Skip to main content
SpringerLink
Log in

Copper diffusion in ion-exchanged soda-lime glass

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

Cu-alkali ion exchange in silicate glasses gives rise to a peculiar copper distribution, with the presence of both the Cu2+ and Cu+ oxidation states. Grazing incidence X-ray absorption near-edge structure spectroscopy and secondary ion mass spectrometry were performed on different ion-exchanged samples. The results show that the Cu2+/Cu+ ratio is strongly depth-dependent. The relative presence of the two species throughout the exchanged region turns out to be governed by their different diffusion regimes, while the chemistry of the red-ox process is shown to play a minor role. A phenomenological model is proposed to describe the diffusion process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R.V. Ramaswamy, R. Srivastava: IEEE J. Lightwave Technol. 6, 984 (1988) and references therein

    Article  ADS  Google Scholar 

  2. R. Debnath: J. Lumin. 43, 375 (1989)

    Article  Google Scholar 

  3. E. Borsella, A. Dal Vecchio, M.A. Garcia, C. Sada, F. Gonella, R. Polloni, A. Quaranta, L.J.G.W. Van Wilderen: J. Appl. Phys. 91, 1 (2002)

    Article  Google Scholar 

  4. F. Gonella, P. Mazzoldi: Handbook of Nanostructured Materials and Nanotechnology, Vol. 4 (Academic Press, S. Diego, h.s. nalwa edition 2000)

  5. U. Kreibig, M. Vollmer: Optical Properties of Metal Clusters, Vol. 25 of Springer Series in Materials Science (Springer, Berlin 1995)

  6. E. Cattaruzza, G. Battaglin, F. Gonella, R. Polloni, C. Mattei, G. Maurizio, P. Mazzoldi, C. Sada, M. Montagna, C. Tosello, M. Ferrari: Philos. Mag. B, 82, 735 (2002)

    Article  ADS  Google Scholar 

  7. P. Mazzoldi, G.W. Arnold, G. Battaglin, F. Gonella, R.F. Haglund Jr.: J. Nonlin. Opt. Phys. Mater. 5, 285 (1996)

    Article  ADS  Google Scholar 

  8. S. Gevorgyan: Electron. Eng. (U.K.) 26, 38 (1990)

    Google Scholar 

  9. T. Yoko, T. Nishiwaki, K. Kamiya, S. Sakka: J. Am. Ceram. Soc. 74, 1104 (1991)

    Article  Google Scholar 

  10. H. Marquez, D. Salazar, A. Villalobos, G. Paez, J.Ma. Rincon: Appl. Opt. 34, 5817 (1995)

    Article  ADS  Google Scholar 

  11. F. Gonella, F. Caccavale, L.D. Bogomolova, F. D’Acapito, A. Quaranta: J. Appl. Phys. 83, 1200 (1998)

    Article  ADS  Google Scholar 

  12. S. Sakka, K. Kamiya, K. Kato: J. Non-Cryst. Solids 52, 77 (1982)

    Article  ADS  Google Scholar 

  13. I. Davoli, H.N. Thanh, F. D’Acapito: AIP Conference Proceedings, Vol. 652 (2003) p. 388

  14. S. Pascarelli, F. Boscherini, F. D’Acapito, J. Hrdy, C. Meneghini, S. Mobilio: J. Synchr. Rad. 3, 147 (1996)

    Article  Google Scholar 

  15. F. D’Acapito, I. Davoli, P. Ghigna, S. Mobilio: J. Synchr. Rad. 10, 260 (2003)

    Article  Google Scholar 

  16. F. D’Acapito, S. Mobilio, J. Regnard, E. Cattaruzza, F. Gonella, P. Mazzoldi: J. Non-Cryst. Solids 232–234, 364 (1998)

  17. B.L. Henke, E.M. Gullison, J.C. Davis: X-ray interaction: photoabsorption, scattering, transmission, and reflection at E=50–30000 eV, Z=1-92, Vol. 54 of Atomic Data and Nuclear Data Tables (1993)

