Abstract
These compounds with various connecting groups between the two lipophilic groups were prepared by the reaction of glycol diglycidyl ethers with long-chain alcohols, followed by sulfation with chlorosulfonic acid or with a mixture of chlorosulfonic acid and acetic acid. The Krafft point of all these new amphipathic compounds was below 0°C, and they had good water solubility. These compounds were superior in surface active properties to general anionic surfactants with one lipophilic chain and one hydrophilic group, such as sodium dodecylsulfate. The effect of the structure of the connecting group on CMC, γCMC, foaming properties and wetting ability was investigated. They also showed excellent lime-soap dispersing ability.
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References
Ringsdorf, H., B. Schlarb and J. Venzer,Angew. Chem. Int. Ed. Engl. 27:113 (1988).
Kunitake, T. and Y. Okahata,J. Am. Chem. Soc. 97:3860 (1977).
Gu, X-P. I. Ikeda and M. Okahara,Synthesis: 649 (1985).
Maeda, H., T. Kikui, Y. Nakatsuji and M. Okahara,Ibid. Synthesis: 185 (1983).
Ikeda, I., Y. Tsuji, Y. Nakatsuji and M. Okahara,J. Org. Chem. 51:1128 (1986).
Nakatsuji, Y., Y. Tsuji, I. Ikeda and M. Okahara, ——Ibid.51: 78 (1986).
Gu, X-P. I. Ikeda, M. Okahara and J. Kim,Chem. Lett.: 1715 (1986).
Okahara, M., A. Masuyama, Y. Sumida and Y-P. Zhu,J. Jpn. Oil Chem. Soc. (Yukagaku) 37:716 (1988), andChem. Abstracts 110:10096q (1989).
Micich, T.J. and W.M. Linfield,J. Am. Oil Chem. Soc. 65:820 (1988).
Hidaka, H., H. Sei, T. Furuta and T. Ishikawa,J. Jpn. Oil Chem. Soc. (Yukagaku) 27:370 (1978), andChem. Abstracts 89:146372g (1978).
Rosen, M.J., inSurfactants and Interfacial Phenomena, 2nd edn., John Wiley & Sons, New York, 1989, pp. 122, 123 and 220.
Yano, W. and W. Kimura,Yakagaku 11:138 (1962).
Borghetty, H.C. and C.A. Bergman.,J. Am. Oil Chem. Soc. 27:88 (1950).
Götte, E. and M.J. Schwuger,Tenside Detergents 6:131 (1969).
Rosen, M.J.,J. Am. Oil Chem. Soc. 49:293 (1972).
Hartley, G.H.,Trans. Faraday Soc. 37:130 (1941).
Masuyama, A., A. Shindoh, D. Ono and M. Okahara,J. Am. Oil Chem. Soc. 66:834 (1989).
Linfield, W.M., inAnionic Surfactants, Part I, Marcel Dekker, Inc., New York, 1976, pp. 2 and 3.
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Zhu, Yp., Masuyama, A. & Okahara, M. Preparation and surface active properties of amphipathic compounds with two sulfate groups and two lipophilic alkyl chains. J Am Oil Chem Soc 67, 459–463 (1990). https://doi.org/10.1007/BF02638962
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DOI: https://doi.org/10.1007/BF02638962