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The aurophilicity phenomenon: A decade of experimental findings, theoretical concepts and emerging applications

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Abstract

The term ‘aurophilicity’ was introduced in 1989 to describe phenomena in the structural chemistry of gold which could not be readily rationalized by conventional concepts of chemical bonding. In the following decade the aurophilicity concept has been widely applied and supported by the results of many experimental as well as theoretical studies. It will be carried over into the new millennium as a continued incentive for investigations that will help in the understanding of the unique properties of gold.

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References

  1. R. J. Puddephatt, ‘The Chemistry of Gold’, Elsevier, Amsterdam, 1978

    Google Scholar 

  2. H. Schmidbaur (ed.) ‘Gold: Progress in Chemistry, Biochemistry and Technology’, J. Wiley & Sons, Chichester, 1999

    Google Scholar 

  3. W. S. Rapson and T. Groenewald, ‘Gold Usage’, Academic Press, London, 1978

    Google Scholar 

  4. P. G. Jones,Gold Bull., 1981,14, 102 and 159; 1983,16, 114; 1986,19, 46

    CAS  Google Scholar 

  5. (a) H. Schmidbaur,Gold Bull., 1990,23, 11; (b) H. Schmidbaur,Chem. Soc. Rev., 1995,24, 391

    Article  CAS  Google Scholar 

  6. (a) P. Pyykkö and J. P. Desclaux,Accounts Chem. Res., 1979,12, 276; (b) R. G. Pearson, in ‘Bioinorganic Chemistry of Gold Coordination Compounds’ (B. M. Sutton, R. G. Franz, eds. ), Smith Kline French Laboratory, 1983, p. 156

    Article  Google Scholar 

  7. A. Bayler, A. Schier and H. Schmidbaur,J. Am. Chem. Soc., 1996,118, 7006

    Article  CAS  Google Scholar 

  8. H. Schmidbaur and K. C. Dash,Adv. Inorg. Chem. Radiochem., 1982,25, 239

    Article  CAS  Google Scholar 

  9. H. Schmidbaur, W. Graf and G. Müller,Angew. Chem. Int. Ed. Engl., 1988,27, 417

    Article  Google Scholar 

  10. (a) F. Scherbaum, A. Grohmann, B. Huber, C. Krüger and H. Schmidbaur,Angew. Chem. Int. Ed. Engl., 1988,27, 1544; (b) F. Scherbaum, A. Grohmann, G. Müller and H. Schmidbaur,ibid., 1989,28, 463; (c) H. Schmidbaur, F. Scherbaum, B. Hubert and G. Müller,ibid., 1988,27, 419

    Article  Google Scholar 

  11. W. S. Rapson,Gold Bull., 1989,22, 19

    Article  Google Scholar 

  12. A. Bayler, A. Bauer and H. Schmidbaur,Chem. Ber., 1997,130, 115

    Article  CAS  Google Scholar 

  13. H. Schmidbaur, S. Hofreiter and M. Paul,Nature, 1995,377, 503

    Article  CAS  Google Scholar 

  14. (a) A. N. Nesmeyanov, E. G. Perevalova, Y. T. Struchkov, M. Y. Antipin, K. I. Grandberg and V. P. Dyadchenko,J. Organomet. Chem., 1980,201, 343; (b) K. Angermaier and H. Schmidbaur,Inorg. Chem., 1994,33, 2069; (c) K. Angermaier, and H. Schmidbaur,Z. Naturforsch., 1996,51b, 879; (d) F. Canales, M. C. Gimeno, P. G. Jones and A. Laguna,Angew. Chem. Int. Ed. Engl., 1994,33, 769

    Article  CAS  Google Scholar 

  15. (a) A. Grohmann, J. Riede and H. Schmidbaur,Nature, 1990,345, 140; (b) A. Schier, A. Grohmann, J. M. Lopez-de-Luzuriaga and H. Schmidbaur,Inorg. Chem., 2000,39, 547

    Article  CAS  Google Scholar 

  16. (a) E. Zeller and H. Schmidbaur,J. Chem. Soc., Chem. Commun., 1993, 69; (b) R. E. Bachman and H. Schmidbaur,Inorg. Chem., 1996,35, 1399

    Article  Google Scholar 

  17. H. Shan, Y. Yang, A. J. James and P. R. Sharp,Science, 1997,275, 1460

    Article  CAS  Google Scholar 

  18. U. M. Tripathi, W. Scherer, A. Schier and H. Schmidbaur,Inorg. Chem., 1998,37, 174

    Article  CAS  Google Scholar 

  19. (a) K. Angermaier and H. Schmidbaur,J. Chem. Soc., Dalton Trans., 1995, 559; (b) J. Lopez-de-Luzuriaga, M. Söldner, A. Schier and H. Schmidbaur,Z. Naturforsch., 1997,52b, 209

