Skip to main content
SpringerLink
Log in

Sensing adsorption kinetics through slip velocity measurements of polymer melts

  • Regular Article
  • Published:
The European Physical Journal E Aims and scope Submit manuscript

Abstract.

The evolution over time of the nonlinear slip behavior of a polydimethylsiloxane (PDMS) polymer melt on a weakly adsorbing surface made of short non-entangled PDMS chains densely end-grafted to the surface of a fused silica prism has been measured. The critical shear rate at which the melt enters the nonlinear slip regime has been shown to increase with time. The adsorption kinetics of the melt on the same surface has been determined independently using ellipsometry. We show that the evolution of slip can be explained by the slow adsorption of melt chains using the Brochard-de Gennes's model.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. Auvray, P.G. De Gennes, Europhys. Lett. 2, 647 (1986)

    Article  ADS  Google Scholar 

  2. P. Auroy, L. Auvray, L. Léger, J. Phys.: Condens. Matter 2, SA317 (1990)

    ADS  Google Scholar 

  3. P. Auroy, L. Auvray, L. Léger, Phys. Rev. Lett. 66, 719 (1991)

    Article  ADS  Google Scholar 

  4. P. Auroy, L. Auvray, L. Léger, Macromolecules 24, 2523 (1991)

    Article  ADS  Google Scholar 

  5. P. Auroy, Y. Mir, L. Auvray, Phys. Rev. Lett. 69, 93 (1992)

    Article  ADS  Google Scholar 

  6. Y. Mir, P. Auroy, L. Auvray, Phys. Rev. Lett. 75, 2863 (1995)

    Article  ADS  Google Scholar 

  7. P. Auroy, L. Auvray, Macromolecules 25, 4134 (1992)

    Article  ADS  Google Scholar 

  8. L. Auvray, P. Auroy, M. Cruz, J. Phys. I 2, 943 (1992)

    Google Scholar 

  9. L. Auvray, M. Cruz, P. Auroy, J. Phys. II 2, 1133 (1992)

    Google Scholar 

  10. J. Lal, L. Auvray, J. Phys. II 4, 2119 (1994)

    Google Scholar 

  11. L. De Vargas, O. Manero, Polym. Eng. Sci. 29, 1232 (1989)

    Article  Google Scholar 

  12. G. Chauveteau, A. Zaitoun, Basic rheological behavior of xanthan polysaccharide solutions in porous media: Effect of pore size and polymer concentration, in Proceedings of the First European Symposium on Enhanced Oil Recovery, Bournemouth, England (Society of Petroleum Engineers, Richardson, TX, 1981) pp. 197--212

  13. A. Cuenca, H. Bodiguel, Lab Chip 12, 1672 (2012)

    Article  Google Scholar 

  14. A. Cuenca, H. Bodiguel, Phys. Rev. Lett. 110, 108304 (2013)

    Article  ADS  Google Scholar 

  15. A.V. Ramamurthy, J. Rheol. 30, 337 (1986)

    Article  ADS  Google Scholar 

  16. J.M. Piau, N. El Kissi, J. Non-Newton. Fluid Mech. 54, 121 (1994)

    Article  Google Scholar 

  17. M.M. Denn, Annu. Rev. Fluid Mech. 33, 265 (2001)

    Article  ADS  Google Scholar 

  18. J. Cayer-Barrioz, D. Mazuyer, A. Tonck, E. Yamaguchi, Tribol. Lett. 32, 81 (2008)

    Article  Google Scholar 

  19. A. Dėdinaitė, Soft Matter 8, 273 (2012)

    Article  ADS  Google Scholar 

  20. C.L. Navier, Mémoire sur les lois du mouvement des fluides, in Mémoires de l'Académie des Sciences, Tome 6 (1827) pp. 389--440

