Abstract
Ag/polyamidoamine (PAMAM) nanocomposites were produced by photoreduction of relevant metallic salts in different generations of PAMAM (PAMAMs) methanol solutions under room temperature and ambient pressure. The obtained Ag nanoparticles were quite uniform in size with a diameter of about 15 nm. Thermogravimetric analysis (TGA) results showed that the amount of Ag nanoparticles could well affect the thermal stability of PAMAMs. As the mass ratio of Ag nanoparticles to PAMAMs increased, the weight-losing ratios decreased. Meanwhile, TGA curves also indicated that the thermal behavior of Ag/PAMAMs was greatly different in the two stages of low (130~280 °C) and high temperature (280~450 °C) range; the loading of Ag nanoparticles mainly influences the thermal stability of PAMAMs in high temperature region (280~450 °C). Moreover, the multistage decomposition profile of derivative thermal gravimetry curves suggested that there might contain some intermediate Ag/PAMAMs type of composites.
References
Nicolais L, Carotenuto G (2005) Metal-Polymer Nanocomposites. Wiley InterScience, New York, pp 1–2, Ch.1
Nicolais L, Carotenuto G (2005) Metal-Polymer Nanocomposites. Wiley Interscience, New York, pp 37–71, Ch.2
Verne E, Di Nunzio S et al (2005) Surface characterization of silver-doped bioactive glass. BiomateriaIs 26(25):5111–5119
Shanmugam S, Viswanathan B, Varadarajan TK (2006) A novel single step chemical route for noble metal nanoparticles embedded organic-inorganic composite films. Mat Chem Phys 95(1):51–55
Nalwa HS (2002) Nanostructured Materials and Nanotechnology. Academic, California, pp 40–66, Ch.1
Raveendran P, Goyal A (2006) Stabilization and growth of silver nanocrystals in dendritic polyol dispersions. Mat Lett 60:897–900
Sun YY, Wang D (2007) Synthesis of silver (nano)particle under hyperbranched poly(amido amine) s. J Appl Polym Sci 103:3701–3705
Nicolais L, Carotenuto G (2005) Metal-Polymer Nanocomposites. Wiley InterScience, New York, Ch.1, 2–24, Ch.4, 139–149
Wang LM, Chen DJ (2004) “One-pot” fabrication of Ag/PMMA "shell/core" nanocomposites by chemical reduction method. Chem Lett 8:1010–1011
Lei ZL, Fan YH (2006) Preparation of silver nanocomposites stabilized by an amphiphilic block copolymer under ultrasonic irradiation. Mat Lett 60:2256–2260
Zhou Y, Yu SH et al (1999) A novel ultraviolet irradiation photoreduction technique for the preparation of single-crystal Ag nanorods and Ag dendrites. Adv Mater 11(10):850–853
Son WK, Youk JH, Park WH (2006) Antimicrobial cellulose acetate nanofibers containing silver nanoparticles. Carbohydrate Polym 65:430–434
Naylor AM, Goddard WA, Kiefer GE, Tomalia DA (1989) Starburst dendrimers. 5. Molecular shape control. J Am Chem Soc 111(6):2339–2341
Jensen AW, Maru BS, Zhang X (2005) Preparation of fullerene-shell dendrimer-core nanoconjugates. Nano Lett 5:1171–1173
Zhao MQ, Crooks RM, Sun L (1998) Preparation of Cu nanoclusters within dendrimer templates. J Am Chem Soc 120(19):4877–4878
Ottaviani MF, Valluzzi R, Balogh L (2002) Internal structure of silver-poly(amidoamine) dendrimer complexes and nanocomposites. Macromolecules 35:5105–5115
Hideo T, Zhao MQ et al (1998) Preparation and characterization of dendrimer monolayers and dendrimer–alkanethiol mixed monolayers adsorbed to gold. J Am Chem Soc 120(18):4492–4501
Tomalia DAB, Dewald J, Hall M et al (1985) New class of polymers: starburst-dendritic macromolecules. Polym J 17:117–132
Singh N, Khanna PK (2007) In situ synthesis of silver nano-particles in polymethylmethacrylate. Mater Chem Phys 104:367–372
Acknowledgment
This program is financially supported by Natural Science Foundation of Hebei Province (E200800440).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Peng, Z., Zhang, J., Sun, X. et al. The thermolysis behavior of Ag/PAMAMs nanocomposites. Colloid Polym Sci 287, 609–614 (2009). https://doi.org/10.1007/s00396-009-2015-2
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-009-2015-2