    Article  Google Scholar 

  20. W. Schneider, A. Bauer and H. Schmidbaur,J. Chem. Soc., Dalton Trans., 1997, 415

  21. A. Bauer, F. P. Gabbai, A. Schier and H. Schmidbaur,Phil. Trans. Royal Soc. Lond. A, 1996,354, 381

    Article  CAS  Google Scholar 

  22. C. Hollatz and H. Schmidbaur, unpublished results 1999

  23. P. Lange, A. Schier,J. Riede and H. Schmidbaur, Z. Naturforsch., 1994,49b, 642

    Google Scholar 

  24. E. Zeller, H. Beruda, A. Kolb, P. Bissinger, J. Riede and H. Schmidbaur,Nature 1991,352, 141

    Article  CAS  Google Scholar 

  25. H. Beruda, E. Zeller and H. Schmidbaur,Chem. Ber., 1993,126, 2037

    Article  CAS  Google Scholar 

  26. (a) Y. Katsukawa, S. Onaka, Y. Yamada, M. Yamashita,Inorg. Chim. Acta, 1999,294, 255; (b) F. P. Gabbai, S. -C. Chung, A. Schier, S. Krüger, N. Rösch and H. Schmidbaur,Inorg. Chem., 1997,36, 5699; (c) V. G. Albano, C. Castellari, C. Femoni, M. C. Iapalucci, G. Longoni, M. Monari, M. Rauccio and S. Zacchini,Inorg. Chim. Acta, 1999,291, 372; (d) C. K. Schauer, S. Harris, M. Sabat, E. J. Voss and D. F. Shriver,Inorg. Chem., 1995,34, 5017

    Article  CAS  Google Scholar 

  27. N. Dufour, A. Schier and H. Schmidbaur,Organometallics, 1993,12, 2408

    Article  CAS  Google Scholar 

  28. H. Schmidbaur, F. P. Gabbai, A. Schier and J. Riede,Organometallics, 1995,14, 4969

    Article  CAS  Google Scholar 

  29. (a) K. Dziwok, J. Lachmann, D. L. Wilkinson, G. Müller and H. Schmidbaur,Chem. Ber., 1990,123, 423; (b) H. Schmidbaur, K. Dziwok, A. Grohmann and G. Müller,Chem. Ber., 1989,122, 893

    Article  CAS  Google Scholar 

  30. R. Narajanaswany, M. A. Young, E. Parkhurst, M. Ouelette, M. E. Kerr, D. M. Ho, R. C. Elder, A. E. Bruce and M. R. M. Bruce,Inorg. Chem., 1993,32, 2506

    Article  Google Scholar 

  31. H. Schmidbaur, W. Graf and G. Müller,Helv. Chim. Acta, 1986,69, 1748

    Article  CAS  Google Scholar 

  32. D. E. Harwell, M. D. Mortimer, C. B. Knobler, F. A. L. Anet and M. F. Hawthorne,J. Am. Chem. Soc., 1996,118, 2679

    Article  CAS  Google Scholar 

  33. (a) J. Zank, A. Schier and H. Schmidbaur,J. Chem. Soc., Dalton Trans., 1998, 323; (b) H. Schmidbaur, A. Kolb and P. Bissinger, Inorg. Chem., 1992,31, 4370

    Article  Google Scholar 

  34. (a) P. G. Jones,Z. Naturforsch., 1982,37b, 823; (b) S. Esperas,Acta Chem. Scand., 1976,A 30, 527

    CAS  Google Scholar 

  35. (a) J. Strähle, W. Hiller and W. Conzelmann,Z. Naturforsch., 1984,39b, 538; (b) S. Ahrland, B. Aurivillius, K. Dreisch, B. Noren and A. Oskarsson,Acta Chem. Scand., 1992,46, 262; (c) K. Angermaier, E. Zeller and H. Schmidbaur,J. Organomet. Chem., 1994,472, 371

    Google Scholar 

  36. M. Preisenberger, A. Schier and H. Schmidbaur,J. Chem. Soc., Dalton Trans., 1999, 1645

  37. (a) W. Schneider, K. Angermaier, A. Sladek and H. Schmidbaur,Z. Naturforsch., 1996,51b, 790; (b) A. Bauer and H. Schmidbaur,J. Am. Chem. Soc., 1996,118, 5324

