Skip to main content
SpringerLink
Log in

Some properties of cesium perchloratoborate

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The boron atom is capable of coordinating four perchlorato groups with the formation of the complex anion [B(ClO4)4]−.

  2. 2.

    The properties of cesium perchloratoborate were studied. The low heat stability of Cs[B(ClO4)4] is explained by the substantial deviation in the symmetry of the ClO4 groups from tetrahedral and a weakening of the Cl-O(B) bonds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. J. Lewis, R. S. Nyholm, and G. A. Rodley, Nature,207, No. 4992, 72 (1965).

    Google Scholar 

  2. W. C. Jones and W. E. Bull, J. Chem. Soc., A, 1849 (1968).

    Google Scholar 

  3. Chem. Eng. News,42, No. 38, 53 (1964).

  4. L. E. Moore, R. B. Gayhart, and W. E. Bull, J. Inorg. Nuclear Chem., 26, 896 (1964).

    Google Scholar 

  5. A. E. Wickenden and R. A. Krause, Inorg. Chem.,4, 404 (1965).

    Google Scholar 

  6. S. F. Pavkovic and D. W. Meek, Inorg. Chem.,4, 1091 (1965).

    Google Scholar 

  7. A. V. Butcher, D. J. Phillips, and J. P. Redfern, J. Inorg. Nuclear Chem.,28, 2765 (1966).

    Google Scholar 

  8. N. T. Barker, C. M. Harris, and E. D. McKenzie, Proc. Chem. Soc., 335 (1961).

  9. W. R. McWhinnie, J. Inorg. Nuclear Chem., 26, 21 (1964).

    Google Scholar 

  10. I. Ruidisch and M. Schmidt, Z. Naturforsch.,18b, 508 (1963).

    Google Scholar 

  11. H. C. Clark and R. J. O'Brien, Inorg. Chem.,2, 740 (1963).

    Google Scholar 

  12. V. M. Vdovenko, L. G. Mashirov, and D. N. Suglobov, Radiokhimiya,6, 299 (1964).

    Google Scholar 

  13. P. Pauling, G. B. Robertson, and G. A. Rodley, Nature,207, No. 4992, 73 (1965).

    Google Scholar 

  14. F. A. Cotton and D. L. Weaver, J. Am. Chem. Soc.,87, 4189 (1965).

    Google Scholar 

  15. F. Madaule-Aubry and G. M. Brown, Acta Cryst.,B24, 746 (1968).

    Google Scholar 

  16. D. G. Lemesheva and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1877 (1969).

  17. R. A. Mosher, E. K. Ives, and E. F. Morello, J. Am. Chem. Soc.,85, 3037 (1963).

    Google Scholar 

  18. K. V. Titova and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2670 (1970).

  19. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds [Russian translation], Mir (1966).

  20. V. Ya. Rosolovskii, Chemistry of Anhydrous Perchloric Acid [in Russian], Nauka (1966).

Download references

Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, USSR

    V. Ya. Rosolovskii & V. P. Babaeva

Authors
  1. V. Ya. Rosolovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. P. Babaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 873–875, April, 1971.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rosolovskii, V.Y., Babaeva, V.P. Some properties of cesium perchloratoborate. Russ Chem Bull 20, 792–794 (1971). https://doi.org/10.1007/BF00853930

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00853930

Keywords

Search

Navigation