Abstract
We investigated mantle eclogite and garnet pyroxenite xenoliths from the V. Grib kimberlite located in the Arkhangelsk diamond province. The eclogites in the lithospheric mantle beneath the Arkhangelsk province were strongly modified by metasomatic processes, which totally obliterated the primary features of protolith. Detailed studies of the xenoliths allowed us to distinguish the following metasomatic events: (1) early mantle metasomatism and (2) interaction with kimberlite melt. During the multiple early mantle metasomatism, primary clinopyroxene and garnet were replaced by metasomatic clinopyroxene, garnet, amphibole, calcite, and phlogopite under the influence of carbonated ultramafic melts. The impact of kimberlite melt caused the dissolution and recrystallisation of solid-phase inclusions and formation of melt pockets consisting of serpentine, chlorite, carbonate, spinel, perovskite, amphibole, recrystallized garnet, and clinopyroxene. En route to the surface in kimberlite melt, the xenoliths were disintegrated and primary garnet and clinopyroxene were metasomatized with increasing Ti and Cr contents, up to formation of high-Cr megacrysts. The garnet pyroxenites are represented by high-Ca, low-Mg and low-Ca, high-Mg types. It is shown that the high-Ca, low-Mg garnet pyroxenites can be the final products of the eclogite xenolith metasomatism by carbonated ultramafic melts. The low-Ca, high-Mg pyroxenites were derived through the interaction of a partial eclogite melt with depleted peridotites.
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In supplementary materials to the Russian and English on-line versions on sites https://elibrary.ru/ and http://link.springer.com/ respectively report: ESM_1.pdf (Supplementary 1)—Description of analytical methods; ESM_2.xlsx (Supplementary 2)—Major-oxide composition of minerals; ESM_3.xlsx (Supplementary 3)—Geochemical tables: trace-element composition of minerals and whole rock; ESM_4.pdf (Supplementary 4)—Additional figures.
REFERENCES
Arzamastsev, A.A. and Fu-Yuan Wu, U–Pb geochronology and Sr–Nd isotopic systematics of minerals from the ultrabasic-alkaline massifs of the Kola Province, Petrology, 2014, vol. 22, no. 5, pp. 462–479.
Aulbach, S., Creaser, R.A., Pearson, N.J., et al., Sulfide and whole rock Re-Os systematics of eclogite and pyroxenite xenoliths from the Slave Craton, Canada, Earth Planet. Sci. Lett., 2009, vol. 283, pp. 48–58. https://doi.org/10.1016/j.epsl.2009.03.023
Aulbach, S., Viljoen, K.S., and Gerdes, A., Diamondiferous and barren eclogites and pyroxenites from the western Kaapvaal Craton record subduction processes and mantle metasomatism, respectively, Lithos, 2020a. https://doi.org/10.1016/j.lithos.2020.105588
Aulbach, S., Massuyeau, M., Garber, J.M., et al., Ultramafic carbonated melt- and auto-metasomatism in mantle eclogites: compositional effects and geophysical consequences, Geochem. Geophys. Geosyst., 2020b. https://doi.org/10.1029/2019GC008774
Beard, A.D., Downes, H., Hegner, E., and Sablukov, S.M., Geochemistry and mineralogy of kimberlites from the Arkhangelsk region, NW Russia: evidence for transitional kimberlite magma types, Lithos, 2000, vol. 51, nos. 1–2, pp. 47–73.
Bogdanova, S.V. and Gorbatschev, R., Europe|East European Craton, Earth Systems and Environmental Sciences (Elsevier, 2016), pp. 1–18.
Bussweiler, Y., Polymineralic inclusions in megacrysts as proxies for kimberlite melt evolution—a review, Minerals, 2019, vol. 9, no. 9, p. 530.
Carswell, D.A., Primary and secondary phlogopites and clinopyroxenes in garnet lherzolite xenoliths, Physics and Chemistry of the Earth (Pergamon Press Ltd, 1975), pp. 417–429.
Coleman, R.G., Lee, D.E., Beatty, L.B., and Brannock, W.W., Eclogites and eclogites: their differences and similarities, Geol. Soc. Am. Bull., 1965, vol. 76, pp. 483–508.
