Abstract
The influence of carrier gas pressure on the retention factor k′ of light hydrocarbons C1–C4 in a monolithic capillary column based on divinylbenzene was studied. It was shown that, for monolithic columns and nonideal carrier gases, the pressure dependence of lnk′ was nonlinear over a wide pressure range and could be described by the classic Everett equation. It was concluded that the competitive adsorption model failed to describe the experimental data correctly, especially for strongly retained sorbates and/or heavy carrier gases.
Similar content being viewed by others
References
A. T. James and A. J. Martin, Biochem. J. 50, 679 (1952).
V. A. Davankov, Zh. Fiz. Khim. 74(10), 1911 (2000) [Russ. J. Phys. Chem. 74 (10), (2000)].
A. V. Kiselev et al., Physicochemical Application of Gas Chromatography (Khimiya, Moscow, 1973) [in Russian].
A. J. B. Cruickshank, M. L. Windsor, and C. L. Young, Trans. Faraday Soc. 295, 259 (1966).
D. H. Everett, Trans. Faraday Soc. 61, 1637 (1965).
L. A. Onuchak, S. Yu. Kudryashov, Yu. I. Arutyunov, and V. A. Davankov, Zh. Fiz. Khim. 80(8), 1493 (2006) [Russ. J. Phys. Chem. 80 (8), 1315 (2006)].
A. V. Bulanova, Dokl. Akad. Nauk 348(6), 772 (1996) [Dokl. Phys. Chem. 348 (4–6), 143 (1996)].
N. V. Nesterova, A. V. Bulanova, and O. G. Larionov, Khim. Khim. Tekhnol. 44(1), 84 (2001).
D. DeVault, J. Am. Chem. Soc. 65, 532 (1943).
V. G. Berezkin and I. V. Malyukova, Usp. Khim. 67(9), 835 (1998).
S. Golshan-Shirazi and G. Guiochon, J. Chromatogr., A 658, 149 (1994).
A. A. Korolev, V. E. Shiryaeva, T. P. Popova, et al., Vysokomol. Soedin., Ser. A. 48(8), 1373 (2006) [Polymer Science, Ser. A 48 (8), 779 (2006)].
A. V. Kozin and A. A. Kurganov, in Chromatography for the Benefit of Russia, Ed. by A. A. Kurganov (Izd. Granitsa, Moscow, 2007) [in Russian].
A. V. Kozin, A. A. Korolev, V. E. Shiryaeva, et al., Zh. Fiz. Khim. 81(3), 512 (2007) [Russ. J. Phys. Chem. A 81 (3), 433 (2007)].
A. A. Korolev, V. E. Shiryaeva, T. P. Popova, and A. A. Kurganov, Zh. Fiz. Khim. 80(1), 132 (2006) [Russ. J. Phys. Chem. 80 (1), 120 (2006)].
P. W. Atkins, Physical Chemistry, 6th ed. (Oxford University Press, Oxford, 1998).
Physical Values: A Handbook, Ed. by I. S. Grigor’ev and E. Z. Melikhov (Energoatomizdat, Moscow, 1991), p. 316 [in Russian].
A. J. B. Cruickshank, M. L. Windsor, and C. L. Young, Proc. R. Soc. London, Ser. A 295, 259 (1966).
M. L. Windsor and C. L. Young, J. Chromatogr. 27(2), 355 (1967).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Korolev, V.E. Shiryaeva, T.P. Popova, A.V. Kozin, A.A. Kurganov, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 4, pp. 776–783.
Rights and permissions
About this article
Cite this article
Korolev, A.A., Shiryaeva, V.E., Popova, T.P. et al. The influence of carrier gas pressure on the retention of sorbates on monolithic capillary columns in gas chromatography. Russ. J. Phys. Chem. 83, 670–676 (2009). https://doi.org/10.1134/S0036024409040268
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024409040268