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Facile Fabrication of Hollow Molecularly Imprinted Polymer Particles with Multicore Structure via Miniemulsion Polymerization

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Abstract

The meticulous design on the internal structure of molecularly imprinted polymers particles has been widely concerned because of their unique recognition ability. In this study, we construct the molecularly imprinted polymers particles with hollow multicore structure for the specific recognition of bisphenol A via miniemulsion polymerization. The hollow multicore structure inside particles derives from the polymerization induced phase separation occurring within miniemulsion droplets. The formation mechanism of hollow multicore structure was analyzed in detail. The binding property of molecularly imprinted polymers was estimated by the binding kinetics, binding isotherm and special recognition. The molecularly imprinted polymers particles with hollow multicore structure exhibit remarkable binding kinetics because of low mass transfer resistance and desirable selectivity towards bisphenol A.

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Funding

This work was supported by the Science and Technology Research Project of Higher Education in Hebei Province (Grant no. QN2021036), the Science and Technology Research and Development Project of Handan City (Grant no. 21422111278), the National Natural Science Foundation of China (Grant no. 21902041).

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Authors and Affiliations

  1. College of Materials Science and Engineering, Hebei University of Engineering, 056038, Handan, China

    Zehu Wang, Zongqi Li & Xiying Fu

  2. Technology Innovation Center of Modified Plastics of Hebei Province, 056038, Handan, China

    Zehu Wang, Zongqi Li & Xiying Fu

  3. Academic Affairs Office, Hebei University of Engineering, 056038, Handan, China

    Ruiye Yan

Authors
  1. Zehu Wang
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  2. Zongqi Li
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  3. Ruiye Yan
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  4. Xiying Fu
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Corresponding authors

Correspondence to Zehu Wang or Ruiye Yan.

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Zehu Wang, Li, Z., Yan, R. et al. Facile Fabrication of Hollow Molecularly Imprinted Polymer Particles with Multicore Structure via Miniemulsion Polymerization. Polym. Sci. Ser. B 64, 479–486 (2022). https://doi.org/10.1134/S1560090422700269

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  • DOI: https://doi.org/10.1134/S1560090422700269

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