Skip to main content
Log in

Nanostructured Ti-Cr-B-N and Ti-Cr-Si-C-N coatings for hard-alloy cutting tools

  • Nanostructured Materials and Functional Coatings
  • Published:
Russian Journal of Non-Ferrous Metals Aims and scope Submit manuscript

Abstract

Nanostructured Ti-Cr-B-N and Ti-Cr-Si-C-N coatings with various contents of chromium and nitrogen are obtained by the magnetron sputtering of multiphase composite targets. Their structure and phase composition are investigated by X-ray phase analysis, transmission and scanning electron microscopy, X-ray photoelectron spectroscopy, and optical emission glow-discharge spectroscopy. The Ti-Cr-B-N and Ti-Cr-Si-C-N coatings are based on the fcc phase with texture (100) and crystallite size <25 nm. The Si3N4-based hexagonal phase was also revealed in the Ti-Cr-Si-C-N coatings. An investigation into the properties of coatings with the use of methods of nanoindentation, scratch testing, and by performing tribological tests showed that they have a hardness of up to 30 GPa, an adhesion strength no lower than 35 N, and their friction coefficient falls in the range of 0.35–0.57. Coatings also possess high thermal stability, resistance to oxidation, and corrosion stability in a 1N H2SO4 solution. The data obtained in tests of hard-alloy cutting tools indicate that the deposition of nanostructured Ti-Cr-B-N and Ti-Cr-Si-C-N coatings increases its resistance by a factor of 11–17.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Holubar, P., Jilek, M., and Sima, M., Surf. Coat. Technol, 1999, vol. 120–121, p. 184.

    Article  Google Scholar 

  2. Muller, K.B., J. Mater. Proces. Technol, 2002, vol. 130–131, p. 432.

    Article  Google Scholar 

  3. Mitterer, C., Holler, F., Reitberger, D., et al., Surface Coat. Technol, 2003, vol. 163–164, p. 716.

    Article  Google Scholar 

  4. Kiryukhantsev-Korneev, F.V., Shtansky, D.V., Sheveiko, A.N., et al., Fiz. Met. Metalloved., 2004, vol. 97, no. 3, p. 96.

    CAS  Google Scholar 

  5. Shtansky, D.V., Kiryukhantsev-Korneev, F.V., Sheveiko, A.N., et al., Fiz. Tverd. Tela, 2005, vol. 47, no. 2, p. 242 [Phys. Sol. St. (Engl. Transl.), vol. 47, no. 2, p. 252].

    Google Scholar 

  6. Kiryukhantsev-Korneev, F.V., Petrzhik, M.I., Sheveiko, A.N., et al., Fiz. Met. Metalloved., 2007, vol. 104, no. 2, p. 176.

    CAS  Google Scholar 

  7. Shtansky, D.V., Levashov, E.A., Sheveiko, A.N., and Moore, J.J., J. Mater. Synth. Proces, 1998, vol. 6, no. 1, p. 61.

    Article  CAS  Google Scholar 

  8. Karvankova, P., Veprek-Heijman, M.G.J., Zawrah, M.F., and Veprek, S., Thin Solid Films, 2004, vol. 467, p. 133.

    Article  CAS  Google Scholar 

  9. Otani, Y. and Hofmann, S., Thin Solid Films, 1996, vol. 287, p. 188.

    Article  CAS  Google Scholar 

  10. Park, I.-W. and Kim, K.H., J. Mater. Proces. Technol, 2002, vol. 130–131, p. 254.

    Article  Google Scholar 

  11. Shtansky, D.V., Sheveiko, A.N., Petrzhik, M.I., et al., Surf. Coat. Technol., 2005, vol. 200, p. 208.

    Article  CAS  Google Scholar 

  12. Shtansky, D.V., Sheveyko, A.N., Sorokin, D.I., et al., Surf. Coat. Technol., 2008, vol. 202, p. 5953.

    Article  CAS  Google Scholar 

  13. Petrzhik, M.I. and Levashov, E.A., Kristallografiya, 2007, vol. 52, no. 6, p. 1002 [Crystallogr. Rep. (Engl. Transl.), vol. 52, no. 6, p. 966].