  21. N.V. Churaev, V.D. Sobolev, A.N. Somov, J. Colloid Interface Sci. 97, 574 (1984)

    Article  ADS  Google Scholar 

  22. R. Pit, H. Hervet, L. Léger, Phys. Rev. Lett. 85, 980 (2000)

    Article  ADS  Google Scholar 

  23. V.S.J. Craig, C. Neto, D.R.M. Williams, Phys. Rev. Lett. 87, 0545041 (2001)

    Article  Google Scholar 

  24. T. Schmatko, H. Hervet, L. Léger, Phys. Rev. Lett. 94, 244501 (2005)

    Article  ADS  Google Scholar 

  25. C. Neto, D.R. Evans, E. Bonaccurso, H. Butt, V.S.J. Craig, Rep. Prog. Phys. 68, 2859 (2005)

    Article  ADS  Google Scholar 

  26. C. Cottin-Bizonne, S. Jurine, J. Baudry, J. Crassous, F. Restagno, E. Charlaix, Eur. Phys. J. E 9, 47 (2002)

    Article  Google Scholar 

  27. E. Secchi, S. Marbach, A. Niguès, D. Stein, A. Siria, L. Bocquet, Nature 537, 210 (2016)

    Article  ADS  Google Scholar 

  28. P.G. De Gennes, C. R. Acad. Sci. Paris 288, 219 (1979)

    MathSciNet  Google Scholar 

  29. S.-Q. Wang, P.P. Drda, Macromol. Chem. Phys. 198, 673 (1997)

    Article  Google Scholar 

  30. O. Bäumchen, R. Fetzer, K. Jacobs, Phys. Rev. Lett. 103, 247801 (2009)

    Article  ADS  Google Scholar 

  31. M. Hénot, E. Drockenmuller, L. Léger, F. Restagno, ACS Macro Lett. 7, 112 (2018)

    Article  Google Scholar 

  32. F.J. Lim, W.R. Schowalter, J. Rheol. 33, 1359 (1989)

    Article  ADS  Google Scholar 

  33. N.E. Kissi, J. Paiu, J. Non-Newton. Fluid Mech. 37, 55 (1990)

    Article  Google Scholar 

  34. S.G. Hatzikiriakos, J.M. Dealy, J. Rheol. 36, 703 (1992)

    Article  ADS  Google Scholar 

  35. K.B. Migler, H. Hervet, L. Léger, Phys. Rev. Lett. 70, 287 (1993)

    Article  ADS  Google Scholar 

  36. P.P. Drda, S.-Q. Wang, Phys. Rev. Lett. 75, 2698 (1995)

    Article  ADS  Google Scholar 

  37. S.-Q. Wang, P.A. Drda, Macromolecules 29, 2627 (1996)

    Article  ADS  Google Scholar 

  38. S.-Q. Wang, P.A. Drda, Macromolecules 29, 4115 (1996)

    Article  ADS  Google Scholar 

  39. E. Durliat, H. Hervet, L. Léger, Europhys. Lett. 38, 383 (1997)

    Article  ADS  Google Scholar 

  40. L. Léger, H. Hervet, G. Massey, E. Durliat, J. Phys.: Condens. Matter 9, 7719 (1997)

    ADS  Google Scholar 

  41. G. Massey, H. Hervet, L. Léger, Europhys. Lett. 43, 83 (1998)

    Article  ADS  Google Scholar 

  42. A. Chennevière, F. Cousin, F. Boué, E. Drockenmuller, K.R. Shull, L. Léger, F. Restagno, Macromolecules 49, 2348 (2016)

    Article  ADS  Google Scholar 

  43. M. Ilton, T. Salez, P.D. Fowler, M. Rivetti, M. Aly, M. Benzaquen, J.D. McGraw, E. Raphaël, K. Dalnoki-Veress, O. Bäumchen, Beyond the Navier-de Gennes Paradigm: Slip Inhibition on Ideal Substrates, arXiv:1708.03420 (2017)

  44. C. Gay, Eur. Phys. J. B 7, 251 (1999)

    Article  ADS  Google Scholar 

  45. F.J. Rielly, W.L. Price, SPE J. 17, 1097 (1961)

    Google Scholar 

  46. D.S. Kalika, M.M. Denn, J. Rheol. 31, 815 (1987)

    Article  ADS  Google Scholar 

  47. F. Brochard, P.G. De Gennes, Langmuir 8, 3033 (1992)

    Article  Google Scholar 

  48. A. Adjari, F. Brochard-Wyart, P.-G. de Gennes, L. Leibler, J.-L. Viovy, M. Rubinstein, Physica A: Stat. Mech. Appl. 204, 17 (1994)

    Article  ADS  Google Scholar 

  49. A. Ajdari, F. Brochard-Wyart, C. Gay, P.G. De Gennes, J. Phys. II 5, 491 (1995)

    Google Scholar 

  50. F. Brochard-Wyart, C. Gay, P.G. de Gennes, Macromolecules 29, 377 (1996)

    Article  ADS  Google Scholar 

  51. S. Jeong, S. Cho, J.M. Kim, C. Baig, J. Rheol. 61, 253 (2017)

    Article  ADS  Google Scholar 

  52. P. De Gennes, Scaling Concepts in Polymer Physics (Cornell University Press, 1979)

  53. L. Léger, H. Hervet, P. Auroy, E. Boucher, G. Massey, The reptation model: tests through diffusion measurements in linear polymer melts, in Rheology for Polymer Melt Processing, edited by J.-M. Piau, J.-F. Agassant, Rheology Series, Vol. 5 (Elsevier, 1996) pp. 1--16

  54. C. Cohen, D. Damiron, S.B. Dkhil, E. Drockenmuller, F. Restagno, L. Léger, J. Polym. Sci. Part A: Polym. Chem. 50, 1827 (2012)

    Article  ADS  Google Scholar 

  55. L.J. Fetters, D.J. Lohse, D. Richter, T.A. Witten, A. Zirkel, Macromolecules 27, 4639 (1994)

    Article  ADS  Google Scholar 

  56. C. Marzolin, P. Auroy, M. Deruelle, J.P. Folkers, L. Léger, A. Menelle, Macromolecules 34, 8694 (2001)

    Article  ADS  Google Scholar 

  57. M. Hénot, A. Chennevière, E. Drockenmuller, L. Léger, F. Restagno, Macromolecules 50, 5592 (2017)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Physique des Solides, CNRS, Univ. Paris-Sud, Université Paris-Saclay, 91405, Orsay Cedex, France

    Marceau Hénot, Liliane Léger & Frédéric Restagno

  2. Univ Lyon, Université Lyon 1, CNRS, Ingénierie des Matériaux Polymères, UMR 5223, F-69003, Lyon, France

    Eric Drockenmuller

Authors
  1. Marceau Hénot
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Eric Drockenmuller
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Liliane Léger
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Frédéric Restagno
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Frédéric Restagno.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hénot, M., Drockenmuller, E., Léger, L. et al. Sensing adsorption kinetics through slip velocity measurements of polymer melts. Eur. Phys. J. E 41, 83 (2018). https://doi.org/10.1140/epje/i2018-11697-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1140/epje/i2018-11697-4

Keywords

Search

Navigation