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Calculation of the Frequencies of Vibration-Rotation Transitions of the H36Cl Molecule

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Abstract

Dunham coefficients Ymj of the H36Cl molecule are calculated based on previously determined mass-independent spectroscopic parameters Umj, \(\Delta _{{mj}}^{A}\) and \(\Delta _{{mj}}^{B}\). Pure rotational and vibration–rotation transitions of the (1–0), (2–0), and (3–0) bands are presented up to Jmax = 25 for the first time. The calculated and observed line positions are compared for the fundamental and first overtone bands. The RKR potential of the H36Cl molecule is retrieved.

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Funding

The work by S.N. Mikhailenko was supported by the Ministry of Science and Higher Education of the Russian Federation (V.E. Zuev Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences).

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  1. Industrial University of Tyumen, 625000, Tyumen, Russia

    T. I. Velichko

  2. V.E. Zuev Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences, 634055, Tomsk, Russia

    S. N. Mikhailenko

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  1. T. I. Velichko
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Translated by O. Ponomareva

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Velichko, T.I., Mikhailenko, S.N. Calculation of the Frequencies of Vibration-Rotation Transitions of the H36Cl Molecule. Atmos Ocean Opt 35, 626–633 (2022). https://doi.org/10.1134/S1024856022060264

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