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Synthesis and crystal structure of new supramolecular adducts of [PtCl6]2− with cucurbit [7] uril: [(H3O)2 (PtCl6)]3 (C42H42N28O14)2·H2O

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Wuhan University Journal of Natural Sciences

Abstract

A novel supramolecular adduct [(H3O)2 (PtCl6)]3 (C42H42N28O14)2·H2O (1) was synthesized by mixing [PtCl6]2− and cucurbit [7] uril in solution of hydrochloric acid. The crystal structure was determined by single crystal X-ray diffraction analysis. The crystal belongs to orthorhombic system and space group F dd2 with cell dimensions:a=4. 705 33 (5) nm,b=7. 153 80 (6) nm,c=1. 894 61 (2) nm,Z=16,V=63, 7744 (11) nm3,D c =1.534 g/cm3, μ=3. 007 mm−1,F(000)=29 120,R 1=0.070 7,wR 2=0. 169 2. In crystal, the cucurb [7] uril molecules from two zig-zag chains.

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Author notes

  1. Wu Cheng-tai

    Present address: College of Chemistry and Molecular Sciences, Wuhan University, 430072, Wuhan Hubei, China

Authors and Affiliations

  1. College of Chemistry and Molecular Sciences, Wuhan University, 430072, Wuhan Hubei, China

    Yan Kun, Liu Si-min & Liang Feng

  2. Fujian Institute of Research on the Structure of Matter, CAS, 350002, Fuzhou Fujian, China

    Huang Zi-xiang

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  1. Yan Kun
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  2. Huang Zi-xiang
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  3. Liu Si-min
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  4. Liang Feng
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  5. Wu Cheng-tai
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Additional information

Foundation item: Supported by the National Natural Science Foundation of China (20172040)

Biography: Yan kun (1977-), female, Master, research direction: macrocyclic chemistry.

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Kun, Y., Zi-xiang, H., Si-min, L. et al. Synthesis and crystal structure of new supramolecular adducts of [PtCl6]2− with cucurbit [7] uril: [(H3O)2 (PtCl6)]3 (C42H42N28O14)2·H2O. Wuhan Univ. J. Nat. Sci. 9, 99–101 (2004). https://doi.org/10.1007/BF02912727

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  • DOI: https://doi.org/10.1007/BF02912727

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