Abstract
The possibilities and aspects of using laser ablation (LA) to study the microhemogeneity and composition of tantalum pentoxides and a Ta2O5-based lithium tantalate charge doped with small concentrations of rare earth elements (TRs) are studied. It is shown that LA can be performed for Ta2O5〈TR〉 precursor and LiTaO3ťTR〉 charge samples pelletized without a binder. The detection limits of TR are determined via inductively coupled plasma mass spectrometry (ICP-MS), and the conditions for quantitative analysis are found. Based on the calculated values of root-mean-square deviation S r , it is proved that the distribution of the dopant in the studied samples is chemically homogeneous.
Similar content being viewed by others
References
S. L. Votyakov and N. N. Adamovich, Litosfera, No. 4, 56 (2011).
S. M. Masloboeva, V. T. Kalinnikov, and I. R. Elizarova, in Proceedings of the 3rd International Conference on Chemistry and Chemical Technology, Armenia, Yerevan, September 16–20, 2013, p. 73.
S. M. Masloboeva, I. R. Elizarova, G. I. Kadyrova, and L. G. Arutyunyan, Inorg. Mater. 50, 803 (2014).
S. L. Votyakov, N. N. Adamovich, and S. P. Glavatskikh, in Year-Book-2009, Tr. IGG UrO RAN, No. 157, 310 (2010).
D. O. Kuleshov and I. R. Elizarova, Mezhd. Zh. Prikl. Fundam. Issled., No. 1, 176 (2012).
N. J. Saetveit, S. J. Bajic, D. P. Baldwin, and R. S. Houk, J. Anal. At. Spectrom. 23, 54 (2008).
H. R. Kuhn and D. Gunther, Anal. Bioanal. Chem. 383, 434 (2005).
H. C. Liu, O. V. Borisov, X. L. Mao, et al., Appl. Spectrosc. 54, 1435 (2000).
M. Guillong, I. Horn, and D. Gunther, J. Anal. At. Spectrom. 18, 1224 (2003).
T. E. Jeffries, S. E. Jackson, and H. P. Longerich, J. Anal. At. Spectrom. 13, 935 (1998).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © I.R. Elizarova, S.M. Masloboeva, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 9, pp. 1443–1449.
Rights and permissions
About this article
Cite this article
Elizarova, I.R., Masloboeva, S.M. Using laser ablation to study the microhomogeneity and composition of rare-earth doped Ta2O5 Precursors and a LiTaO3 charge. Russ. J. Phys. Chem. 89, 1655–1661 (2015). https://doi.org/10.1134/S0036024415090113
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024415090113