Czas, J., Stachel, T., Pearson, D.G., et al., Diamond brecciation and annealing accompanying major metasomatism in eclogite xenoliths from the Sask Craton, Canada, Mineral. Petrol., 2018, vol. 112, pp. 311–423.
De Stefano, A., Kopylova, M.G., Cartigny, P., and Afanasiev, V., Diamonds and eclogites of the Jericho kimberlite (Northern Canada), Contrib. Mineral. Petrol., 2009, vol. 158, pp. 295–315.
Giuliani, A., Soltys, A., Phillips, D., et al., The final stages of kimberlite petrogenesis: petrography, mineral chemistry, melt inclusions and Sr–C–O isotope geochemistry of the, Chem. Geol., 2017, vol. 455, pp. 342–456.
Gréau, Y., Huang, J.X., Griffin, W.L., et al., Type I eclogites from Roberts Victor kimberlites: products of extensive mantle metasomatism, Geochim. Cosmochim. Acta, 2011, vol. 75, pp. 6927–6954. https://doi.org/10.1016/j.gca.2011.08.035
Griffin, W.L., Shee, S.R., Ryan, C.G., et al., Harzburgite to lherzolite and back again: metasomatic processes in ultramafic xenoliths from the Wesselton, Contrib. Mineral. Petrol., 1999, vol. 134, pp. 232–250.
Griffin, W.L., O’Reilly, S.Y., Abe, N., et al., The origin and evolution of Archean lithospheric mantle, Precambrian Res., 2003, vol. 127, pp. 19–41.
Griffin, W.L. and O’Reilly, S.Y., Cratonic lithospheric mantle: is anything subducted?, Episodes, 2007, vol. 30, pp. 43–53.
Hawthorne, F.C., Oberti, R., Harlow, G.E., et al., Ima report: nomenclature of the amphibole supergroup, Am. Mineral., 2012, vol. 97, nos. 11–12, pp. 2031–2048.
Herzberg, C., Origin of high-mg bimineralic eclogite xenoliths in kimberlite: a comment on a paper by aulbach and arndt, Earth Planet. Sci. Lett., 2019, vol. 510, pp. 231–233.
Horodyskyj, U.N., Lee, C.T.A., and Ducea, M.N., Similarities between Archean high-Mgo eclogites and Phanerozoic arc-eclogite cumulates and the role of arcs in Archean continent formation, Earth Planet. Sci. Lett., 2007, vol. 256, nos. 3–4, pp. 510–520.
Jacob, D.E., Nature and origin of eclogite xenoliths from kimberlites, Lithos, 2004, vol. 77, pp. 295–316.
Karandashev V.K., Khvostikov V.A., Nosenko, S.Yu., and Burmii, Zh.P., Use of highly enriched stable isotopes in mass analysis of rock samples, grounds, soils, and bottom deposits by induction coupled plasma mass spectrometry, Zavodskaya Laboratoriya. Diagnostika Materialov, 2016, vol. 82, no. 7, pp. 6–15.
Kargin, A.V., Sazonova, L.V., Nosova, A.A., and Tretyachenko, V.V., Composition of garnet and clinopyroxene in peridotite xenoliths from the Grib kimberlite pipe, Arkhangelsk diamond province, Russia: evidence for mantle metasomatism associated with kimberlite melts, Lithos, 2016, vol. 262, pp. 442–455.
Kargin, A.V., Sazonova, L.V., Nosova, A.A., et al., Cr-rich clinopyroxene megacrysts from the Grib kimberlite, Arkhangelsk province, Russia: relation to clinopyroxene–phlogopite xenoliths and evidence for mantle metasomatism by kimberlite melts, Lithos, 2017, vol. 292-293, pp. 34–38. https://doi.org/10.1016/j.gsf.2016.03.001
Kiseeva, E.S., Kamenetsky, V.S., Yaxley, G.M., and Shee, S.R., Mantle melting versus mantle metasomatism - “the” chicken or the “egg"" dilemma, Chem. Geol., 2017, vol. 455, pp. 120–130.
