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Nanomaterials and Water Purification: Opportunities and Challenges

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Abstract

Advances in nanoscale science and engineering suggest that many of the current problems involving water quality could be resolved or greatly ameliorated using nanosorbents, nanocatalysts, bioactive nanoparticles, nanostructured catalytic membranes and nanoparticle enhanced filtration among other products and processes resulting from the development of nanotechnology. Innovations in the development of novel technologies to desalinate water are among the most exciting and promising. Additionally, nanotechnology-derived products that reduce the concentrations of toxic compounds to sub-ppb levels can assist in the attainment of water quality standards and health advisories. This article gives an overview of the use of nanomaterials in water purification. We highlight recent advances on the development of novel nanoscale materials and processes for treatment of surface water, groundwater and industrial wastewater contaminated by toxic metal ions, radionuclides, organic and inorganic solutes, bacteria and viruses. In addition, we discuss some challenges associated with the development of cost effective and environmentally acceptable functional nanomaterials for water purification.

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References

  • A.A. Adesina (2004) ArticleTitleIndustrial exploitation of photocatalysis progress, perspectives and prospects Catal. Surv. Asia 8 IssueID4 265–273 Occurrence Handle10.1007/s10563-004-9117-0

    Article  Google Scholar 

  • M. Aorkas D. Tsiourvas C.M. Paleos (2003) ArticleTitleFunctional dendrimeric “nanosponges” for the removal of polycyclic aromatic hydrocarbons from water Chem. Mater 15 IssueID14 2844–2847 Occurrence Handle10.1021/cm030214q

    Article  Google Scholar 

  • R. Asahi T. Morikawa T. Ohwaki K. Aoki Y. Taga (2001) ArticleTitleVisible-light photocatalysis in nitrogen-doped titanium oxides Science 293 IssueID5528 269–271 Occurrence Handle10.1126/science.1061051 Occurrence Handle11452117

    Article  PubMed  Google Scholar 

  • E. Alvarez-Ayuso A. Garcia-Sanchez X. Querol (2003) ArticleTitlePurification of metal electroplating waste waters using zeolites Water Res. 37 4855–4862 Occurrence Handle10.1016/j.watres.2003.08.009 Occurrence Handle14604631

    Article  PubMed  Google Scholar 

  • E. Bae W. Choi (2003) ArticleTitleHighly enhanced photoreductive degradation of perchlorinated compounds on dye-sensitized metal/TiO2 under visible light Environ. Sci. Technol. 37 IssueID1 147–152 Occurrence Handle10.1021/es025617q Occurrence Handle12542303

    Article  PubMed  Google Scholar 

  • L. Balogh D.R. Swanson D.A. Tomalia G.L. Hagnauer A.T. McManus (2001) ArticleTitleDendrimer-silver complexes and nanocomposites as antimicrobial agents Nano Lett. 1 IssueID1 18–21 Occurrence Handle10.1021/nl005502p

    Article  Google Scholar 

  • A. Bianco K. Kostarelos C.D. Partidos M. Prato (2005) ArticleTitleBiomedical applications of functionalized carbon nanotubes Chem. Commun. 5 571–577 Occurrence Handle10.1039/b410943k

    Article  Google Scholar 

  • E.R. Birnbaum K.C. Rau N.N. Sauer (2003) ArticleTitleSelective anion binding from water using soluble polymers Sep. Sci. Technol. 38 IssueID2 389–404 Occurrence Handle10.1081/SS-120016581

    Article  Google Scholar 

  • C.Z.S. Chen S. Cooper (2002) ArticleTitleInteractions between dendrimer biocides and bacterial membranes Biomaterials 23 IssueID16 3359–3368 Occurrence Handle10.1016/S0142-9612(02)00036-4 Occurrence Handle12099278

    Article  PubMed  Google Scholar 

  • J. Chen M. Liu L. Zhang J. Zhang L. Jin (2003) ArticleTitleApplication of nano TiO2 towards polluted water treatment combined with electro-photochemical method Water Res. 37 3815–3820 Occurrence Handle10.1016/S0043-1354(03)00332-4 Occurrence Handle12909099

