Abstract
The magnetic data χ(T) and μ(T) of the Mn(II) phthalocyanine have been fitted by assuming the existence of a Heisenberg exchange interaction between the Mn cations. From our model it has been possible to explain the electronic structure of the Mn cations and the high value of the anisotropy magnetic field.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Ingram, D.J.E., Bennet, J.E.: J. Chem. Phys.38, 2778 (1963)
Engelsma, G., Yamamoto, A., Markham, E., Calvin, M.: J. Phys. Chem.66, 2517 (1962)
Barraclough, C.G., Martin, R.L., Mitra, S., Sherwood, R.C.: J. Chem. Phys.53, 1638 (1970)
Lever, A.B.P.: Adv. Inorg. Chem. Radiochem.7, 27 (1965)
Barraclough, C.G., Gragson, A.K., Mitra, S.: J. Chem. Phys.60, 962 (1974)
Labarta, A., Viñas, X., Tejada, J.: J. Chem. Phys.78, 5816 (1983)
Boudreax, E.A., Mulay, L.N.: Theory and applications of molecular Paramagnetism. New York: John Wiley (1976)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Labarta, A., Molins, E. & Tejada, J. A new interpretation of the magnetic properties and electronic structure of manganese (II) phthalocyanine. Z. Physik B - Condensed Matter 58, 299–304 (1985). https://doi.org/10.1007/BF01303671
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01303671