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Effect of the nature of the active-component precursor on the properties of Pt/MgAlO x catalysts in propane and n-decane dehydrogenation

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Abstract

The Pt/MgAlO x catalysts, in which a mixed aluminum–magnesium oxide obtained by the heat treatment of corresponding layered double hydroxides was used as a support, were studied. The effects of the nature of active-component precursors ([PtCl6]2–, [PtCl4]2–, and [Pt3(CO)6] 2-6 ), and the Mg/Al ratio in the support on the anchoring of complexes, the disperse state of platinum, and the properties of the obtained catalysts in the reactions of propane and n-decane dehydrogenation were found.

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    L. N. Stepanova, O. B. Belskaya & V. A. Likholobov

  2. Omsk State University, Omsk, 644077, Russia

    L. N. Stepanova

  3. Omsk State Technical University, Omsk, 644050, Russia

    O. B. Belskaya & V. A. Likholobov

  4. Omsk Research Center, Siberian Branch, Russian Academy of Sciences, Omsk, 644024, Russia

    V. A. Likholobov

Authors
  1. L. N. Stepanova
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  2. O. B. Belskaya
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  3. V. A. Likholobov
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Corresponding author

Correspondence to L. N. Stepanova.

Additional information

Original Russian Text © L.N. Stepanova, O.B. Belskaya, V.A. Likholobov, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 4, pp. 400–409.

This paper is based on the proceedings of the V All-Russian Scientific Youth School and Conference “Chemistry under the Sigma Sign: Studies, Innovations, and Technologies” (Omsk, May 15–20, 2016).

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Stepanova, L.N., Belskaya, O.B. & Likholobov, V.A. Effect of the nature of the active-component precursor on the properties of Pt/MgAlO x catalysts in propane and n-decane dehydrogenation. Kinet Catal 58, 383–391 (2017). https://doi.org/10.1134/S0023158417040188

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  • DOI: https://doi.org/10.1134/S0023158417040188

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