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Ionic Ring-Opening Polymerization for the Synthesis of Star-Shaped Polymers

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Abstract

Features of ionic ring-opening polymerization for preparing star-shaped polymers are considered. The possibilities of controlled synthesis of star-shaped structures using cyclic monomers of various classes are demonstrated. Data on the preparation of star polymers using the approaches of “grafting from” a multifunctional initiator, “grafting through” a macromonomer, and “grafting to” a multifunctional coupling agent are systematized and summarized.

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Funding

This work was supported by the Government of the Russian Federation within the framework of the state support for Leading Scientific Schools, grant no. 14.W03.31.0022.

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Blokhin, A.N., Dudkina, M.M. & Tenkovtsev, A.V. Ionic Ring-Opening Polymerization for the Synthesis of Star-Shaped Polymers. Polym. Sci. Ser. C 64, 161–175 (2022). https://doi.org/10.1134/S1811238222700187

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