Skip to main content
SpringerLink
Log in

Catalytic conversion of C2-C3 alcohols on detonation nanodiamond and its modifications

  • Chemical Kinetics and Catalysis
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The catalytic activity of detonation nanodiamond and its modifications obtained through treatment with hydrogen or air at elevated temperatures is studied in the conversion of C2-C3 alcohols. The catalysts were characterized by means of electron microscopy, optical (FTIR) spectroscopy, elemental analysis and pulse microcatalytic method. It has been established that nanodiamond exhibits high catalytic activity in the conversion of alcohols. The oxidizing and reducing treatment of nanodiamond changes its activity and selectivity, and the activity of oxidized nanodiamond is considerably higher than that of reduced nanodiamond.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ultrananocrystalline Diamond, Synthesis, Properties, and Application, Ed. by O. A. Shenderova and D. M. Gruen (William Andrew., Norwich, New York, 2006), p. 600.

    Google Scholar 

  2. I. I. Kulakova, Phys. Solid State 46, 636 (2004).

    Article  CAS  Google Scholar 

  3. V. Yu. Dolmatov, Nanotekhnika, No. 1, 56 (2008).

  4. J. L. Figueiredo and M. F. R. Pereira, Catal. Today 150, 2 (2010).

    Article  CAS  Google Scholar 

  5. D. S. Su, J. Zhang, B. Frank, et al., ChemSusChem. 3, 169 (2010).

    Article  CAS  Google Scholar 

  6. E. V. Golubina, S. A. Kachevsky, E. S. Lokteva, et al., Mendeleev Commun. 19(3), 133 (2009).

    Article  CAS  Google Scholar 

  7. D. S. Su, N. I. Maksimova, G. Mestl, et al., Carbon 45, 2145 (2007).

    Article  CAS  Google Scholar 

  8. J. Zhang, D. S. Su, A. Zhang, et al., Angew. Chem. 119, 7460 (2007).

    Article  Google Scholar 

  9. M. A. Ryashentseva, E. V. Egorova, A. I. Trusov, et al., Usp. Khim. 75, 1119 (2006).

    Google Scholar 

  10. J. Bedia, J. M. Rosas, J. Marquerz, et al., Carbon 47, 286 (2009).

    Article  CAS  Google Scholar 

  11. G. S. Szymański and G. Rychlicki, Carbon 29, 489 (1991).

    Article  Google Scholar 

  12. G. S. Szymański and G. Rychlicki, Carbon 31, 247 (1993).

    Article  Google Scholar 

  13. G. S. Szymański, G. Rychlicki, and A. P. Terzyk, Carbon 32, 265 (1994).

    Article  Google Scholar 

  14. C. Morena-Castilla, F. Carrasco-Marin, C. Parejo- Perez, and M. V. Lopez-Ramon, Carbon 39, 869 (2001).

    Article  Google Scholar 

  15. F. Carrasco-Marin, A. Mueden, and C. Moreno-Castilla, J. Phys. Chem. B 102, 9239 (1998).

    Article  CAS  Google Scholar 

  16. E. Jasińska, B. Krzyżyńska, and M. Kozłowski, Catal. Lett. 125, 145 (2008).

    Article  Google Scholar 

  17. A. Dementjev, K. Maslakov, I. Kulakova, and V. Korolkov, Diamond Relat. Mater. 16, 2083 (2007).

    Article  CAS  Google Scholar 

  18. E. Pretsch, P. Buhlmann, and C. Affolter, Structure Determination of Organic Compounds; Tables of Spectral Data (Mir, Moscow, 2009) [in Russian].

    Google Scholar 

  19. E. Pretsch, P. Buhlmann, and C. Affolter, Structure Determination of Organic Compounds. Tables of Spectral Data (Springer, 2000), p. 421.

  20. Yu. N. Zhitnev, E. A. Tveritinova, and V. V. Lunin, Russ. J. Phys. Chem. A 82, 140 (2008).

    Article  CAS  Google Scholar 

  21. Tables of Physical Values. The Manual, Ed. by I. K. Kikoin (Atomizdat, Moscow, 1976), pp. 213, 229, 337 [in Russian].

    Google Scholar 

  22. I. I. Kulakova, V. V. Korol’kov, R. Yu. Yakovlev, and G. V. Lisichkin, Nanotechnol. Russia 5, 474 (2010).

    Article  Google Scholar 

  23. I. I. Kulakova, B. N. Tarasevich, A. P. Rudenko, et al., Vestn. Mosk. Univ., Ser. Khim. 34, 506 (1993).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    E. A. Tveritinova, I. I. Kulakova, Yu. N. Zhitnev, A. V. Fionov & V. V. Lunin

  2. Department of Physics, Chemistry, and Biology, Linköping University, Linköping, 58183, Sweden

    A. Lund, W. Chen & I. Buyanova

Authors
  1. E. A. Tveritinova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. I. Kulakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. N. Zhitnev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Fionov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. Lund
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. W. Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. I. Buyanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. V. V. Lunin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. A. Tveritinova.

Additional information

Original Russian Text © E.A. Tveritinova, I.I. Kulakova, Yu.N. Zhitnev, A.V. Fionov, A. Lund, W. Chen, I. Buyanova, V.V. Lunin, 2012, published in Zhurnal Fizicheskoi Khimii, 2012, Vol. 86, No. 1, pp. 31–36.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tveritinova, E.A., Kulakova, I.I., Zhitnev, Y.N. et al. Catalytic conversion of C2-C3 alcohols on detonation nanodiamond and its modifications. Russ. J. Phys. Chem. 86, 26–31 (2012). https://doi.org/10.1134/S0036024412010281

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024412010281

Keywords

Search

Navigation