Summary
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1.
The dissociation constants of aliphatic nitro compounds may be found spectrophotometrically to a high degree of accuracy.
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2.
The dissociation constants of ten nitroalkanes have been measured at various temperatures (trinitromethane, 1,1-dinitroalkanes, and 1,1,3,3-tetranitroalkanes).
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3.
The acidity function H− has been found for hydrochloric acid in concentrations from 0.1–1.2 M.
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4.
Standard values of the enthalpy and entropy of the dissociation reactions of nitroalkanes have been calculated from the temperature dependence of the dissociation constants.
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Novikov, S.S., Slovetskii, V.I., Shevelev, S.A. et al. Spectrophotometric determination of the dissociation constants of aliphatic nitro compounds. Russ Chem Bull 11, 552–559 (1962). https://doi.org/10.1007/BF00904751
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DOI: https://doi.org/10.1007/BF00904751