Abstract
The extraction properties of 2,3-bis(diphenylphosphinyl)buta-1,3-diene (L1) and 3,4-bis(diphenylphosphinyl)-2,5-dimethylhexa-2,4-diene (L2) with respect to f elements are studied for the extraction of microquantities of U(VI) and Th(IV) from HNO3 solutions with solutions of the extracting agents in 1,2-dichloroethane. The introduction of methyl groups into the 1,3-butadiene carbon skeleton of bis(phosphine oxide) increases the efficiency of U(VI) extraction. The coordination properties of bis(phosphine oxides) L1 and L2 are studied for the complexes with uranyl nitrate. The crystal structures of bis(phosphine oxide) L1·THF (CIF file CCDC no. 2107403) and its complexes with uranyl nitrate I and II (CIF files CCDC nos. 2107404 and 2107405, respectively) are confirmed by X-ray diffraction data.
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Notes
The signal of the left part of the p-C coalesces with the left part of the o-C doublet.
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ACKNOWLEDGMENTS
Elemental analyses and NMR, IR, and Raman spectra recording were supported by the Ministry of Science and Higher Education of the Russian Federation using scientific equipment of the Center for Molecular Structure Investigation at the Institute of Organoelement Compounds, Russian Academy of Sciences.
Funding
This work was supported by the Russian Science Foundation, project no. 20-13-00329.
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Translated by E. Yablonskaya
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Brel, V.K., Artyushin, O.I., Morgalyuk, V.P. et al. Extraction and Coordination Properties of 2,3-Bis(diphenylphosphinyl)buta-1,3-diene and 3,4-Bis(diphenylphosphinyl)-2,5-dimethylhexa-2,4-diene. Russ J Coord Chem 48, 201–209 (2022). https://doi.org/10.1134/S1070328422040017
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DOI: https://doi.org/10.1134/S1070328422040017