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Epoxy oligomers based on eugenol cyclotriphosphazene derivatives

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Abstract

Oligomers of hexakis(4-allyl-2-methoxyphenoxy)cyclotriphosphazene have been synthesized and their molecular structure studied by X-ray and NMR analysis. The nonplanar character of a phosphazene cycle is established, and the bond lengths P-N and valence angles N-P-N are shown to change in narrow ranges (1.5771–1.5894 Å and 117.80°–118.37°, respectively). During epoxidation of hexakis(4-allyl-2-methoxyphenoxy)cyclotriphosphazene by m-chloroperbenzoic acid or peracetic acid, in addition to hexaepoxy derivatives, the corresponding dimer is formed due to partial intermolecular interaction of epoxy groups.

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 125047, Russia

    V. V. Kireev, N. S. Bredov & Yu. V. Bilichenko

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    K. A. Lysenko

  3. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    R. S. Borisov

  4. ZAO VladMiVa, ul. Michurina 39a, Belgorod, 308002, Russia

    V. P. Chuev

Authors
  1. V. V. Kireev
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  2. N. S. Bredov
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  3. Yu. V. Bilichenko
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  4. K. A. Lysenko
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  5. R. S. Borisov
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  6. V. P. Chuev
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Corresponding author

Correspondence to V. V. Kireev.

Additional information

Original Russian Text © V.V. Kireev, N.S. Bredov, Yu.V. Bilichenko, K.A. Lysenko, R.S. Borisov, V.P. Chuev, 2008, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2008, Vol. 50, No. 6, pp. 951–958.

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Kireev, V.V., Bredov, N.S., Bilichenko, Y.V. et al. Epoxy oligomers based on eugenol cyclotriphosphazene derivatives. Polym. Sci. Ser. A 50, 609–615 (2008). https://doi.org/10.1134/S0965545X08060035

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  • DOI: https://doi.org/10.1134/S0965545X08060035

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