    Google Scholar 

  38. (a) W. Conzelmann, W. Hiller, J. Stähle and G. M. Sheldrick,Z. Anorg. Allg. Chem., 1984,512, 169; (b) R. Usón, A. Laguna, M. Laguna, J. Jimenez, M. P. Gomez, A. Sainz and G. P. Jones,J. Chem. Soc., Dalton Trans., 1990, 3457

    Article  CAS  Google Scholar 

  39. J. H. K. Yip, R. Feng and J. J. Vittal,Inorg. Chem., 1999,38, 3586

    Article  CAS  Google Scholar 

  40. (a) D. Braga, F. Grepioni and G. R. Desiraju,Chem. Rev., 1998,98, 1375; (b) S. R. Pathaneni and G. R. Desiraju,J. Chem. Soc., Dalton Trans., 1993, 319; (c) M. A. Bennett, L. L. Welling and A. C. Willis,Inorg. Chem., 1997,36, 5670

    Article  CAS  Google Scholar 

  41. (a) P. M. van Calcar, M. M. Olmstead and A. L. Balch,J. Chem. Soc., Chem. Commun.,1995, 1773; (b) P. M. van Calcar, M. M. Olmstead and A. L. Balch,Inorg. Chem., 1997,36, 5231

    Google Scholar 

  42. (a) D. M. P. Mingos, J. Yau, S. Menzer and D. J. Williams,Angew. Chem., 1995,107, 2045; (b) C. P. McArdle, M. J. Irwin, M. C. Jennings and R. J. Puddephatt,Angew. Chem., 1999,111, 3571

    Article  Google Scholar 

  43. (a) W. Schneider, A. Bauer and H. Schmidbaur,Organometallics, 1996,15, 5445; (b) B. -C. Tzeng, A. Schier, and H. Schmidbaur,Inorg. Chem., 1999,38, 3978

    Article  CAS  Google Scholar 

  44. (a) J. Vicente, M. T. Chicote, M. D. Abrisqueta, R. Guerrero and P. G. Jones,Angew. Chem., Int. Ed. Engl., 1997,36, 1203; (b) J. G. Jones and B. Ahrens,New J. Chem., 1998,22, 1401; (c) B. Ahrens, P. G. Jones and A. K. Fischer,Eur. J. Inorg. Chem., 1999, 1103

    Article  CAS  Google Scholar 

  45. (a) H. G. Raubenheimer, F. Scott, G. J. Kruger, J. G. Toerien, R. Otte, W. van Zyl, I. Taljaard, P. Olivier and L. Linford,J. Chem. Soc., Dalton Trans., 1994, 2091; (b) D. M. P. Mingos, J. Yau, S. Menzer and D. J. Williams,J. Chem. Soc., Dalton Trans., 1995, 319; (c) J. -C. Shi, B. -S. Khang and T. C. W. Mak,J. Chem. Soc., Dalton Trans., 1997, 2171; (d) W. Schneider, A. Bauer and H. Schmidbaur,J. Chem. Soc., Dalton Trans., 1997, 415

  46. D. Perreault, M. Drouin, A. Michel, V. M. Miskowski, W. P. Schaefer and P. D. Harvey,Inorg. Chem., 1992,31, 695

    Article  CAS  Google Scholar 

  47. (a) Z. Assefa, B. G. McBurnett, R. J. Staples, J. P. Fackler Jr., B. Assmann, K. Angermaier and H. Schmidbaur,Inorg. Chem., 1995,34, 75; (b) H. Xiao, Y. -X. Weng, W. -T. Wong, T. C. W. Mak and C. -M. Che,J. Chem. Soc., Dalton Trans., 1997, 22; (c) T. Zhang, M. Drouin and P. D. Harvey,Inorg. Chem. 1999,38, 4928; (d) V. W. W. Yam, T. -F. Lai and C. -M. Che,J. Chem. Soc., Dalton Trans., 1990, 3747

