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Ternary mixture MTBE+1-pentanol+nonane at 298.15 K and atmospheric pressure

Measurements and analysis of densities and excess molar volumes

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Abstract

Densities at 298.15 K and atmospheric pressure have been measured, using a DMA 4500 Anton Paar densimeter, for the ternary mixture methyl tert-butyl ether (MTBE)+1-pentanol+nonane and for the involved binary mixture 1-pentanol+nonane. In addition, excess molar volumes were determined from the densities of the pure liquids and mixtures. Suitable fitting equations have been used in order to correlate adequately the excess molar volumes.

Experimental data were also used to test several empirical expressions for estimating ternary properties from experimental binary results.

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Authors and Affiliations

  1. Departamento de Física Aplicada, Facultad de Física, Campus Universitario Sur, Universidade de Santiago de Compostela, 15782, Santiago de Compostela, Spain

    P. V. Verdes, M. M. Mato & M. I. Paz Andrade

  2. Departamento de Física Aplicada, Facultad de Ciencias, Universidade de Vigo, 36200, Vigo, Spain

    M. M. Mato & J. L. Legido

Authors
  1. P. V. Verdes
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  2. M. M. Mato
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  3. J. L. Legido
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  4. M. I. Paz Andrade
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Correspondence to M. I. Paz Andrade.

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Verdes, P.V., Mato, M.M., Legido, J.L. et al. Ternary mixture MTBE+1-pentanol+nonane at 298.15 K and atmospheric pressure. J Therm Anal Calorim 92, 179–183 (2008). https://doi.org/10.1007/s10973-007-8759-3

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  • DOI: https://doi.org/10.1007/s10973-007-8759-3

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