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Zirconium(IV) catalysis in perborate oxidation of iodide

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Abstract

Zirconium(IV) catalyzes perborate oxidation of iodide ion. In acidic solution the oxidation is zero order with respect to perborate, first order with respect to Zr(IV), independent of [H+] and exhibits Michaelis-Menten dependence on [I−]. Mechanistic pathway of the catalysis is discussed and a rate equation is derived.

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Authors and Affiliations

  1. Department of Chemistry, Annamalai University, 608002, Annamalainagar, India

    C. Karunakaran & B. Muthukumaran

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  1. C. Karunakaran
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  2. B. Muthukumaran
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Karunakaran, C., Muthukumaran, B. Zirconium(IV) catalysis in perborate oxidation of iodide. React Kinet Catal Lett 60, 387–394 (1997). https://doi.org/10.1007/BF02475703

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  • DOI: https://doi.org/10.1007/BF02475703

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