    Google Scholar 

  14. Sundgren, J.-E. and Hultman, L., Materials and Processes for Surface and Interface Engineering, Netherlands: Kluwer, 1995, p. 453.

    Google Scholar 

  15. Kiryukhantsev-Korneev, F.V., Sheveiko, A.N., Levashov, E.A., and Shtanskii, D.V., Vopr. Materialoved., 2008, vol. 2, no. 54, p. 187.

    Google Scholar 

  16. Patsalas, P., Charitidis, C., and Logothetidis, S., Surf. Coat. Technol., 2000, vol. 125, p. 335.

    Article  CAS  Google Scholar 

  17. Kadlec, S., Musil, J., Munz, W.-D., et al., Surf. Coat. Technol., 1989, vol. 39–40, p. 487.

    Article  Google Scholar 

  18. Wittberg, T.N., Hoenigman, J.R., Moddeman, W.E., et al., J. Vac. Sci. Technol., 1978, vol. 15, p. 348.

    Article  CAS  Google Scholar 

  19. Smith, K.L. and Black, K.M., J. Vac. Sci. Technol., 1984, vol. 2, p. 744.

    Article  CAS  Google Scholar 

  20. Shtansky, D.V., Kiryukhantsev-Korneev, Ph.V., Sheveyko, A.N., et al., Surf. Coat. Technol., 2007, vol. 202, p. 861.

    Article  CAS  Google Scholar 

  21. Mayrhofer, P.H., Nanostructured thin films and nanodispersion strengthened films, NATO Ser. Kluwer, 2004, p. 57.

  22. Paternoster, C., Fabrizi, A., Cecchini, R., et al., Surf. Coat. Technol., 2008, vol. 203, p. 736.

    Article  CAS  Google Scholar 

  23. Marques, A.P. and Cavaleiro, A., Thin Solid Films, 2003, vol. 441, p. 150.

    Article  CAS  Google Scholar 

  24. Kiryukhantsev-Korneev, F.V., Sheveiko, A.N., Petrzhik, M.I., et al., Abstracts of Papers, Trudy XI Mezhdunarodnoi nauchno-tekhnicheskoi konferentsii “Vysokie tekhnologii v promyshlennosti Rossii” (Proc. XI Int. Sci.-Pract. Conf. “High Technologies in Russian Industry), Moscow: ZNIITI Tekhnomash, 2005, p. 461.

    Google Scholar 

  25. Kiryukhantsev-Korneev, Ph.V., Pierson, J.F., Petrzhik, M.I., et al., Thin Solid Films, 2009, vol. 517, p. 2675.

    Article  CAS  Google Scholar 

  26. Panfilov, Yu.V., Belikov, A.I., and Gladyshev, I.V., Abstracts of Papers, Trudy XI Mezhdunarodnoi nauchno-tekhnicheskoi konferentsii “Vysokie tekhnologii v promyshlennosti Rossii” (Proc. XI Int. Sci.-Pract. Conf. “High Technologies in Russian Industry), Moscow: ZNIITI Tekhnomash, 2005, p. 488.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to F. V. Kiryukhantsev-Korneev.

Additional information

Original Russian Text © F.V. Kiryukhantsev-Korneev, A.N. Sheveiko, V.A. Komarov, M.S. Blanter, E.A. Skryleva, N.A. Shirmanov, E.A. Levashov, D.V. Shtansky, 2010, published in Izvestiya VUZ. Poroshkovaya Metallurgiya i Funktsional’nye Pokrytiya, 2010, No. 2, pp. 39–47.

About this article

Cite this article

Kiryukhantsev-Korneev, F.V., Sheveiko, A.N., Komarov, V.A. et al. Nanostructured Ti-Cr-B-N and Ti-Cr-Si-C-N coatings for hard-alloy cutting tools. Russ. J. Non-ferrous Metals 52, 311–318 (2011). https://doi.org/10.3103/S1067821211030138

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1067821211030138

Keywords

Navigation