Skip to main content
SpringerLink
Log in

Performance of a zeolite-containing catalyst and catalysts based on noble metals in intermolecular hydrogen transfer between С6 hydrocarbons

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The activities of a zeolite-containing catalyst and catalysts containing a noble metal in intermolecular hydrogen transfer between С6 hydrocarbons are compared. The zeolite-containing catalyst is ineffective in hydrogen transfer from cyclohexane to 1-hexene and in cyclohexene conversion at <400°С. Cyclohexene disproportionation at Т < 200°С takes place only over catalysts containing a noble metal. The cyclohexene conversion selectivity depends strongly on the support type. Using deuterated compounds, it has been demonstrated that intermolecular hydrogen transfer via the dehydrogenation–hydrogenation mechanism involves only the initial cyclohexene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Bukharkina, T.V. and Digurov, N.G., Khimiya prirodnykh energonositelei i uglerodnykh materialov (Chemistry of Natural Energy Carriers and Carbon Materials), Moscow RKhTU im. D. I. Mendeleeva, 1999.

    Google Scholar 

  2. Gryaznov, V.M., Usp. Khim., 1963, vol. 32, no. 4, p. 433.

    Article  CAS  Google Scholar 

  3. Potapenko, O.V., Doronin, V.P., Sorokina, T.P., and Likholobov, V.A., Fuel Process. Technol., 2014, vol. 251, p. 251.

    Article  Google Scholar 

  4. Potapenko, O.V., Doronin, V.P., Sorokina, T.P., Talsi, V.P., and Likholobov, V.A., Appl. Catal., B, 2012, vols. 117–118, p. 177.

    Article  Google Scholar 

  5. Magnoux, P., Gallet, A., and Guisnet, M., Bull. Soc. Chim. Fr., 1987, vol. 5, p. 810.

    Google Scholar 

  6. Cheng, W-C. and Rajagopalan, K., J. Catal., 1989, vol. 119, p. 354.

    Article  CAS  Google Scholar 

  7. Jacquinot, E., Raatz, F., Macedo, A., and Marcilly, Ch., Stud. Surf. Sci. Catal., 1989, vol. 46, p. 115.

    Article  Google Scholar 

  8. Cheng, W-C., Peters, A.W., and Rajagopalan, K., Prepr. Am. Chem. Soc., Div. Pet. Chem., 1989, vol. 34, p. 719.

    CAS  Google Scholar 

  9. Balandin, A.A. and Brusow, J.J., Russ. J. Phys. Chem., 1936, vol. 34, p. 96.

    Google Scholar 

  10. Carra, S., Beltrame, P., and Ragaini, V., J. Catal., 1964, vol. 3, p. 353.

    Article  CAS  Google Scholar 

  11. Carra, S., Ragaini, V., and Guella, F., J. Catal., 1967, vol. 8, p. 261.

    Article  CAS  Google Scholar 

  12. Davis, S.M. and Somotjai, G.A., J. Catal., 1980, vol. 65, p. 78.

    Article  CAS  Google Scholar 

  13. Crabtree, R.H. and Pamell, C.P., Organometallics, 1985, vol. 4, p. 519.

    Article  CAS  Google Scholar 

  14. Chaudret, B.N., Cole-Hamilton, D.J., and Wilkinson, G., Acta Chem. Scand., Ser. A, 1978, vol. 32, p. 763.

    Article  Google Scholar 

  15. De la Puente, G. and Sedran, U., Chem. Eng. Sci., 2000, vol. 55, p. 759.

    Article  Google Scholar 

  16. De la Puente, G., Souza-Aguiar, E.F., Zanon Zotin, F.M., Doria Camorim, V.L., and Sedran, U., Appl. Catal., A, 2000, vol. 197, p. 41.

    Article  Google Scholar 

  17. Suarez, W., Cheng, W.-C., Rajagopalan, K., and Peters, A.W., Chem. Eng. Sci., 1990, vol. 8, p. 2581.

    Article  Google Scholar 

  18. Zelinsky, N.D. and Pavlov, G., Ber. Dtsch. Chem. Ges., 1923, vol. 56, p. 1249.

    Article  Google Scholar 

  19. Zelinsky, N.D. and Pavlov, G., Ber. Dtsch. Chem. Ges., 1924, vol. 57, p. 669.

    Article  Google Scholar 

  20. Brieger, G. and Nestrick, T.J., Chem. Rev., 1974, vol. 74, p. 567.

    Article  CAS  Google Scholar 

  21. Doronin, V.P., Sorokina, T.P., Lipin, P.V., Potapenko, O.V., Korotkova, N.V., and Gordenko, V.I., Catal. Ind., 2015, vol. 7, no. 1, p. 12.

    Article  Google Scholar 

  22. Passamonti, F.J., De la Puente, G., and Sedran, U., Catal. Today, 2008, vols. 133–135, p. 314.

    Article  Google Scholar 

  23. Sedran, U.A., Catal. Rev. Sci. Eng., 1994, vol. 36, no. 3, p. 405.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    K. A. Bukin, O. V. Potapenko, V. P. Doronin, T. P. Sorokina & T. I. Gulyaeva

Authors
  1. K. A. Bukin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Potapenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. P. Doronin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. P. Sorokina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. I. Gulyaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to K. A. Bukin.

Additional information

Original Russian Text © K.A. Bukin, O.V. Potapenko, V.P. Doronin, T.P. Sorokina, T.I. Gulyaeva, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 3, pp. 283–291.

The article is based on the proceedings of Young Researchers’ 5th Russian National School and Conference “Chemistry under the SIGMA Sign: Research, Innovations, and Technologies” (Omsk, May 15–20, 2016).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bukin, K.A., Potapenko, O.V., Doronin, V.P. et al. Performance of a zeolite-containing catalyst and catalysts based on noble metals in intermolecular hydrogen transfer between С6 hydrocarbons. Kinet Catal 58, 271–278 (2017). https://doi.org/10.1134/S002315841703003X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S002315841703003X

Keywords

Search

Navigation