Skip to main content
Log in

Electrochemical hydrogen storage of aligned multiwalled carbon nanotubes

  • Reports
  • Published:
Chinese Science Bulletin

Abstract

Hydrogen storage of aligned multi-walled carbon nanotubes (a-MWNTs), non-aligned MWNTs (n-MWNTs) and graphite electrodes are studied by the electrochemical measurements. The electrodes are prepared by mixing carbon nanotubes (CNTs), copper powder and PTFE binder in a weight ratio of 1: 5: 3 and compressing the mixture into porous nickel collector. The results show that the electrochemical hydrogen storage capacity of the a-MWNT electrode is up to 1625 mAh/g, corresponding to a high hydrogen storage of 5.7 wt%, which is 10 times that of graphite electrode and is 13 times that of n-MWNT electrode, suggesting that a-MWNTs are promising materials for electrochemical hydrogen storage.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Zou, Z., Ye, J., Sayama, K. et al., Direct splitting of water under visible light irradiation with an oxide semeiconductor photocatalyst, Nature, 2001, 414: 625–627.

    Article  PubMed  CAS  Google Scholar 

  2. Hamada, N., Sawada, S., Oshiyama, A., New one-dimensional conductors: Graphitic microtubules, Physics Review Letters, 1992, 68(10): 1579–1581.

    Article  CAS  Google Scholar 

  3. Iijima, S., Helical microtubules of graphitic carbon, Nature, 1991, 354: 56–58.

    Article  CAS  Google Scholar 

  4. Mintmire, J. W., Dunlap, B. I., White, C. T., Are fullerene tubules metallic, Physics Review Letters, 1992, 68(5): 631–634.

    Article  CAS  Google Scholar 

  5. Dillon, A. C., Jones, K. M., Bekkedahl, T. A. et al., Storage of hydrogen in single-walled carbon nanotubes, Nature, 1997, 386: 377–379.

    Article  CAS  Google Scholar 

  6. Nützenadel, C., Züttel, A., Chartouni, D. et al., Electrochemical storage of hydrogen in nanotube materials, Electrochemical and Solid-State Letters, 1999, 2(1): 30–32.

    Article  Google Scholar 

  7. Lee, S. M., Park, K. S., Choi, Y. C. et al., Hydrogen adsorption and storage in carbon nanotubes, Synthetic Metals, 2000, 113: 209–216.

    Article  CAS  Google Scholar 

  8. Qin, X., Gao, X. P., Yuan, H. T. et al., Electrochemical hydrogen storage of multiwalled carbon nanotubes, Electrochemical and Solid-State Letters, 2000, 3(12): 532–535.

    Article  CAS  Google Scholar 

  9. Rajalakshmi, N., Dhathathreyan, K. S., Govindaraj, A. et al., Electrochemical investigation of single-walled carbon nanotubes for hydrogen storage, Electrochimica Acta, 2000, 45: 4511–4515.

    Article  CAS  Google Scholar 

  10. Fazle Kibria, A. K. M., Mo, Y. H., Park, K. S. et al., Electrochemical hydrogen storage behaviors of CVD, AD and LA grown carbon nanotubes in KOH medium, International Journal of Hydrogen Energy, 2001, 26: 823–829.

    Article  CAS  Google Scholar 

  11. Züttel, A., Sudan, P., Mauron, Ph. et al., Hydrogen storage in carbon nanostructures, International Journal of Hydrogen Energy, 2002, 27: 203–212.

    Article  Google Scholar 

  12. Zhang, X. F., Cao, A. Y., Li, Y. H. et al., Chemical Physics Letters, 2002, 351: 183–188.

    Article  CAS  Google Scholar 

  13. Li, Y. H., Wang, S. G., Cao, A. Y. et al., Adsorption of fluoride from water by amorphous alumina supported on carbon nanotubes, Chemical Physics Letters, 2001, 350: 412–416.

    Article  CAS  Google Scholar 

  14. Zhang Dawei, Yuan Huatang, Wang Genshi et al., Study on electrochemical characteristics of Cu-coated hydrogen storage alloy, Journal of Functional Materials and Devices (in Chinese), 1998, 9(10): 167–174.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Donghui Hao.

About this article

Cite this article

Hao, D., Zhu, H., Zhang, X. et al. Electrochemical hydrogen storage of aligned multiwalled carbon nanotubes. Chin.Sci.Bull. 48, 538–542 (2003). https://doi.org/10.1360/03tb9115

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1360/03tb9115

Keywords

Navigation