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Production of Alcohols and Olefins from CO and H2 on a Cobalt Catalyst at High Pressures and in the Gas Circulation Mode

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Abstract

The results of a study of the synthesis of products from CO and H2 on a supported industrial Co–Al2O3/SiO2 catalyst under medium and high pressures in the gas circulation mode are presented. It was found that an increase in pressure from 2.0 to 8.0 MPa led to an increase in the amount of formed alcohols and synthesis olefins by factors of 10.5 and 2.0, respectively. It was determined that alcohols obtained in the synthesis were not the products of olefin hydration. The effect of an increase in selectivity for C5+ products with temperature at a high pressure in the gas recirculation mode, which is atypical for the Fischer–Tropsch synthesis, was confirmed.

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Funding

This study was supported by the Russian Foundation for Basic Research (project no. 20-33-90149) and the Ministry of Science and Higher Education of the Russian Federation (state assignment no. 2019-0990) and carried out using the equipment of the Center for Shared Use “Nanotechnologies” at the Platov South-Russian State Polytechnic University (NPI).

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Authors and Affiliations

  1. Platov South-Russian State Polytechnic University (NPI), 346128, Novocherkassk, Russia

    I. N. Zubkov, V. N. Soromotin, A. P. Savost’yanov, S. A. Mitchenko & R. E. Yakovenko

Authors
  1. I. N. Zubkov
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  2. V. N. Soromotin
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  3. A. P. Savost’yanov
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  4. S. A. Mitchenko
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  5. R. E. Yakovenko
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Corresponding author

Correspondence to R. E. Yakovenko.

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The authors declare that they have no conflicts of interest.

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Translated by V. Makhlyarchuk

Abbreviations and notation: GHSV, gas hourly space velocity; SEM, scanning electron microscopy; XRD, X-ray diffraction.

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Zubkov, I.N., Soromotin, V.N., Savost’yanov, A.P. et al. Production of Alcohols and Olefins from CO and H2 on a Cobalt Catalyst at High Pressures and in the Gas Circulation Mode. Kinet Catal 63, 218–225 (2022). https://doi.org/10.1134/S0023158422020148

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  • DOI: https://doi.org/10.1134/S0023158422020148

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