Kononova, V.A., Golubeva, Y.Y., Bogatikov, O.A., and Kargin, A.V., Diamond resource potential of kimberlites from the Zimny Bereg field, Arkhangel’sk oblast, Geol. Ore Deposits, 2007, vol. 49, pp. 421–441.
Koreshkova, M.Yu., Levskii, L.K., and Ivanikov, V.V., Petrology of a lower crustal xenolith suite from dikes and explosion pipes of the Kandalaksha graben, Petrology, 2001, vol. 9, no. 1, pp. 79–96.
Korolev, N., Nikitina, L.P., Goncharov, A., et al., Three types of mantle eclogite from two layers of oceanic crust: a key case of metasomataically-aided transformation of low-to-high-magnesian eclogite, J. Petrol., 2021, vol. 62, pp. 1–38. https://doi.org/10.1007/s00710-020-00704-0
Kostrovitsky, S.I., Malkovets, V.G., Verichev, E.M., et al., Megacrysts from the Grib kimberlite pipe (Arkhangelsk province, Russia), Lithos, 2004, vol. 77, nos. 1–4, pp. 511–523.
Kutolin, V.A. and Frolova, V.M., Petrology of ultrabasic inclusions from basalts of Minusa and Transbaikalian regions (Siberia, USSR), Contrib. Mineral. Petrol., 1970, vol. 29, no. 2, pp. 163–179.
Larionova, Yu.O., Sazonova, L.V., Lebedeva, N.M., et al., Kimberlite age in the Arkhangelsk Province, Russia: isotopic geochronologic Rb–Sr and 40Ar/39Ar and mineralogical data on phlogopite, Petrology, 2016, vol. 24, no. 4, pp. 562–593. https://doi.org/10.1134/S0869591116040020
Lebedeva, N.M., Nosova, A.A., Kargin, A.V., and Sazonova, L.V., Multi-stage evolution of kimberlite melt as inferred from inclusions in garnet megacrysts in the Grib kimberlite (Arkhangelsk region, Russia), Mineral. Petrol., 2020a, vol. 114, pp. 273–288. https://doi.org/10.1007/s00710-020-00704-0
Lebedeva, N.M., Nosova, A.A., Kargin, A.V., et al., Sr–Nd–O isotopic evidence of variable sources of mantle metasomatism in the subcratonic lithospheric mantle beneath the Grib kimberlite, northwestern Russia, Lithos, 2020b, vol. 376–377, 105779. https://doi.org/10.1016/j.lithos.2020.105779
Le Roex, A., Tinguely, C., and Gregoire, M., Eclogite and garnet pyroxenite xenoliths from kimberlites emplaced along the southern margin of the Kaapvaal Craton, Southern Africa: mantle or lower crustal fragments?, J. Petrol., 2020, vol. 61. https://doi.org/10.1093/petrology/egaa040
Luo, Y. and Korenaga, J., Efficiency of eclogite removal from continental lithosphere and its implications for cratonic diamonds, Geology, 2021, vol. 49, pp. 438–441. https://doi.org/10.1130/G48204.1
Malkovets, V., Taylor, L., Griffin, W., et al., Eclogites from the Grib kimberlite pipe, Arkhangelsk, Russia, 8th International Kimberlite Conference, Abstract, Canada, 2003 (Elsevier, Victoria, 2003), p. 5.
Mallik, A. and Dasgupta, R., Reaction between MORB-eclogite derived melts and fertile peridotite and generation of ocean island basalts, Earth Planet. Sci. Lett., 2012, vol. 329–330, pp. 97–108. https://doi.org/10.1016/j.epsl.2012.02.007
Mandler, B.E. and Grove, T.L., Controls on the stability and composition of amphibole in the Earth’s mantle, Contrib. Mineral. Petrol., 2016, vol. 171, no. 8, pp. 1–20.
Mattey, D., Lowry, D., and Macpherson, C., Oxygen isotope compositions of mantle peridotite, Earth Planet. Sci. Lett., 1994, vol. 128, pp. 231–241.