    Article  PubMed  Google Scholar 

  • M.D. Chen (2004) ArticleTitleEffects of nanophase materials (<=20 nm) on biological responses J. Environ. Sci. Health A. 39 IssueID10 2691–2705

    Google Scholar 

  • X. Cheng A.T. Kan M.B. Tomson (2004) ArticleTitleNaphthalene Adsorption and Desorption from Aqueous C60 Fullerene J. Chem. Eng. Data. 49 675–683 Occurrence Handle10.1021/je030247m

    Article  Google Scholar 

  • N. Chitose S. Ueta T.A. Yamamoto (2003) ArticleTitleRadiolysis of aqueous phenol solutions with nanoparticles. 1. Phenol degradation and TOC removal in solutions containing TiO2 induced by UV, gamma-ray and electron beams Chemosphere 50 IssueID8 1007–1013 Occurrence Handle10.1016/S0045-6535(02)00642-2 Occurrence Handle12531706

    Article  PubMed  Google Scholar 

  • K.A. DeFriend M.R. Wiesner A.R. Barron (2003) ArticleTitleAlumina and aluminate ultrafiltration membranes derived from alumina nanoparticles J. Membr. Sci. 224 IssueID1–2 11–28 Occurrence Handle10.1016/S0376-7388(03)00344-2

    Article  Google Scholar 

  • V.L. Colvin (2003) ArticleTitleThe potential environmental impact of engineered nanomaterials Nature Biotechnol. 10 1166–1170 Occurrence Handle10.1038/nbt875

    Article  Google Scholar 

  • E.A. Deliyanni D.N. Bakoyannakis A.I. Zouboulis K.A. Matis (2003) ArticleTitleSorption of As(V) ions by akaganéite-type nanocrystals Chemosphere 50 IssueID1 155–163 Occurrence Handle10.1016/S0045-6535(02)00351-X Occurrence Handle12656241

    Article  PubMed  Google Scholar 

  • M.S. Diallo S. Christie P. Swaminathan J.H. Johnson SuffixJr. W.A. Goddard SuffixIII (2005) ArticleTitleDendrimer enhanced ultrafiltration. 1. recovery of Cu(II) from aqueous solutions using Gx-NH2 PAMAM dendrimers with ethylene diamine core Environ. Sci. Technol. 39 IssueID5 1366–1377 Occurrence Handle10.1021/es048961r Occurrence Handle15787379

    Article  PubMed  Google Scholar 

  • M.S. Diallo S. Christie P. Swaminathan L. Balogh X. Shi W. Um C. Papelis W.A. Goddard SuffixIII J.H. Johnson SuffixJr. (2004) ArticleTitleDendritic chelating agents 1. Cu(II) binding to ethylene diamine core poly(amidoamine) dendrimers in aqueous solutions Langmuir 20 2640–2651 Occurrence Handle10.1021/la036108k Occurrence Handle15835132

    Article  PubMed  Google Scholar 

  • Diallo M.S., 2004. Water treatment by dendrimer enhanced filtration. US Patent Pending. Unpublished.

  • I. Dror D. Baram B. Berkowitz (2005) ArticleTitleUse of nanosized catalysts for transformation of chloro-organic pollutants Environ. Sci. Technol. 39 IssueID5 1283–1290 Occurrence Handle10.1021/es0490222 Occurrence Handle15787368

    Article  PubMed  Google Scholar 

  • A. Favre-Reguillon G. Lebuzit J. Fooz A. Guy (2003) ArticleTitleSelective concentration of uranium from seawater by nanofiltration Ind. Eng. Chem. Res. 42 5900–5904 Occurrence Handle10.1021/ie030157a

    Article  Google Scholar 

  • J.M.J. Fréchet D.A. Tomalia (Eds) (2001) Dendrimers and Other Dendritic Polymers Wiley and Sons New York

    Google Scholar 

  • Freedonia Group, Inc., 2005. Nanomaterials – market size, market share, market leaders, demand forecast, sales, company profiles, market research, industry trends. Study #: 1887. URL: http://www.freedoniagroup.com/Nanomaterials.html

  • G.E. Fryxell Y. Lin S. Fiskum J.C. Birnbaum H. Wu K. Kemner S. Kelly (2005) ArticleTitleSelf-assembled monolayers on mesoporous supports Environ. Sci. Technol. 39 IssueID5 1324–1331 Occurrence Handle10.1021/es049201j Occurrence Handle15787373

    Article  PubMed  Google Scholar 

  • Fugetsu B., S. Satoh, T. Shiba, T. Mizutani, Y.B. Lin, N. Terui &. Al. 2004. Caged multiwalled carbon nanotubes as the adsorbents for affinity-based elimination of ionic dyes. Environ. Sci. Technol. 38, 6890–6896.

