Abstract
Presence of pesticide residues was studied in rain water during 2002 employing multi residue analysis method by gas liquid chromatography equipped with ECD and NPD detectors and capillary columns. The presence of pesticide residues in surface aquatic system triggered the investigation of the presence of pesticides in rain water. A total of 13 pesticides were detected in rain water samples. Among the different groups of pesticides, organochlorines were present in the range of 0.041–7.060 ppb with maximum concentration of p,p’-DDT up to 7.060 μg l−1. Synthetic pyrethroids were present ranging from 0.100 to 1.000 μg l−1 and organophosphates in the range of 0.050–4.000 μg l−1 showing maximum contamination with cypermethrin (1.000 μg l−1) and monocrotophos (4.000 μg l−1) of the respective groups. Almost 80% samples showed the residues above MRL of 0.5 ppb fixed for multi residues and on the basis of single pesticide, 16–50% samples contained residues above the MRL value of 0.1 ppb.
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Agnihotri, N. P., Gajbhiye, V. T., Kumar, M., & Mohapatra, S. P. (1994). Organochlorine insecticide residues in Ganga river water near Farrukhabad, India. Environmental Monitoring and Assessment, 30, 105–112.
Barbesh, J. E., & Resek, E. A. (1996). Pesticides in groundwater. Volume 2 of the series pesticides in hydrologic environment (p. 425). Chelsea, MI.: Ann Arbor.
Bevenue, A.,Ogata, J. N., & Hylin, J. W. (1972). Organochlorine pesticides in rain water, Oahu,1971–72. Bulletin of Environmental Contamination and Toxicology, 8(4), 238–241.
Charizopoulos, E., & Mourkidou, E. P. (1998). The occurrence of pesticides in rain water of Axios river basin. In Abstract Book, 9th international congress: Pesticide chemistry the food environment challenge held at London. Abs: 6E–022.
Dua, V. K., Pant, C. S., & Sharma, V. P. (1994). HCH residues in rain water from Hardwar, India. Bulletin of Environmental Contamination and Toxicology, 52(6), 797–801.
Fatokio, S., & Awofolu, O. R. (2004). Levels of organochlorine pesticide residues in marine-, surface-, ground- and drinking waters from the Eastern Cape Province of South Africa. Journal of Environmental Science and Health. Part B. Pesticides, Food Contaminants, and Agricultural Wastes, 39(1), 101–114.
Govt. of India Notification-GSR No. 759E and 760E dated 29.9.02, Ministry of Health and Family Welfare.
Gustafson, D. I. (1993). Pesticides in drinking water (p. 4). New York: Van Nostrand Reinhold.
Hernandez, L. M., Fernandez, M. A., & Gonzalez, M. J. (1992). Organochlorine pollutants in water,soils and earthworms in Guadalquivir River, Spain. Bulletin of Environmental Contamination and Toxicology, 49, 192–198.
Knedel, W., Chiquin, J. C., Perez, J., & Rosales, S. (1997). Determination of organochlorine, organophosphorous and pyrethroid pesticides in surface and ground water used for human consumption in Guatemala, FAO/IAEA/SIDA Coordinated Research Programme: Agroecological effects resulting from use of persistent pesticides in Central America. Final Report, 47p.
Knedel, W., Chiquin, J. C., Perez, J., & Rosales, S. (1998). Determination of pesticides in surface and ground water used for human consumption in Guatemala. In IAEA. TECDOC-1116, Use of nuclear related techniques in studies of Agroecological effects resulting from use of persistent pesticides in Central America. Final Report. pp. 41–49.
Kreuger, J. (1998). Pesticides in stream water with in an agricultural catchment in Southern Sweden, 1990–96. Science of the Total Environment, 216, 227–251.
Kuivila, K. M. (1993). Diazinon concentration in the Sacramento and San Joaquin rivers and San Francisco Bay,California,U.S, Geological Survey open-file report. pp. 93–440.
Lenarden, Am., De Hevia, M. I. M., Fuse, J. A., De Nochelto, C. B., & Depetris, P. J. (1984). Organochlorine and organophosphorous pesticides in Parana River (Argentina). Science of the Total Environment, 34, 289–297.
Mohapatra, S. P., Gajbhiye, V. T., Agnihotri, N. P., & Raina, M. (1995). Insecticide pollution of Indian rivers. The Environmentali, 15, 41–44.
Pearce, P. A., Reynolds, L. M., & Peakall, D. B. (1978). DDT residues in rain water in New Brunswick and estimate of aerial transport of DDT in to Gulf of St. Lawrence, 1967–68. Pesticides Monitoring Journal, 11(4), 199–204.
Sakai, M. (2002). Determination of pesticides and chronic test with Daphnia magna for rain water samples. Journal of Environmental Science and Health. Part B. Pesticides, Food Contaminants, and Agricultural Wastes, 37(3), 247–254.
Wheatlay, G. A., & Hardmen, J. A. (1965). Indications of the presence of organochlorine insecticides in rain water in Central England. Nature, 207, 486–487.
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Kumari, B., Madan, V.K. & Kathpal, T.S. Pesticide residues in rain water from Hisar, India. Environ Monit Assess 133, 467–471 (2007). https://doi.org/10.1007/s10661-006-9601-2
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DOI: https://doi.org/10.1007/s10661-006-9601-2