Skip to main content
Log in

Extraction and Coordination Properties of 2,3-Bis(diphenylphosphinyl)buta-1,3-diene and 3,4-Bis(diphenylphosphinyl)-2,5-dimethylhexa-2,4-diene

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The extraction properties of 2,3-bis(diphenylphosphinyl)buta-1,3-diene (L1) and 3,4-bis(diphenylphosphinyl)-2,5-dimethylhexa-2,4-diene (L2) with respect to f elements are studied for the extraction of microquantities of U(VI) and Th(IV) from HNO3 solutions with solutions of the extracting agents in 1,2-dichloroethane. The introduction of methyl groups into the 1,3-butadiene carbon skeleton of bis(phosphine oxide) increases the efficiency of U(VI) extraction. The coordination properties of bis(phosphine oxides) L1 and L2 are studied for the complexes with uranyl nitrate. The crystal structures of bis(phosphine oxide) L1·THF (CIF file CCDC no. 2107403) and its complexes with uranyl nitrate I and II (CIF files CCDC nos. 2107404 and 2107405, respectively) are confirmed by X-ray diffraction data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.

Similar content being viewed by others

Notes

  1. The signal of the left part of the p-C coalesces with the left part of the o-C doublet.

REFERENCES

  1. Demkowicz, S., Rachon, J., Daśko, M., and Kozak, W., RSC Adv., 2016, vol. 6, p. 7101.

    Article  CAS  Google Scholar 

  2. Ni, H., Chan, W.-L., and Lu, Y., Chem. Rev., 2018, vol. 118, p. 9344.

    Article  CAS  Google Scholar 

  3. Baumgartner, T. and Réau, R., Chem. Rev., 2006, vol. 106, p. 4681.

    Article  CAS  Google Scholar 

  4. Rozen, A.M. and Krupnov, B.V., Russ. Chem. Rev., 1996, vol. 65, p. 973.

    Article  Google Scholar 

  5. Myasoedov, B.F. and Kalmykov, S.N., Mendeleev Commun., 2015, vol. 25, no. 5, p. 319.

    Article  CAS  Google Scholar 

  6. Mathew, M. and Palenik, G.J., Inorg. Chim. Acta, 1971, vol. 5, p. 573.

    Article  CAS  Google Scholar 

  7. Harrison, P.G., Sharpe, N.W., Pelizzi, C., et al., Dalton Trans., 1983, p. 921.

  8. Pettinari, C., Marchetti, F., Cingolani, A., et al., Inorg. Chim. Acta, 1991, vol. 312, p. 125.

    Article  Google Scholar 

  9. Spichal, Z., Necas, M., and Pinkas, J., Inorg. Chem., 2005, vol. 44, p. 2074.

    Article  CAS  Google Scholar 

  10. Al-Resayes, S.I., Hitchcock, P.B., and Nixon, J.F., Chem. Commun., 1991, p. 78.

  11. Beagley, B., Dyer, G., McAuliffe, C.A., et al., Chem. Commun., 1991, p. 965.

  12. Jin, Q.-H., Wu, J.-Q., Zhang, Y.-Y., et al., NCS, 2009, vol. 224, p. 428.

    CAS  Google Scholar 

  13. Lees, A.M.J. and Platt, A.W.G., Inorg. Chem., 2003, vol. 42, p. 4673.

    Article  CAS  Google Scholar 

  14. Spichal, Z., Necas, M., and Pinkas, J., Inorg. Chem., 2005, vol. 44, p. 2070.

    Article  Google Scholar 

  15. Spichal, Z., Petricek, V., Pinkas, J., and Necas, M., Polyhedron, 2008, vol. 27, p. 283.

    Article  CAS  Google Scholar 

  16. Spichal, Z., Necas, M., Pinkas, J., and Zdrahal, Z., Polyhedron, 2006, vol. 25, p. 2006.

    Article  Google Scholar 

  17. Berezin, A.S., Davydova, M.P., Bagryanskaya, I.Yu., et al., Inorg. Chem. Commun., 2019, vol. 107, p. 107473.

    Article  CAS  Google Scholar 

  18. Artem’ev, A.V., Davydova, M.P., et al., Dalton Trans., 2019, vol. 48, no. 43, p. 16448.

