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Strength of glass (a review)

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Abstract

After defining the termglass, brief consideration is given to the theories of glass structure which have been propounded. That glass, in practice, is very much weaker than its theoretical strength predicts is established, and the prime factor for this is shown to be the surface condition of the glass. Surface defects which are accentuated by heat treatment or other processes are considered, and the effects of the structural state, loading, and water and other liquids are dealt with. Methods of measuring the strength of glass are discussed and techniques of strength reinforcement, particularly in respect of producing a flaw-free surface and protecting it against subsequent damage, in the light of current knowledge are indicated. Many possible techniques for achieving strengthening have been postulated in the literature and some of these have now been commercially applied. Particularly, thermal and chemical toughening processes — the latter including ion-diffusion techniques recently developed — are reviewed. Where possible, references to the original papers and patents are provided. The references given, whilst not comprehensive, will permit a wider study of the subject.

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References

  1. E. V. Condon,Amer. J. Phys. 22 (1954) 43.

    Google Scholar 

  2. J. T. Randall et al, Z. Kristollogr. 75 (1930) 196.

    Google Scholar 

  3. A. A. Lebedev,Trans. Opt. Inst. Leningr. 2 (1921) 51.

    Google Scholar 

  4. W. M. Zachariasen,J. Amer. Chem. Soc. 58 (1932) 3841.

    Google Scholar 

  5. B. E. Warren et al, J. Amer. Ceram. Soc. 75 (1930) 196.

    Google Scholar 

  6. N. Valenkov andE. A. Porai-Koshits,Z. Kristallogr. 95 (1936) 195.

    Google Scholar 

  7. I. Peyches,Silicates Industr. 28 (1963) 223.

    Google Scholar 

  8. J. Zarzychki andR. Mezard,Phys. and Chem. of Glasses 3 (1962) 163.

    Google Scholar 

  9. V. Garino-Canina,C. R. Acad. Sci., Paris 252 (1961) 1807.

    Google Scholar 

  10. J. M. Stevels,J. Soc. Glass. Tech. 35 (1951) 284.

    Google Scholar 

  11. M. Polanyi,Z. für Phys. 7 (1921) 323.

    Google Scholar 

  12. E. Orowan,Inst. of Eng. and Shipp. in Scotland 89 (1945–46) 165.

    Google Scholar 

  13. A. A. Griffith,Phil. Trans. Roy. Soc. A221 (1920) 163.

    Google Scholar 

  14. J. T. Littleton,Phys. Rev. 22 (1923) 510.

    Google Scholar 

  15. F. W. Preston,J. Soc. Glass Tech. 17 (1933) 4.

    Google Scholar 

  16. R. Bowles andB. Sugarman,Glass Tech. 3 (1962) 156.

    Google Scholar 

  17. K. H. H. Müller,Z. Physik 69 (1931) 431.

    Google Scholar 

  18. B. Proctor,Phys. and Chem. of Glasses 3 (1962) 7.

    Google Scholar 

  19. C. Symmers et al, ibid 3 (1962), p. 76.

    Google Scholar 

  20. F. O. Anderegg,Industr. Engng. Chem. 31 (1939) 290.

    Google Scholar 

  21. W. H. Otto,J. Amer. Ceram. Soc. 38 (1955) 122.

    Google Scholar 

  22. W. F. Thomas,Phys. and Chem. of Glasses 1 (1960) 4.

    Google Scholar 

  23. E. M. Andrade andL. C. Tsien,Proc. Roy. Soc. A159 (1937) 346.

    Google Scholar 

  24. J. E. Gordon et al, ibid A249 (1959) 65.

    Google Scholar 

  25. A. S. Argon,ibid A250 (1959) 472.

    Google Scholar 

  26. J. Nakayama,J. Phys. Soc. Japan 14 (1959) 1107.

    Google Scholar 

  27. F. M. Ernsberger,Proc. Roy. Soc. A257 (1960) 213; “Advances in Glass Technology” (Plenum Press, New York, 1962).

    Google Scholar 

  28. W. C. Levengood,J. Appl. Phys. 37 (1959) 378.

    Google Scholar 

  29. W. Brearley andD. G. Holloway,Phys. and Chem. of Glasses 4 (1963) 69.

    Google Scholar 

  30. J. Cornelissen andA. L. Zijlstra, Internal communication of the Glass Development Centre of the Philips Glass Works (1960).

