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Features of the Liquid-Phase Oxidation of Alkenes to Carbonyl Compounds in the Presence of Palladium Compounds

  • CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY
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Abstract

Some specific features in the liquid-phase oxidation of alkenes to ketones or aldehydes in the presence of palladium compounds (Wacker oxidation) are discussed. It is shown that selecting the appropriate conditions of the reaction (the effective compositions of the catalyst, the oxidizing agent, and solvent) allows the selective synthesis of either ketones or aldehydes from terminal alkenes and ketones from internal alkenes.

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Funding

This work was supported by the RF Ministry of Science and Higher Education as part of a state task for the Russian Academy of Sciences’ Boreskov Institute of Catalysis, project no. AAAA-A21-121011390007-7.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    L. L. Gogin & E. G. Zhizhina

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  1. L. L. Gogin
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  2. E. G. Zhizhina
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Correspondence to L. L. Gogin.

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Translated by M. Timoshinina

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Gogin, L.L., Zhizhina, E.G. Features of the Liquid-Phase Oxidation of Alkenes to Carbonyl Compounds in the Presence of Palladium Compounds. Catal. Ind. 13, 263–268 (2021). https://doi.org/10.1134/S2070050421030041

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  • DOI: https://doi.org/10.1134/S2070050421030041

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