  • Hollman A.M. & D. Bhattacharyya, 2004. Pore assembled multilayers of charged polypeptides in microporous membranes for ion separation. Langmuir 20(13), 5418–5424.

    Google Scholar 

  • S.P. Hong A.U. Bielinska A. Mecke B. Keszler J.L. Beals X.Y. Shi L. Balogh B.G. Orr J.R. Baker M.M.B. Holl (2004) ArticleTitleInteraction of poly(amidoamine) dendrimers with supported lipid bilayers and cells: Hole formation and the relation to transport Bioconjugate Chem. 15 774–782 Occurrence Handle10.1021/bc049962b

    Article  Google Scholar 

  • G. Jia H. Wang L. Yan X. Wang R. Pei T. Yan Y. Zhao X. Guo (2005) ArticleTitleCytotoxicity of carbon nanomaterials: Single-wall nanotube, multi-wall nanotube, and fullerene Environ. Sci. Technol. 39 IssueID5 1378–1383 Occurrence Handle10.1021/es048729l Occurrence Handle15787380

    Article  PubMed  Google Scholar 

  • R. Jevprasesphant J. Penny D. Attwood N.B. McKeown A. D’Emanuele (2003) ArticleTitleEngineering of dendrimer surfaces to enhance transepithelial transport and reduce cytotoxicity Pharm. Res. 20 IssueID10 1543–1550 Occurrence Handle10.1023/A:1026166729873 Occurrence Handle14620505

    Article  PubMed  Google Scholar 

  • K. Kabra R. Chaudhary R.L. Sawhney (2004) ArticleTitleTreatment of hazardous organic and inorganic compounds through aqueous-phase photocatalysis: A review Ind. Eng. Chem. Res. 43 IssueID24 7683–7696 Occurrence Handle10.1021/ie0498551

    Article  Google Scholar 

  • S.D. Kelly K.M. Kemmer G.E. Fryxell J. Liu S.V. Mattigod K.F. Ferris (2001) ArticleTitleX-ray-absorption fine-structure spectroscopy study of the interactions between contaminant tetrahedral anions and self-assembled monolayers on mesoporous supports J. Phys. Chem. B. 105 IssueID27 6337–6346 Occurrence Handle10.1021/jp0045890

    Article  Google Scholar 

  • C. Lam J.T. James R. McCluskey R.L. Hunter (2004) ArticleTitlePulmonary toxicity of carbon nanotubes in mice 7 and 90 days after intratracheal instillation Toxicol. Sci. 77 126–134 Occurrence Handle10.1093/toxsci/kfg243 Occurrence Handle14514958

    Article  PubMed  Google Scholar 

  • N.K. Lazaridis D.N. Bakoyannakis E.A. Deliyanni (2005) ArticleTitleChromium(VI) sorptive removal from aqueous solutions by nanocrystalline akaganeite Chemosphere 58 IssueID1 65–73 Occurrence Handle10.1016/j.chemosphere.2004.09.007 Occurrence Handle15522334

    Article  PubMed  Google Scholar 

  • H.F. Lecoanet J.Y. Bottero M.R. Wiesner (2004) ArticleTitleLaboratory assessment of the mobility of nanomaterials in porous media Environ. Sci. Technol. 38 IssueID19 5164–5169 Occurrence Handle10.1021/es0352303 Occurrence Handle15506213

    Article  PubMed  Google Scholar 

  • H.F. Lecoanet M.R. Wiesner (2004) ArticleTitleVelocity effects on fullerene and oxide nanoparticle deposition in porous media Environ. Sci. Technol. 38 IssueID19 5164–5169 Occurrence Handle10.1021/es0352303 Occurrence Handle15506213