Mikhailenko, D., Golovin, A., Korsakov, A., et al., Metasomatic evolution of coesite-bearing diamondiferous eclogite from the Udachnaya kimberlite, Minerals, 2020, vol. 10. https://doi.org/10.3390/min10040383
Misra, K.C., Anand, M., Taylor, L.A., and Sobolev, N.V., Multi-stage metasomatism of diamondiferous eclogite xenoliths from the Udachnaya kimberlite pipe, Yakutia, Siberia, Contrib. Mineral. Petrol., 2004, vol. 146, no. 6, pp. 696–714.
Morimoto, N., Nomenclature of pyroxenes, Mineral. Petrol., 1988, vol. 39, no. 1, pp. 55–76.
Niida, K. and Green, D.H., Stability and chemical composition of pargasitic amphibole in MORB pyrolite under upper mantle conditions, Contrib. Mineral. Petrol., 1999, vol. 135, no. 1, pp. 18–40.
Nosova, A.A., Dubinina, E.O., Sazonova, L.V., et al., Geochemistry and oxygen isotopic composition of olivine in kimberlites from the Arkhangelsk province: contribution of mantle metasomatism, Petrology, 2017, vol. 25, pp. 150–180. https://doi.org/10.1007/978-3-642-28394-9_12
Pearson, D.G., Snyder, G.A., Shirey, S.B., et al., Archaean Re-Os age for Siberian eclogites and constraints on Archaean tectonics, Nature, 1995a, vol. 374, no. 6524, pp. 711–713.
Pearson, D.G., Shirey, S.B., Carlson, R.W., et al., Re-Os, Sm-Nd, and Rb-Sr isotope evidence for thick Archaean lithospheric mantle beneath the Siberian craton modified by multistage metasomatism, Geochim. Cosmochim. Acta, 1995b, vol. 59, no. 5, pp. 959–977.
Perchuk, A.L., Yapaskurt, V.O., and Davydova, V.V., Melt inclusions in eclogite garnet: experimental study of natural processes, Russ. Geol. Geophys., 2008, vol. 49, no. 5, pp. 310–312.
Pivin, M., Féménias, O., and Demaiffe, D., Metasomatic mantle origin for Mbuji–Mayi and Kundelungu garnet and clinopyroxene megacrysts (Democratic Republic of Congo), Lithos, 2009, vol. 112, pp. 951–960. https://doi.org/10.1016/j.lithos.2009.03.050
Pobric, V., Korolev, N., and Kopylova, M., Eclogites of the North Atlantic Craton: insights from the Chidliak eclogite xenoliths (S. Baffin Island, Canada), Contrib. Mineral. Petrol., 2020, vol. 175, pp. 1–25.
Rapp, R.P., Shimizu, N., Norman, M.D., and Applegate, G.S., Reaction between slab-derived melts and peridotite in the mantle wedge: experimental constraints at 3.8 GPa, Chem. Geol., 1999, vol. 160, no. 4, pp. 335–356.
Reid, A.M., Donaldson, C.H., Dawson, J.B., et al., The Igwisi Hills extrusive “kimberlites”, Phys. Chem. Earth, 1975, pp. 199–218.
Sablukov, S.M., Sablukova, L.I., Shavyrina, M.V., Mantle xenoliths from the Zimnii Bereg kimberlite deposits of rounded diamonds, Arkhangelsk Diamondiferous Province, Petrology, 2000, vol. 8, no. 5, pp. 466–494.
Samsonov, A.V., Nosova, A.A., Tretyachenko, V.V., and Larchenko, V.A., Collisional sutures in the Early Precambrian crust as a factor responsible for localization of diamondiferous kimberlites in the northern East European Platform, Dokl. Earth Sci., 2009, vol. 425, pp. 226–230. https://doi.org/10.1134/S1028334X09020111
Sazonova, L.V., Nosova, A.A., Kargin, A.V., et al., Olivine from the Pionerskaya and V. Grib kimberlite pipes, Arkhangelsk Diamond Province, Russia: types, composition, and origin, Petrology, 2015, vol. 23, pp. 227–258.
Shatskiy, A., Bekhtenova, A., Podborodnikov, I.V., et al., Solidus of carbonated phlogopite eclogite at 3-6 gpa: implications for mantle metasomatism and ultra-high pressure metamorphism, Gondwana Res, 2022, vol. 103, pp. 188–204.
