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Structure and some properties of [UO2(SeO4)(C5H12N2O)2(H2O)]

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Abstract

The complex [UO2(SeO4)(C5H12N2O)2(H2O)] (I) was synthesized and studied by thermal analysis, IR spectroscopy, and X-ray crystallography. The crystals are orthorhombic: a = 13.1661(3) Å, b = 16.4420(5) Å, c = 17.4548(6) Å, Pbca, Z = 8, R = 0.0423. The structural units of crystal I are chains with the composition coinciding with that of the compounds of the AB2M 13 crystal chemical group of the uranyl complexes (A = UO 2+2 , B2 = SeO 2−4 , M1 = C5H12N2O and H2O).

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Authors and Affiliations

  1. Samara State University, ul. Akademika Pavlova, 1, Samara, 443011, Russia

    L. B. Serezhkina, E. V. Grechishnikova & A. V. Savchenkov

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. V. Peresypkina & A. V. Virovets

Authors
  1. L. B. Serezhkina
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  2. E. V. Peresypkina
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  3. A. V. Virovets
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  4. E. V. Grechishnikova
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  5. A. V. Savchenkov
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Original Russian Text © L.B. Serezhkina, E.V. Peresypkina, A.V. Virovets, E.V. Grechishnikova, A.V. Savchenkov, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 11, pp. 1822–1829.

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Serezhkina, L.B., Peresypkina, E.V., Virovets, A.V. et al. Structure and some properties of [UO2(SeO4)(C5H12N2O)2(H2O)]. Russ. J. Inorg. Chem. 56, 1739–1746 (2011). https://doi.org/10.1134/S0036023611110234

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  • DOI: https://doi.org/10.1134/S0036023611110234

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