    Article  PubMed  Google Scholar 

  • Y.-H. Li J. Ding Z.K. Luan Z.C. Di Y.F. Zhu CL Xu D.H. Wu B.Q. Wei (2003) ArticleTitleCompetitive adsorption of Pb2+, Cu2+ and Cd2+ ions from aqueous solutions by multiwalled carbon nanotubes Carbon 41 IssueID14 2787–2792 Occurrence Handle10.1016/S0008-6223(03)00392-0

    Article  Google Scholar 

  • Q.L Li D.X. Yuan Q.M. Lin (2004) ArticleTitleEvaluation of multi-walled carbon nanotubes as an adsorbent for trapping volatile organic compounds from environmental samples J. Chromatogr. 1026 283–288 Occurrence Handle10.1016/j.chroma.2003.10.109

    Article  Google Scholar 

  • Y. Lin S.K. Fiskum W. Yantasee H. Wu S.V. Mattigod E. Vorpagel G.E. Fryxell K.N. Raymond J. Xu (2005) ArticleTitleIncorporation of hydroxypiridinone ligands into self-assembled monolayers on mesoporous supports for selective actinide sequestration Environ. Sci. Technol. 39 IssueID5 1332–1337 Occurrence Handle10.1021/es049169t Occurrence Handle15787374

    Article  PubMed  Google Scholar 

  • N. Malik R. Wiwattanapatapee R. Klopsch K. Lorenz H. Frey J.W. Weener E.W. Meijer W. Paulus R. Duncan (2000) ArticleTitleRelationship between structure and biocompatibility in vitro, and preliminary studies on the biodistribution of I-125-labelled polyamidoamine dendrimers in vivo J. Control. Release 65 IssueID1–2 133–148 Occurrence Handle10.1016/S0168-3659(99)00246-1 Occurrence Handle10699277

    Article  PubMed  Google Scholar 

  • C.L. Mangun Z.R Yue J. Economy S. Maloney P. Kemme D. Cropek (2001) ArticleTitleAdsorption of organic contaminants from water using tailored ACFs Carbon Chem. Mater. 13 2356–2360 Occurrence Handle10.1021/cm000880g

    Article  Google Scholar 

  • D.E. Meyer K. Wood L.G. Bachas D. Bhattacharyya (2004) ArticleTitleDegradation of chlorinated organics by membrane-immobilized nanosized metals Environ. Prog. 23 IssueID3 232–242 Occurrence Handle10.1002/ep.10031

    Article  Google Scholar 

  • M.S. Mohsen J.O. Jaber M.D. Afonso (2003) ArticleTitleDesalination of brakish water by nanofiltration and reverse osmosis Desalination 157 IssueID1 167–167 Occurrence Handle10.1016/S0011-9164(03)00397-7

    Article  Google Scholar 

  • N. Moreno X. Querol C. Ayora (2001) ArticleTitleUtilization of zeolites synthesized from coal fly ash for the purification of acid mines water Environ. Sci. Technol. 35 3526–3534 Occurrence Handle10.1021/es0002924 Occurrence Handle11563657

    Article  PubMed  Google Scholar 

  • J.T. Nurmi P.G. Tratnyek V. Sarathy D.R. Baer J.E. Amonette K. Pecher C. Wang J.C. Lineham D.W. Matson R.L. Penn M.D. Driessen (2005) ArticleTitleCharacterization and properties of metallic iron nanoparticles: spectroscopy, electrochemistry, and kinetics Environ. Sci. Technol. 39 IssueID5 1221–1230 Occurrence Handle10.1021/es049190u Occurrence Handle15787360

    Article  PubMed  Google Scholar 

  • S.O. Obare G.J. Meyer (2004) ArticleTitleNanostructured materials for environmental remediation of organic contaminants in water J. Environ. Sci. Health A. 39 IssueID10 2549–2582

    Google Scholar 

  • E. Oberdörster (2004) ArticleTitleManufactured nanomaterials (Fullerenes, C-60) induce oxidative stress in the brain of juvenile largemouth bass Environ. Health Pers. 112 IssueID10 1058–1062