Shchukina, E.V., Agashev, A.M., Soloshenko, N.G., et al., Origin of V. Grib pipe eclogites (Arkhangelsk region, NW Russia): geochemistry, Sm-Nd and Rb-Sr isotopes and relation to regional Precambrian tectonics, Mineral. Petrol., 2019. https://doi.org/10.1007/s00710-019-00679-7
Shu, Q., Brey, G.P., and Pearson, D.G., Eclogites and garnet pyroxenites from Kimberley, Kaapvaal Craton, South Africa: their diverse origins and complex metasomatic signatures, Mineral. Petrol., 2018, vol. 112, pp. 43–56.
Smart, K.A., Heaman, L.M., Chacko, T., et al., The origin of high-MgO diamond eclogites from the Jericho kimberlite, Canada, Earth Planet. Sci. Lett., 2009, vol. 284, pp. 527–537.
Smart, K.A., Tappe, S., Simonetti, A., et al., Tectonic significance and redox state of paleoproterozoic eclogite and pyroxenite components in the Slave cratonic mantle lithosphere, Voyageur kimberlite, Arctic Canada, Chem. Geol., 2017, vol. 455, pp. 98–119. https://doi.org/10.1016/j.chemgeo.2016.10.014
Smart, K.A., Tappe, S., Woodland, A.B., et al., Metasomatized eclogite xenoliths from the central kaapvaal craton as probes of a seismic mid-lithospheric discontinuity, Chem. Geol., 2021, vol. 578. https://doi.org/10.1016/j.chemgeo.2021.120286
Smit, K.V., Stachel, T., Creaser, R.A., et al., Origin of eclogite and pyroxenite xenoliths from the Victor kimberlite, Canada, and implications for superior craton formation, Geochim. Cosmochim. Acta, 2014, vol. 125, pp. 308–337. https://doi.org/10.1016/j.gca.2013.10.019
Spetsius, Z.V. and Taylor, L.A., Partial melting in mantle eclogite xenoliths: connections with diamond paragenesis, Int. Geol. Rev., 2002, vol. 44, pp. 973–987.
Sun, S.-S. and McDonough, W.F., Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes, Geol. Soc. London: Spec. Publ., 1989, vol. 42, pp. 313–345. https://doi.org/10.1144/GSL.SP.1989.042.01.19
Taylor, L.A. and Neal, C.R., Eclogites with oceanic crustal and mantle signatures from the Bellsbank kimberlite, South Africa, Part I: mineralogy, petrography, and whole rock chemistry, J. Geol., 1989, vol. 97, pp. 551–567.
Warr, L.N., IMA–CNMNC approved mineral symbols, Mineral. Mag., 2021, vol. 85, pp. 291–320.
White, W.M., Isotope Geochemistry, Blackwell: John Wiley & Sons, 2015.
Yaxley, G.M. and Green, D.H., Reactions between eclogite and peridotite: mantle refertilisation by subduction of oceanic crust, Swiss J. Geosci., vol. 78, no. Suppl. 1998, pp. 243–255.
ACKNOWLEDGMENTS
We are grateful to I.S. Sagaidak and other colleagues from the Northwestern Regional Fund of Geological Information, Arkhangelsk, and the corporate management of the JSC Severalmaz and personally A.S. Galin, I.S. Zesin, and A.N. Gudin for permission and help with kimberlite sampling. E.O. Dubinina is thanked for the measurement of oxygen isotope composition in minerals and N.N. Korotaeva, for SEM study of minerals. We acknowledge critical comments by A.V. Kargin (IGEM RAS), and reviewers D.M. Mikhailenko (IGM, SB RAS) and M.G. Kopylova (University of British Columba), which significantly improved the manuscript.
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The study was supported by the Russian Foundation for Basic Research (project no. 19-35-90037).
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Lebedeva, N.M., Nosova, A.A., Sazonova, L.V. et al. Metasomatized Xenoliths of Mantle Eclogites and Garnet Pyroxenites from the V. Grib Kimberlite, Arkhangelsk Province. Petrology 30, 479–498 (2022). https://doi.org/10.1134/S0869591122050046
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DOI: https://doi.org/10.1134/S0869591122050046