Skip to main content
SpringerLink
Log in

Molar absorption coefficient of ozone in aqueous solutions

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

The value of the molar absorption coefficient of ozone in aqueous solutions (2992 ± 71 M–1 cm–1 at 260 nm) is found based on the determination of ozone concentration by iodometry. This value is confirmed by the results of determination of O3 concentration by reaction with the bromide ion and virtually coincides with the maximum absorption coefficient of ozone in the gas phase in the region the Hartley band. In the determinations of ozone concentration in aqueous solutions by direct spectrophotometry, we recommend the value of the molar absorption coefficient ε(О3)260 = 3000 M–1 cm–1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lunin, V.V., Popovich, M.P., and Tkachenko, S.N., Fizicheskaya khimiya ozona (Physical Chemistry of Ozone), Moscow Mosk. Gos. Univ., 1998.

    Google Scholar 

  2. Orphal, J., J. Photochem. Photobiol., A, 2003, vol. 157, no. 2–3, p. 185.

    Article  CAS  Google Scholar 

  3. Gorshelev, V., Serdyuchenko, A., Weber, M., Chehade, W., and Burrows, J.P., Atmos. Meas. Tech., vol. 7, no. 2, p. 609.

  4. Atkinson, R., Baulch, D.L., Cox, R.A., Crowley, J.N., Hampson, R.F., Hynes, R.G., Jenkin, M.E., Rossi, M.J., and Troe, J., Atmos. Chem. Phys., 2004, vol. 4, p. 1461.

    Article  CAS  Google Scholar 

  5. Sander, S.P., Abbatt, J., Barker, J.R., Burkholder, J.B., Friedl, R.R., Golden, D.M., Huie, R.E., Kolb, C.E., Kurylo, M.J., Moortgat, G.K., Orkin, V.L., and Wine, P.H., Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation no. 17, Pasadena JPL Publication 10–6, Jet Propulsion Laboratory, 2011.

    Google Scholar 

  6. Hoigné, J. and Bader, H., Water Res., 1976, vol. 10, no. 5, p. 377.

    Article  Google Scholar 

  7. Bader, H. and Hoigné, J., in Ozonation Manual for Water and Wastewater Treatment, Masschelein, W.J., Ed., Chichester: Wiley, 1982, p. 169.

  8. Bader, H. and Hoigné, J., Ozone Sci. Eng., 1982, vol. 4, no. 4, p. 169.

    Article  CAS  Google Scholar 

  9. Kilpatrick, M.L., Herrick, C.C., and Kilpatrick, M., J. Am. Chem. Soc., 1956, vol. 78, no. 9, p. 1784.

    Article  CAS  Google Scholar 

  10. Gilbert, E. and Hoigné, J., Gas-Wasserfach, Wasser/ Abwasser, 1983, vol. 124, no. 11, p. 527.

    CAS  Google Scholar 

  11. Nemes, A., Fabian, I., and Gordon, G., Ozone: Sci. Eng., 2000, vol. 22, no. 3, p. 287.

    Article  CAS  Google Scholar 

  12. Hoigné, J., in The Handbook of Environmental Chemistry, vol. 5, part C: Quality and Treatment of Drinking Water II, Hrubec, J., Ed., Berlin–Heidelberg: Springer, 1998, p. 83.

  13. von Sonntag, C. and von Gunten, U., Chemistry of Ozone in Water and Wastewater Treatment: From Basic Principles to Applications, London IWA, 2012.

    Google Scholar 

  14. Jans, U. and Hoigné, J., Ozone Sci. Eng., 1998, vol. 20, no. 1, p. 67.

    Article  CAS  Google Scholar 

  15. Jans, U. and Hoigné, J., Atmos. Environ., 2000, vol. 34, no. 7, p. 1069.

    Article  CAS  Google Scholar 

  16. Hart, E.J., Sehested, K., and Holcman, J., Anal. Chem., 1983, vol. 55, no. 1, p. 46.

    Article  CAS  Google Scholar 

  17. Forni, L., Bahnemann, D., and Hart, E.J., J. Phys. Chem., 1982, vol. 86, no. 2, p. 255.

    Article  CAS  Google Scholar 

  18. Chiou, C.-F., Marinas, B.J., and Adams, J.Q., Ozone Sci. Eng., 1995, vol. 17, no. 3, p. 329.

    Article  CAS  Google Scholar 

  19. Taube, H., Trans. Faraday Soc., 1957, vol. 53, no. 0, p. 656.

    Article  CAS  Google Scholar 

  20. Ferre-Aracil, J., Cardona, S.C., and Navarro-Laboulais, J., Ozone Sci. Eng., 2015, vol. 37, no. 2, p. 106.

    Article  CAS  Google Scholar 

  21. GOST (State Standard) 18301-72: Drinking Water. Methods of Determination of Ozone Residual Content, Moscow: Gosstandart SSSR, 1972.

    Google Scholar 

  22. Masschelein, W.J., Blaich, L., Langlais, B., Thieben, E., Bell, J., and Reading, A., Ozone Sci. Eng., 1998, vol. 20, no. 6, p. 433.

    Article  CAS  Google Scholar 

  23. Alekseev, V.N., Kolichestvennyi analiz (Quantitative Analysis) Moscow: Mir, 1969, 2nd ed.

    Google Scholar 

  24. Abel, E., Monatsh. Chem., 1958, vol. 89, no. 2, p. 313.

    Article  CAS  Google Scholar 

  25. Kolthoff, I.M., Belcher, R., Stenger, V.A., and Matsuyama, G., Volumetric Analysis, vol. 3 Titration Methods: Oxidation–Reduction Reactions, New York: Interscience, 1957.

    Google Scholar 

  26. Razumovskii, S.D. and Zaikov, G.E., Ozon i ego reaktsii s organicheskimi soedineniyami (kinetika i mekhanizm) (Ozone and Its Reactions with Organic Compounds: Kinetics and Mechanism), Moscow Nauka, 1974.

    Google Scholar 

  27. Liu, Q., Schurter, L.M., Muller, C.E., Aloisio, S., Francisco, J.S., and Margerum, D.W., Inorg. Chem., 2001, vol. 40, no. 17, p. 4436.

    Article  CAS  Google Scholar 

  28. Haag, W.R. and Hoigné, J., Environ. Sci. Technol., vol. 17, no. 5, p. 261.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    A. V. Levanov, A. N. Tyutyunnik, E. E. Antipenko & V. V. Lunin

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    O. Ya. Isaikina & V. V. Lunin

Authors
  1. A. V. Levanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. Ya. Isaikina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. N. Tyutyunnik
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. E. Antipenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. V. Lunin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Levanov.

Additional information

Original Russian Text © A.V. Levanov, O.Ya. Isaikina, A.N. Tyutyunnik, E.E. Antipenko, V.V. Lunin, 2016, published in Zhurnal Analiticheskoi Khimii, 2016, Vol. 71, No. 6, pp. 577–581.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Levanov, A.V., Isaikina, O.Y., Tyutyunnik, A.N. et al. Molar absorption coefficient of ozone in aqueous solutions. J Anal Chem 71, 549–553 (2016). https://doi.org/10.1134/S1061934816060083

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934816060083

Keywords

Search

Navigation