  18. A.L. Ankudinov, B. Ravel, J.J. Rehr, S.D. Conradson: Phys. Rev. B 58, 7565 (1998)

    Article  ADS  Google Scholar 

  19. F. Gonella: Appl. Phys. Lett. 69, 314 (1996)

    Article  ADS  Google Scholar 

  20. F. Gonella, F. Caccavale, A. Quaranta, A. Sambo: J. Mod. Opt. 45, 837 (1998)

    Article  ADS  Google Scholar 

  21. F. D’Acapito, S. Colonna, S. Mobilio, F. Gonella, E. Cattaruzza, P. Mazzoldi: Appl. Phys. Lett. 71, 261 (1997)

    Article  Google Scholar 

  22. J. Lee, T. Yano, S. Shibata, A. Nukui, M. Yamane: J. Non-Cryst. Solids 277, 155 (2000)

    Article  ADS  Google Scholar 

  23. C. Maurizio, F. D’Acapito, M. Benfatto, S. Mobilio, E. Cattaruzza, F. Gonella: Eur. Phys. J. B 14, 211 (2000)

    Article  ADS  Google Scholar 

  24. G.N. Greaves, A. Fontaine, P. Lagarde, D. Raoux, S.J. Gurman: Nature 293, 611 (1981)

    Article  ADS  Google Scholar 

  25. G.N. Greaves, S.J. Gurman, C.R. Catlows, A.V. Chadwick, S.N. Houde-Walter, C.M.B. Henderson, B.R. Dobson: Philos. Mag. A 64, 1059 (1991)

    Article  ADS  Google Scholar 

  26. F. D’Acapito, F. Gonella, E. Cattaruzza, S. Pascarelli, P. Mazzoldi, S. Mobilio: Nucl. Instrum. Methods Phys. Res., Sect. B 120, 110 (1996)

    Article  ADS  Google Scholar 

  27. G. Schulze: Angew. Phys. 40, 335 (1913)

    Article  ADS  Google Scholar 

  28. R.H. Doremus: Modern Aspects of the Vitreous State, Vol. 4 (butterworth and co. ltd. edition, London 1962)

  29. A. Quaranta, F. Gonella: J. Non-Cryst. Solids 192–193, 334 (1995)

  30. R.H. Doremus: J. Phys. Chem. 68, 2212 (1964)

    Article  Google Scholar 

  31. N.P. Bansal, R.H. Doremus: Handbook of glass properties (Academic Press, London 1986)

  32. M. Tomozawa: J. Non-Cryst. Solids 152, 59 (1993)

    Article  ADS  Google Scholar 

  33. G. N. Greaves, K. L. Ngai: J. Non-Cryst. Solids 172, 1378 (1994)

    Article  ADS  Google Scholar 

  34. G. N. Greaves, K. L. Nagai: Phys. Rev. B 52, 6358 (1995)

    Article  ADS  Google Scholar 

  35. P. Mazzoldi, A. Miotello: J. Non-Cryst. Solids 94, 897 (1987)

    Article  ADS  Google Scholar 

  36. J.L. Barton, M. De Billy: J. Nonlin. Opt. Phys. Mater. 38–39, 523 (1980)

  37. J.A. Duffy: J. Non-Cryst. Solids 196, 45 (1996)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. INFM, Dip. di Chimica Fisica, Università Ca’ Foscari di Venezia, Dorsoduro 2137, 30123, Venezia, Italy

    F. Gonella, G. Battaglin & E. Cattaruzza

  2. INFM, Dipartimento di Ingegneria dei Materiali, Università di Trento, via Mesiano 77, 38050, Povo, Trento, Italy

    A. Quaranta

  3. INFM-MATIS, Dipartimento di Fisica, Università di Padova, via Marzolo 8, 35131, Padova, Italy

    S. Padovani & C. Sada

  4. INFM, ESRF, GILDA-CRG, B.P. 220, 38043, Grenoble, France

    F. D’Acapito & C. Maurizio

Authors
  1. F. Gonella
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Quaranta
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Padovani
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. C. Sada
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. F. D’Acapito
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. C. Maurizio
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. G. Battaglin
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. E. Cattaruzza
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to F. Gonella.

Additional information

PACS

61.10.Ht; 61.43.Fs; 82.65.+r; 67.80.Mg

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gonella, F., Quaranta, A., Padovani, S. et al. Copper diffusion in ion-exchanged soda-lime glass. Appl. Phys. A 81, 1065–1071 (2005). https://doi.org/10.1007/s00339-004-2949-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-004-2949-7

Keywords

Search

Navigation