Abstract
Copper–alkali ion exchange technology was used to prepare BK7 glass planar waveguides. The photoluminescence spectra of the waveguides were studied with fluorescence spectrophotometer. It was observed that there were strong emission peaks at around 520 nm, which were strongly influenced by the ion-exchange times. Besides the time, the ion-exchange temperature was important factor as well, the higher ion-exchange temperature was found to bring a blue shift of emission spectra. The blue–green emission band originates from different transition mechanism of energy level. The spectroscopy features of copper within the glass host were also affected by the excitation wavelength, which resulted in a shift of the emission band peaks.
Similar content being viewed by others
References
Ramaswamy RV, Srivastava R (1988) IEEE J Lightwave Technol 6:984
Martin M, Videau JJ, Canioni L, Adameitz F, Sarger L, Leflem G (2000) Appl Opt 39:435
Yoko T, Nishiwaki T, Kamiya K, Sakka SJ (1991) J Am Ceram Soc 74:1104
Márquez H, Salazar D, Villalobos A, Paez G, Rincón JM (1995) Appl Opt 34:5817
D’Acapito F, Colonna S, Mobilio S, Gonella F, Cattaruzza E, Mazzoldi P (1997) Appl Phys Lett 71:2611
Bogomolova LD, Fedorov AG, Kubrinskaya ME, Lazukin VN, Pavlushkina TK, Serpov PV (1985) J Non-Cryst Solids 72:109
Gonella F, Quaranta A, Padovni S, Sada C, D’acapito F, Maurizio C, Battaglin G, Cattaruzza E (2005) Appl Phys A 81:1065
Spirkova J, Tresnakova P, Malichova H, Mika M (2007) J Phys Chem Solids 68:1276
Pedrini C, Jaquier B (1980) J Phys C Solid State Phys 13:4791
Sakka S, Kamiya K, Kato K (1982) J Non-Cryst Solids 52:77
Erwin SC, Lin CC (1989) Phys Rev B 40:1892
Borsella E, Dal Vecchio A, Garcia MA, Sada C, Gonella F, Polloni R, Quaranta A, Van Wilderen LJGW (2002) J Appl Phys 91:90
White JM, Heidrich PF (1976) Appl Opt 15:151
Gonella F, Caccavale F, Bogomolova LD, D’Acapito F, Quaranta A (1998) J Appl Phys 83:1200
Inman JM, Houde-Walter SN, McIntyre BL, Liao ZM, Parker RS, Simmons V (1996) J Non-Cryst Solids 194:85
Dong Y, Gao YJ, Zhang LT, Jia LH, Zheng J (2008) J Optoelectron Laser 19:443
Miliou AN, Srivastava R, Ramaswamy RV (1991) Appl Opt 30:674
Tessman JR, Kahn AH, Shockley W (1953) Phys Rev 92:890
Brandenburg A (1986) J Lightwave Technol 4:1580
Debnath R, Das SK (1989) Chem Phys Lett 155:52
Pedrini C (1978) Phys Status Solidi B 87:273
Annapurna K, Kumar A, Dwivedi RN, Sooraj Hussain N, Buddhudu S (2000) Mater Lett 45:23
Oliver A, Cheang-Wong JC, Roiz J, Hernández JM, Rodriguez-Fernández L, Crespo A (2001) Nucl Instr Methods Phys Res B 175–177:495
Berg JM, Chien RL, McClure DS (1987) J Chem Phys 87:7
Tanaka K, Yano T, Shibata S, Yamane M, Inoue S (1994) J Non-Cryst Solids 178:9
Fujimoto Y, Nakatsuta M (1977) J Lumin 75:213
Klonkowski A, Gryczynski I (1981) J Non-Cryst Solids 44:415
Duffy JA, Ingram MD (1976) J Non-Cryst Solids 21:373
Debnath R (1989) J Lumin 43:375
Auzel F, Pelle F (1996) J Lumin 69:249
Cable M, Xiang ZD (1992) Phys Chem Glasses 33:154
Vij DR (1998) Luminescence of solids. Plenum Press, New York
Acknowledgements
The research project has been supported by National Natural Science Foundation of China (No. 60577008, 60777038), China–Ireland Science and Technology Collaboration Research Fund and International cooperation project (No. 20070708-3) of Jilin Provincial Science & Technology Department of China.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ti, Y., Qiu, F., Cao, Y. et al. Photoluminescence of copper ion exchange BK7 glass planar waveguides. J Mater Sci 43, 7073–7078 (2008). https://doi.org/10.1007/s10853-008-3057-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-008-3057-4