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Polar stationary phases based on poly(oligo ethylene glycol)diacrylates for capillary gas chromatography

  • Physical Chemistry of Separation Processes. Chromatography
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Abstract

New stationary phases for capillary columns in GC are synthesized and studied. The phases are prepared by depositing oligo(ethylene glycol)diacrylates on the column walls and subsequent polymerization (crosslinking) in the presence of peroxide initiators. It is shown that stationary phases based on monomers with molecular weights of 10 kDa or higher exhibit separation properties similar to those of conventional stationary phases based on polyethylene glycol (PEG); however, their thermal stability is higher because they have a higher degree of crosslinking and a more ordered structure of the crosslinked polymers than the respective parameters of phases based on native PEG.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    V. E. Shiryaeva, T. P. Popova, A. A. Korolev, A. Yu. Kanat’eva & A. A. Kurganov

Authors
  1. V. E. Shiryaeva
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  2. T. P. Popova
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  3. A. A. Korolev
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  4. A. Yu. Kanat’eva
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  5. A. A. Kurganov
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Correspondence to V. E. Shiryaeva.

Additional information

Original Russian Text © V.E. Shiryaeva, T.P. Popova, A.A. Korolev, A.Yu. Kanat’eva, A.A. Kurganov, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 8, pp. 1403–1411.

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Shiryaeva, V.E., Popova, T.P., Korolev, A.A. et al. Polar stationary phases based on poly(oligo ethylene glycol)diacrylates for capillary gas chromatography. Russ. J. Phys. Chem. 91, 1571–1579 (2017). https://doi.org/10.1134/S0036024417080325

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  • DOI: https://doi.org/10.1134/S0036024417080325

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