Brito JL (2005) J Mol Catal A 228:189
Teng H, Wang SC (2000) Carbon 38:817
Teng H, Wang SC (2000) Ind Eng Chem Res 39:673
Choma J, Jaroniec M, Kloske M, Zawiślak A (2008) Ochrona Srodowiska 30:3 (in Polish)
Gierszal KP, Jaroniec M, Liang C, Dai S (2007) Carbon 45:2171
Wu D, Fu R, Yu Z (2005) J Appl Polym Sci 96:1429
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Choma, J., Górka, J., Jaroniec, M. et al. Development of Microporosity in Mesoporous Carbons. Top Catal 53, 283–290 (2010). https://doi.org/10.1007/s11244-009-9407-x
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11244-009-9407-x