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Reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid and synthesis of ammine(nitrato)nitrosoruthenium complexes

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Abstract

The reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid has been studied. Reaction products have been identified by IR spectroscopy, NMR, mass spectrometry, powder and single-crystal X-ray diffraction, and chemical analysis. Synthesis methods have been developed for amminenitrosoruthenium complexes containing outer-sphere and coordinated nitrate ions: trans-[RuNO(NH3)4(H2O)](NO3)3 (I), trans-[RuNO(NH3)4(NO3)](NO3)2 (II), and fac-[RuNO(NH3)2(NO3)3] (III). Complex II has two polymorphs: monoclinic and tetragonal. The latter has been studied by X-ray crystallography.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. V. Kabin, V. A. Emel’yanov, N. I. Alferova, S. V. Tkachev & I. A. Baidina

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    E. V. Kabin, V. A. Emel’yanov & V. A. Vorob’yev

Authors
  1. E. V. Kabin
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  2. V. A. Emel’yanov
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  3. V. A. Vorob’yev
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  4. N. I. Alferova
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  5. S. V. Tkachev
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  6. I. A. Baidina
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Correspondence to E. V. Kabin.

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Original Russian Text © E.V. Kabin, V.A. Emel’yanov, V.A. Vorob’yev, N.I. Alferova, S.V. Tkachev, I.A. Baidina, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 8, pp. 1225–1233.

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Kabin, E.V., Emel’yanov, V.A., Vorob’yev, V.A. et al. Reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid and synthesis of ammine(nitrato)nitrosoruthenium complexes. Russ. J. Inorg. Chem. 57, 1146–1153 (2012). https://doi.org/10.1134/S0036023612050105

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  • DOI: https://doi.org/10.1134/S0036023612050105

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