    Article  CAS  Google Scholar 

  48. D. Li, C. -M. Che, S. -M. Peng, S. -T. Liu, Z. -Y. Zhou and T. C. W. Mak,J. Chem. Soc., Dalton Trans., 1993, 189

  49. J. C. Vickery, M. M. Olmstead, E. Y. Fung and A. L. Balch,Angew. Chem. Int. Ed. Engl., 1997,36, 1179

    Article  CAS  Google Scholar 

  50. J. Vicente, M. -T. Chicote and M. -C. Lagunas,Inorg. Chem., 1993,32, 3748

    Article  CAS  Google Scholar 

  51. P. Pyykkö, J. Li and N. Runeberg,Chem. Phys. Lett., 1994,218, 133

    Article  Google Scholar 

  52. (a) M. Munakata, L. P. Wu and T. Kurodo-Sowa,Adv. Inorg. Chem., 1999,46, 173; (b) K. Singh, J. R. Long and P. Stavropoulos,J. Am. Chem. Soc., 1997,119, 2943; (c) J. Strähle, in ‘Unkonventionelle Wechselwirkungen in der Chemie Metallischer Elemente’, B. Krebs, ed., VCH Publishers, New York, 1992, p. 357; (d) L. S. Ahmed, J. R. Dilworth, J. R. Miller and N. Wheatley,Inorg. Chem. Acta, 1998,278, 229

    Article  Google Scholar 

  53. (a) H. -J. Öller, P. Kiprof and H. Schmidbaur,Z. Naturforsch., 1992,47b, 333; (b) H. Schmidbaur, H. -J. Öller, D. L. Wilkinson, B. Huber and G. Müller,Chem. Ber., 1989,122, 31; (c) F. Zamora, M. Sabat, M. Janik, C. Siethoff and B. Lippert,J. Chem. Soc., Chem. Commun., 1997, 485

    Google Scholar 

  54. (a) P. K. Mehrotra and R. Hoffmann,Inorg. Chem. 1978,17, 2182; (b) A. Dedieu and R. Hoffmann,J. Am. Chem. Soc., 1978,100, 2074; (c) C. Janiak and R. Hoffmann,J. Am. Chem. Soc., 1990,112, 5924

    Article  Google Scholar 

  55. J. K. Burdett, O. Eisenstein and W. B. Schweizer,Inorg. Chem., 1994,33, 3261

    Article  CAS  Google Scholar 

  56. D. M. P. Mingos, T. Slee and L. Zhenyang,Chem. Rev., 1990,90, 385

    Article  Google Scholar 

  57. (a) O. D. Häberlen, H. Schmidbaur and N. Rösch,J. Am. Chem. Soc., 1994,116, 8241; (b) N. Rösch, A. Görling, D. E. Ellis and H. Schmidbaur,Inorg. Chem., 1991,30, 3986; (c) N. Rösch, A. Görling, D. E. Ellis and H. Schmidbaur,Angew. Chem. Int. Ed. Engl., 1989,28, 1357

    Article  Google Scholar 

  58. P. Pyykkö, K. Angermaier, B. Assmann and H. Schmidbaur,J. Chem. Soc., Chem. Commun. 1995, 1889

  59. (a) P. Pyykkö, N. Runeberg and F. Mendizabal,Chem. Eur. J., 1997,3, 1451; (b) P. Pyykkö and F. Mendizabal,Chem. Eur. J., 1997,3, 1459

    Article  Google Scholar 

  60. P. Pyykkö,Chem. Rev., 1997,97, 597

    Article  Google Scholar 

  61. P. Schwerdtfeger, A. E. Bruce and M. R. M. Bruce,J. Am. Chem. Soc., 1998,120, 6587

    Article  CAS  Google Scholar 

  62. N. Kaltsoyannis,J. Chem. Soc., Dalton Trans., 1997, 1

  63. (a) J. M. Zuo, M. Kim, M. O'Keefe and J. C. H. Spence,Nature, 1999,401, 49; (b) C. J. Humphreys, Nature, 1999, 401, 21

    Article  CAS  Google Scholar 

  64. (a) B. Standke and M. Jansen,Z. Anorg. Allg. Chem., 1986,535, 39; (b) N. Bartlett,Gold Bull., 1998,31, 22

    Article  CAS  Google Scholar 

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Dedicated to the memory of William S Rapson

Prof Dr Hubert Schmidbaur has the Chair of Inorganic and Analytical Chemistry and is Head of the Inorganic Chemistry Institute at the Technical University of Munich. He has ca 750 publications, with research papers and review articles on a wide range of inorganic topics including gold chemistry. He has received a significant number of international awards and honours, including endowed lectureships, and recently edited a book entitled ‘Gold: Progress in Chemistry, Biochemistry and Technology’, the starting point for which was an international conference in Hanau which he chaired (seeGold Bulletin, 1996,29, 105; 1998,31, 134).

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Schmidbaur, H. The aurophilicity phenomenon: A decade of experimental findings, theoretical concepts and emerging applications. Gold Bull 33, 3–10 (2000). https://doi.org/10.1007/BF03215477

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