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Electronic dynamics and real-time observations of pre-reactive states in aqueous solutions

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Abstract

With the intensive development of ultrafast spectroscopic techniques, reaction dynamics and transition states can be investigated at the subpicosecond time scale (0.05–3 ps). Aqueous ionic solutions represent a paradigm for the characterization of elementary chemical steps at the microscopic level. The discrimination of very short-lived electronic states during electron transfers in molecular liquids provide guidance for further theoretical developments on non-reactive and reactive dynamics in complicated many body systems.

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Authors and Affiliations

  1. Laboratoire d'Optique Appliquée, CNRS URA 1406, INSERM U451, Ecole Polytechnique—ENSTA, 91761, Palaiseau cedex, France

    Y. Gauduel, M. Sander & H. Gelabert

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  1. Y. Gauduel
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  2. M. Sander
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  3. H. Gelabert
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Correspondence to Y. Gauduel.

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Gauduel, Y., Sander, M. & Gelabert, H. Electronic dynamics and real-time observations of pre-reactive states in aqueous solutions. J Radioanal Nucl Chem 232, 125–129 (1998). https://doi.org/10.1007/BF02383726

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