    Article  Google Scholar 

  19. Pollok, T. and Schmidbaur, H., Tetrahedron Lett., 1987, vol. 28, p. 1085.

    Article  CAS  Google Scholar 

  20. Chen, F., Xia, Y., Lin, R., et al., Org. Lett., 2019, vol. 21, p. 579.

    Article  CAS  Google Scholar 

  21. Sheldrick, G.M., Acta Crystrallogr., Sect. A: Found. Adv., 2015, vol. 71, p. 3.

    Article  Google Scholar 

  22. Spek, A.L., Acta Crystrallogr., Sect. C: Struct. Chem., 2015, vol. 71, p. 9.

    Article  CAS  Google Scholar 

  23. Sheldrick, G.M., Acta Crystrallogr., Sect. C: Struct. Chem., 2015, vol. 71, p. 3.

    Google Scholar 

  24. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, p. 339.

    Article  CAS  Google Scholar 

  25. Blatov, V.A., Shevchenko, A.P., and Proserpio, D.M., Cryst. Growth Des., 2014, vol. 14, p. 3576.

    Article  CAS  Google Scholar 

  26. Turanov, A.N., Karandashev, V.K., Kharitonov, A.V., et al., Solvent Extr. Ion Exch., 2000, vol. 18, p. 1109.

    Article  CAS  Google Scholar 

  27. Gillam, A.E., Stern, E.S., and Timmons, C.J., Gillam and Stern’s Introduction to Elektronic Absorption Spectroskopy in Organic Chemistry, London: Edward Arnold, 1970.

    Google Scholar 

  28. Ratovskii, G.V., Sergienko, L.M., Brel, V.K., et al., Zh. Obshch. Khim., 1983, vol. 53, p. 1186.

    CAS  Google Scholar 

  29. Berezin, A.S., Samsonenko, D.G., Brel, V., and Artem’ev, A.V., Dalton Trans., 2018, vol. 47, p. 7306.

    Article  CAS  Google Scholar 

  30. Davydova, M.P., Bauer, I.A., Brel, V.K., et al., Eur. J. Inorg. Chem., 2020, p. 695.

  31. Serezhkina, L.B. and Vologzhanina, A.V., Acta Crystallogr., Sect. B: Struct. Sci. Cryst. Eng. Mater., 2012, vol. 68, p. 305.

    Article  Google Scholar 

  32. Zerezhkin, A.N. and Savchenkov, A.V., Cryst. Growth Des., 2015, vol. 15, p. 2878.

    Article  Google Scholar 

  33. Zerezhkin, V.N. and Savchenkov, A.V., Cryst. Growth Des., 2020, vol. 20, p. 1997.

    Article  Google Scholar 

  34. Vologzhanin, A.V., Ushakov, I.E., and Korlyukov, A.A., Int. J. Mol. Sci., 2021, vol. 21, p. 8970.

    Article  Google Scholar 

  35. Savchenkov, A.V., Klepov, V.V., Vologzhanina, A.B., et al., CrystEngComm, 2015, vol. 17, p. 740.

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

Elemental analyses and NMR, IR, and Raman spectra recording were supported by the Ministry of Science and Higher Education of the Russian Federation using scientific equipment of the Center for Molecular Structure Investigation at the Institute of Organoelement Compounds, Russian Academy of Sciences.

Funding

This work was supported by the Russian Science Foundation, project no. 20-13-00329.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. K. Brel.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by E. Yablonskaya

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Brel, V.K., Artyushin, O.I., Morgalyuk, V.P. et al. Extraction and Coordination Properties of 2,3-Bis(diphenylphosphinyl)buta-1,3-diene and 3,4-Bis(diphenylphosphinyl)-2,5-dimethylhexa-2,4-diene. Russ J Coord Chem 48, 201–209 (2022). https://doi.org/10.1134/S1070328422040017

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328422040017

Keywords:

Navigation