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Reactions of N-(2,2-dichloro-1-cyanoethenyl)-N′-methyl(phenyl)ureas with aliphatic amines

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Abstract

Novel derivatives of 3,3-dichloroprop-2-enenitrile containing methylurea or phenylurea fragments have been synthesized. The obtained N-(2,2-dichloro-1-cyanoethenyl)-N′-methyl(phenyl)ureas undergo intramolecular cyclization in the presence of triethylamine to form 4-(dichloromethylidene)-5-imino-1-methyl (phenyl)imidazolidin-2-ones. Reactions of N-(2,2-dichloro-1-cyanoethenyl)-N′-methylurea with aliphatic amines have afforded 4-(alkylamino)-4-(dichloromethyl)-5-imino-1-methylimidazolidin-2-ones.

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Authors and Affiliations

  1. Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 1, Kiev, 02660, Ukraine

    S. A. Chumachenko, M. V. Kachaeva, O. V. Shablykin & V. S. Brovarets

  2. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    E. B. Rusanov

Authors
  1. S. A. Chumachenko
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  2. M. V. Kachaeva
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  3. O. V. Shablykin
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  4. E. B. Rusanov
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  5. V. S. Brovarets
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Corresponding author

Correspondence to V. S. Brovarets.

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Original Russian Text © S.A. Chumachenko, M.V. Kachaeva, O.V. Shablykin, E.B. Rusanov, V.S. Brovarets, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 5, pp. 795–800.

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Chumachenko, S.A., Kachaeva, M.V., Shablykin, O.V. et al. Reactions of N-(2,2-dichloro-1-cyanoethenyl)-N′-methyl(phenyl)ureas with aliphatic amines. Russ J Gen Chem 87, 985–990 (2017). https://doi.org/10.1134/S1070363217050164

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  • DOI: https://doi.org/10.1134/S1070363217050164

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