    Google Scholar 

  • M.F. Ottaviani P. Favuzza M. Bigazzi N.J. Turro S. Jockusch D.A. Tomalia (2000) ArticleTitleA TEM and EPR investigation of the competitive binding of uranyl ions to starburst dendrimers and liposomes: Potential use of dendrimers as uranyl ion sponges Langmuir 16 IssueID19 7368–7372 Occurrence Handle10.1021/la000355w

    Article  Google Scholar 

  • S. Peltier E. Cotte D. Gatel L. Herremans J. Cavard (2003) ArticleTitleNanofiltration improvements of water quality in a large distribution system Water Sci. Tech.: Water Supply 3 193–200

    Google Scholar 

  • X. Peng Z. Luan J. Ding Z. Di Y. Li B. Tian (2005) ArticleTitleCeria nanoparticles supported nanotubes for the removal of arsenate from water Mater. Lett. 59 399–403 Occurrence Handle10.1016/j.matlet.2004.05.090

    Article  Google Scholar 

  • X.J. Peng Y.H. Li Z.K. Luan Z.C. Di H.Y. Wang B.H. Tian Z.P. Jia (2003) ArticleTitleAdsorption of 1,2-dichlorobenzene from water to carbon nanotubes Chem. Phys. Lett. 376 IssueID1–2 154–158 Occurrence Handle10.1016/S0009-2614(03)00960-6

    Article  Google Scholar 

  • L. Qi Z. Xu (2004) ArticleTitleLead sorption from aqueous solutions on chitosan nanoparticles Colloid. Surf. A. 251 IssueID1–3 183–190 Occurrence Handle10.1016/j.colsurfa.2004.10.010

    Article  Google Scholar 

  • S. Richardson (2003) ArticleTitleWater analysis emerging contaminants and current issues Anal. Chem. 75 IssueID12 2831–2857 Occurrence Handle10.1021/ac0301301

    Article  Google Scholar 

  • C.M. Sayes J.D. Fortner W. Guo D. Lyon A.M. Boyd K.D. Ausman Y.J. Tao B. Sitharaman L.J. Wilson J.B. Hughes J.L. West V.L. Colvin (2004) ArticleTitleThe differential cytotoxicity of water-soluble fullerenes Nano Lett. 4 IssueID10 1881–1887 Occurrence Handle10.1021/nl0489586

    Article  Google Scholar 

  • B. Schrick J.L. Blough A.D. Jones T.E. Mallouk (2002) ArticleTitleHydrodechlorination of trichloroethylene to hydrocarbons using bimetallic nickel-iron nanoparticles Chem. Mater. 14 IssueID12 5140–5147 Occurrence Handle10.1021/cm020737i

    Article  Google Scholar 

  • R.W.J. Scott O.M. Wilson R.M. Crooks (2005) ArticleTitleSynthesis, characterization, and applications of dendrimer-encapsulated nanoparticles J. Phys. Chem. B. 109 IssueID2 692–704 Occurrence Handle10.1021/jp0469665

    Article  Google Scholar 

  • W.K. Son J.H. Youk T.S. Lee W.H. Park (2004) ArticleTitlePreparation of antimicrobial ultrafine cellulose acetate fibers with silver nanoparticles Macromol. Rapid Commun. 25 IssueID18 1632–1637 Occurrence Handle10.1002/marc.200400323

    Article  Google Scholar 

  • I. Sondi B. Salopek-Sondi (2004) ArticleTitleSilver nanoparticles as antimicrobial agent: A case study on E-coli as a model for Gram-negative bacteria J. Coll. Interf. Sci. 275 IssueID1 177–182 Occurrence Handle10.1016/j.jcis.2004.02.012

    Article  Google Scholar 

  • A. Srivastava O.N. Srivastava S. Talapatra R. Vajtai P.M. Ajayan (2004) Nature Mater. 610 614

    Google Scholar 

  • B.W. Stanton J.J. Harris M.D Miller M.L. Bruening (2003) ArticleTitleUltrathin, multilayered polyelectrolyte films as nanofiltration membranes Langmuir 19 IssueID17 7038–7042 Occurrence Handle10.1021/la034603a

