Abstract
The reduction of nickel/silica catalysts was studied in parallel by temperature programmed reduction (TPR) and X-ray diffraction (XRD) methods. The calcined materials contain nickel in the form of nickel oxide and nickel hydrosilicates and a part of the oxide particles is covered with the hydrosilicate species. This oxide is reduced in the same way as unsupported nickel oxide in the absence of water, and in a similar way to nickel hydrosilicates in the presence of water.
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References
A. Roman and B. Delmon, J. Catal. 30 (1973) 333.
M. Houalla, F. Delannay, I. Matsuura and B. Delmon, J. Chem. Faraday Trans. I 76 (1980) 2128.
J.W.E. Coenen, in:Preparation of Catalysts. II, eds. B. Delmon, P. Grange, P.A. Jacobs and G. Poncelet (Elsevier, Amsterdam, 1979) p. 89.
Turlier, H. Praliaud, P. Moral and G.A. Martin, J. Catal. 19 (1985) 287.
J.C. Vedrine, G. Hollinger and T. M. Duc, J. Phys. Chem. 82 (1978) 1515.
A.R. Gonzalez-Elipe, G. Maunura and J.P. Espinos, Surf. Interf. Anal. 16 (1990) 375.
J.P. Espinos, A.R. Gonzalez-Elipe, A. Caballero, J. Garcia and G. Munuera, J. Catal. 136 (1992)415.
L. Bonneviot, M. Che, D. Olivier, G.A. Martin and E. Freund, J. Phys. Chem. 90 (1986) 2112.
B. Mile, D. Stirling, M.A. Zammitt, A. Lovell and M. Webb, J. Catal. 114 (1988) 217.
M. Kuijpers, M.W.C.M.A. Nieuwesteeg, G.J. Wermer and J.W. Geus, J. Catal. 112 (1988) 107.
S. Uchiyama, Y. Obayashi, T. Hayasaka and N. Kawata, Appl. Catal. 47 (1989) 155.
O. Clause, M. Kermarek, L. Bonneviot, F. Villain and M. Che, J. Am. Chem. Soc. 114 (1992) 4709.
O. Clause, L. Bonneviot and M. Che, J. Catal. 138 (1992) 195.
L. Zhang, J. Lin and Y. Chen, J. Chem. Soc. Faraday. Trans. 88 (1992) 2075.
J.W.E. Coenen and P.B. Wells, in:Preparation of Catalysts. III, eds. G. Poncelet, P. Grange and P.A. Jacobs (Elsevier, Amsterdam, 1983) p. 801.
J.W.E. Coenen, Appl. Catal. 54 (1989) 59.
J.W.E. Coenen, Appl. Catal. 54 (1989) 65.
J.W.E. Coenen, Appl. Catal. 75 (1991) 193.
J. Zieliński, J. Catal. 76 (1982) 157.
J. Zieliński, React. Kinet. Catal. Lett. 17 (1981) 69.
J. Zieliński and A. Borodziński, Appl. Catal. 13 (1985) 305.
V.A. Dzisko, S.P. Noskova, L.G. Karakchiev, M.S. Borisova, V.D. Bolgova and T.Ia. Tiulipova, Kinet. Katal. 13 (1972) 366.
G.A. Martin, N. Ceaphalan, P. de Montgolfier and B. Imelik, J. Chim. Phys. 70 (1973) 1422.
N.E. Buyanova, A.P. Karnaukhov, L. Kefeli, I.M. Ratner and O.K. Černavska, Kinet. Katal. 8 (1967) 868.
J.S. Smith, P.A. Thrower and M.A. Vannice, J. Catal. 68 (1981).
C.H. Bartholomew and R. J. Farrauto, J. Catal. 45 (1976) 41.
E. Iglesia and M. Boudard, J. Catal. 81 (1983) 204.
J. Zieliński, Catal. Lett. 12 (1992) 389.
S. Engels, W. Mörke, M. Wilde, W. Roschke and B. Freitag, Z. Anorg. Allg. Chem. 472 (1981) 162.
Y.-W. Chungg, G. Xiong and C.C. Kao, J. Catal. 85 (1984) 273.
R. Lamber and G. Schulz-Ekloff, Surf. Sci. 258 (1991) 258.
J. Zieliński, J. Mol. Catal. 83 (1993) 197.
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Zieliński, J. Reductibility of silica supported nickel oxide. Catal Lett 31, 47–56 (1995). https://doi.org/10.1007/BF00817032
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DOI: https://doi.org/10.1007/BF00817032