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Photoinduced Absorption Spectra of Donor–Acceptor Systems Based on Cobalt(II) and Manganese(III) Phthalocyanine Complexes with Femtosecond Time Resolution

  • ON THE 90th ANNIVERSARY OF THE BIRTH OF G.A. KRESTOV
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Abstract

Results of studying the ultrafast dynamics of excited states of cobalt(II) and manganese(III) octakis(3,5-di-tert-butylphenoxy)phthalocyanines, along with donor–acceptor systems based on them with fullero[60]- and fullero[70]pyrrolidines as acceptors are represented. Excited states are achieved by exposing the absorbing substances to laser pulses in femtosecond absorption spectroscopy. The kinetics and types of photoinduced absorption spectra of metal phthalocyanines and their dyads with substituted pyrrolidines are described, along with the lifetimes of states with separated charges. The corresponding constants of charge separation and recombination are determined.

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ACKNOWLEDGMENTS

The authors are grateful to Prof. V.A. Nadtochenko, Dr. Sci. (Chem.), I.V. Shelaev, Cand. Sci. (Tech.), and F.E. Gostev for their assistance.

Funding

This work was supported by the Russian Science Foundation, grant no. 21-73-20090. The experiments were performed on equipment at the the center of the scientific equipment collective use “The Upper Volga Region Center of Physico-Chemical Research” and N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences (Moscow).

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Authors and Affiliations

  1. Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences, 153045, Ivanovo, Russia

    E. N. Ovchenkova, N. G. Bichan & T. N. Lomova

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  1. E. N. Ovchenkova
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  2. N. G. Bichan
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  3. T. N. Lomova
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Correspondence to N. G. Bichan.

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Translated by O. Kadkin

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Ovchenkova, E.N., Bichan, N.G. & Lomova, T.N. Photoinduced Absorption Spectra of Donor–Acceptor Systems Based on Cobalt(II) and Manganese(III) Phthalocyanine Complexes with Femtosecond Time Resolution. Russ. J. Phys. Chem. 96, 717–723 (2022). https://doi.org/10.1134/S0036024422040240

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