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Synthesis and luminescence properties of neutral Tm(III), Dy(III), and Gd(III) complexes with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)-1,3-propanedione and 1,10-phenanthroline

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Abstract

Neutral complexes of composition [LnL3Phen], where Ln = Tm, Dy, and Gd, were synthesized by the reaction of LnCl3 with heterocyclic diketone 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)-1,3-propanedione (HL, 1) and 1,10-phenanthroline in an aqueous alcohol solution in the presence of NaOH. The composition of the complexes was proved by elemental analysis. Their optical and luminescence properties were studied.

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Authors and Affiliations

  1. People’s Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow, 117198, Russia

    I. V. Taidakov & B. E. Zaitsev

  2. Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, Moscow, 119991, Russia

    A. N. Lobanov & A. G. Vitukhnovskii

Authors
  1. I. V. Taidakov
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  2. B. E. Zaitsev
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  3. A. N. Lobanov
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  4. A. G. Vitukhnovskii
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Corresponding author

Correspondence to I. V. Taidakov.

Additional information

Original Russian Text © I.V. Taidakov, B.E. Zaitsev, A.N. Lobanov, A.G. Vitukhnovskii, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 6, pp. 943–946.

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Taidakov, I.V., Zaitsev, B.E., Lobanov, A.N. et al. Synthesis and luminescence properties of neutral Tm(III), Dy(III), and Gd(III) complexes with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)-1,3-propanedione and 1,10-phenanthroline. Russ. J. Inorg. Chem. 57, 870–873 (2012). https://doi.org/10.1134/S0036023612060241

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  • DOI: https://doi.org/10.1134/S0036023612060241

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