  31. A. Smekal,J. Soc. Glass Tech. 20 (1936) 432.

    Google Scholar 

  32. J. B. Murgatroyd,ibid 28 (1944) 368.

    Google Scholar 

  33. O. L. Anderson,J. Appl. Phys. 29 (1958) 9.

    Google Scholar 

  34. G. M. Bartenov andA. M. Bovkumenko,Soviet Phys. Tech. Phys. 26 (1956) 2508.

    Google Scholar 

  35. H. E. Powell andF. W. Preston,J. Amer. Ceram. Soc. 28 (1945) 145.

    Google Scholar 

  36. T. A. Kontorova,J. Tech. Phys. USSR (1945) 436.

  37. J. B. Ward et al, Glass Tech. 6 (1965) 90.

    Google Scholar 

  38. S. Sakka,J. Ceram. Ass. Japan 65 (1957) 190.

    Google Scholar 

  39. A. L. Zijlstra, Internal communication of the Glass Development Centre of the Philips Glass Works (1959 and 1960).

  40. F. J. Radd andD. H. Oertle,Nature 184 (1959) 976.

    Google Scholar 

  41. C. J. Culf,J. Soc. Glass Tech. 41 (1957) 157.

    Google Scholar 

  42. G. F. Stockdale et al, J. Amer. Ceram. Soc. 34 (1951) 116.

    Google Scholar 

  43. V. K. Moorthy andF. V. Tooley,ibid 39 (1956) 215.

    Google Scholar 

  44. R. E. Mould,ibid 43 (1960) 160.

    Google Scholar 

  45. M. Watanabe et al, Phys. and Chem. of Glasses 2 (1961) 12.

    Google Scholar 

  46. V. K. Moorthy et al, J. Amer. Ceram. Soc. 39 (1956) 395.

    Google Scholar 

  47. K. H. Borchard,Glastech. Ber. 13 (1935) 52.

    Google Scholar 

  48. J. McCormick,Bull. Amer. Ceram. Soc. 15 (1936) 268.

    Google Scholar 

  49. A. J. Holland andW. E. S. Turner,J. Soc. Glass Tech. 24 (1940) 46.

    Google Scholar 

  50. T. C. Baker andF. W. Preston,J. Appl. Phys. 17 (1946) 170.

    Google Scholar 

  51. C. Gurney andS. Pearson,Proc. Phys. Soc. 62 (1949) 469.

    Google Scholar 

  52. R. J. Charles,J. Appl. Phys. 29 (1958) 1549.

    Google Scholar 

  53. R. E. Mould andR. D. Southwick,J. Amer. Ceram. Soc. 42 (1959) 542.

    Google Scholar 

  54. W. H. Otto andF. W. Preston,J. Soc. Glass Tech. 34 (1950) 63.

    Google Scholar 

  55. W. Brearley et al, Phys. and Chem. of Glasses 3 (1962) 181.

    Google Scholar 

  56. H. Schardin andF. Kerkhof,Glasech. Ber. 28 (1955) 124.

    Google Scholar 

  57. R. W. Douglas andJ. O. Isard,J. Soc. Glass Tech. 33 (1949) 289.

    Google Scholar 

  58. H. Tober,Glastech. Ber. 34 (1961) 46.

    Google Scholar 

  59. United Bottle Glass Manufacturers Ltd andE. Seddon,British Patent 556602.

  60. D. T. Bumpstead,J. Soc. Glass Tech. 42 (1958) 204.

    Google Scholar 

  61. B. E. Moody,ibid, p. 177.

    Google Scholar 

  62. K. L. Loewenstein,ibid, p. 70.

    Google Scholar 

  63. L. Riedel,Glas-Email-Keramo-Tech. 8 (1957) 176.

    Google Scholar 

  64. H. Schonbrünn,Glastech. Ber. 31 (1958) 38.

    Google Scholar 

  65. E. I. Dupont De Nemours andCo,US Patents 2831780, 3004863, and 3130071.

  66. United Glass Ltd,British Patent 1024468.

  67. H. M. Lontz et al, Glass Industry 47 (1966) 436.

    Google Scholar 

  68. F. Van Tetterode,Belgian Patent 565739.

  69. C. I. Silvestrovich andI. A. Boguslavskii,Steklo i Keramika 17 (1960) 7.

    Google Scholar 

  70. F. F. Vitman et al, C. R. Acad. Sci. USSR 145 (1962) 85.

    Google Scholar 

  71. O. Schott,German Patent 61573.

  72. G. Frikell,Glas-Email-Keramo-Tech. 9 (1958) 250.

    Google Scholar 

  73. S. M. Brekhovskikh,Steklo i Keramika 17 (1960) 24.

    Google Scholar 

  74. T. M. Mike et al, J. Amer. Ceram. Soc. 43 (1960) 405.

    Google Scholar 

  75. M. W. Thomson, Atomic Energy Res. Estab. (1957) M/R 2305/(25).

  76. Companie de Saint-Gobain SA,French Patents 1253955 and 1253956.

  77. S. S. Kistler,J. Amer. Ceram. Soc. 45 (1962) 59.

    Google Scholar 

  78. Research Corp Inc,British Patent 917388.

  79. G. Korányi,J. Soc. Glass Tech. 43 (1959) 438.

    Google Scholar 

  80. S. Glasstone, “Textbook of Physical Chemistry” (MacMillan, London, 1956).

    Google Scholar 

  81. Corning Glass Works,British Patent 1026770.

  82. Pittsburgh Plate Glass Co,British Patents 1018890 and 1027136.

  83. Imperial Chemical Industries Ltd,British Patents 1011638 and 1014247.

  84. S. D. Stookey et al, “Advances in Glass Technology” (Plenum Press, New York, 1962).

    Google Scholar 

  85. P. Acloque, “Symp. res. mech. du verre”, Union Scientifique Continentale du Verre, Paris (1962).

    Google Scholar 

  86. Corning Glass Works,US Patents 2779136 and 2998675.

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Sugarman, B. Strength of glass (a review). J Mater Sci 2, 275–283 (1967). https://doi.org/10.1007/BF00555385

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