    Article  Google Scholar 

  • P.K. Stoimenov R.L. Klinger G.L. Marchin K.J. Klabunde (2002) ArticleTitleMetal oxide nanoparticles as bactericidal agents Langmuir 18 IssueID17 6679–6686 Occurrence Handle10.1021/la0202374

    Article  Google Scholar 

  • W. Tungittiplakorn L.W. Lion C. Cohen J.Y. Kim (2004) ArticleTitleEngineered polymeric nanoparticles for soil remediation Environ. Sci. Technol. 38 IssueID5 1605–1610 Occurrence Handle10.1021/es0348997 Occurrence Handle15046367

    Article  PubMed  Google Scholar 

  • W. Tungittiplakorn C. Cohen L.W. Lion (2005) ArticleTitleEngineered polymeric nanoparticles for bioremediation of hydrophobic contaminants Environ. Sci. Technol. 39 IssueID5 1354–1358 Occurrence Handle10.1021/es049031a Occurrence Handle15787377

    Article  PubMed  Google Scholar 

  • B. Vander Bruggen L. Lejon C. Vandecasteele (2003) ArticleTitleReuse, treatment, and discharge of the concentrate of pressure-driven membrane processes Environ. Sci. Technol. 37 IssueID17 3733–3738 Occurrence Handle10.1021/es0201754 Occurrence Handle12967090

    Article  PubMed  Google Scholar 

  • B. Bruggen ParticleVander C. Vandecasteele (2003) ArticleTitleRemoval of pollutants from surface water and groundwater by nanofiltration overview of possible applications in the drinking water industry Environ. Pollut. 122 435–445 Occurrence Handle10.1016/S0269-7491(02)00308-1 Occurrence Handle12547533

    Article  PubMed  Google Scholar 

  • US Bureau of Reclamation and Sandia National Laboratories, 2003. Desalination and water purification technology roadmap—a report of the executive committee. Water Purification Research and Development Program Report No 95, US Department of Interior, Bureau of Reclamation, January 2003.

  • US Environmental Protection Agency, 1998a. Variance technology findings for contaminants regulated before 1996. EPA Office of Water Report 815-R-98-003

  • InstitutionalAuthorNameUS Environmental Protection Agency (1998b) ArticleTitleMicrobial and disinfection by-product rules Federal Register 63 IssueID241 69389–69476

    Google Scholar 

  • US Environmental Protection Agency, 1999. Alternative disinfectants and oxidants guidance manual. EPA Office of Water Report 815-R-99-014

  • US Environmental Protection Agency, 2004. Water security research and technical support action plan. EPA Office Research and Development and Office of Water Report EPA/600/R-04/063

  • W.J. Weber SuffixJr. (2002) ArticleTitleDistributed optimal technology networks: A concept and strategy for potable water sustainability Water Sci. Technol. 46 IssueID6–7 241–246

    Google Scholar 

  • W. Yantasee Y. Lin G.E. Fryxell B.J. Busche J.C. Birnbaum (2003) ArticleTitleRemoval of heavy metals from aqueous solution using novel nanoengineered sorbents: Self-assembled carbamoylphosphonic acids on mesoporous silica Separ. Sci. Technol. 38 IssueID15 3809–3825 Occurrence Handle10.1081/SS-120024232

    Article  Google Scholar 

  • W.-X. Zhang (2003) ArticleTitleNanoscale iron particles for environmental remediation J. Nanopart. Res. 5 323–332 Occurrence Handle10.1023/A:1025520116015

    Article  Google Scholar 

  • L.J. Zeman A.L. Zydney (1996) Microfiltration and Ultrafiltration Marcel Dekker New York

    Google Scholar 

  • Zhao H.T. & K.L. Nagy, 2004. Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water. J. Coll. Interf. Sci. 274(2), 613–624.

    Google Scholar 

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Savage, N., Diallo, M.S. Nanomaterials and Water Purification: Opportunities and Challenges. J Nanopart Res 7, 331–342 (2005). https://doi.org/10.1007/s11051-005-7523-5

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