Abstract
The change in the surface composition of a MoB catalyst in the epoxidation of 1-octene with tert-butyl hydroperoxide and the effects of the reactant concentrations and reaction products (tert-butanol and 1,2-epoxyoctane) on this process have been studied.
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References
Weissermel, K., Industrial Organic Chemistry, Weinheim: Wiley-VCH, 2003.
Tolstikov, G.A., Reaktsii gidroperekisnogo okisleniya (Hydroperoxidation Reactions), Moscow: Nauka, 1976.
Lane, S. and Benjamin, N., Chem. Rev., 2003, vol. 103, no. 7, p. 2457.
US Patent 4033901, 1978.
US Patent t 4038290, 1978.
US Patent 4203910, 1981.
Tempesti, E., Giuffre, L., Mazzocchia, C., and Di Renzo, F., Stud. Surf. Sci. Catal., 1985, vol. 20, p. 177.
Tempesti, E., Giuffre, L., Di Renzo, F., Mazzocchia, C., and Modica, G., J. Mol. Catal., 1988, vol. 45, no. 2, p. 255.
Trach, Yu.B., Komarenskaya, Z.M., Nikipanchuk, M.V., Pyrig, I.Yu., and Romanyuk, G.V., Teor. Ekp. Khim., 2001, vol. 37, no. 2, p. 78.
Trach, Yu.B., Makota, O.I., and Pyrig, I.Yu., Vestn. Gos. Univ. L’vov Politekh., Khim. Tekhnol. Veshchestv Ikh Primen., 2001, vol. 426, p. 97.
Trach, Yu.B. and Makota, O.I., Pet. Chem., 2004, vol. 44, no. 1, p. 48.
Trach, Yu.B. and Chernii, M.O., Ukr. Khim. Zh., 2003, vol. 69, no. 12, p. 112.
Trach, Yu.B. and Makota, O.I., Teor. Eksp. Khim., 2002, vol. 38, no. 4, p. 245.
Trach, Yu.B., Nikipanchuk, M.V., and Komarenskaya, Z.M., Kinet. Catal., 2004, vol. 45, no. 4, p. 504.
Nykypanchuk, M.V., Komarenskaya, Z.M., and Chernii, M.O., Kinet. Catal., 2014, vol. 55, no. 2, p. 212.
Antonovskii, V.L., Organicheskie perekisnye initsiatory (Organic Peroxide Initiators), Moscow: Khimiya, 1972.
Kuz’ma, Yu.B. and Chaban, N.F., Dvoinye i troinye sistemy, soderzhashchie bor: Spravochnoe izdanie (Boron-Containing Binary and Ternary Systems: A Handbook), Moscow: Metallurgiya, 1990.
Elimanova, G.G., Smolin, R.A., Batyrshin, N.N., and Kharlampidi, Kh.E., Peredovye tekhnologii i perspektivy razvitiya OAO “Kazan’orgsintez” (“Advanced Technologies and Kazan’orgsintez Company Development Outlook,” Proc. Int. Conf.), Kazan, 2008, p. 25.
Talzi, E.P., Soros. Obrazovat. Zh., 2000, vol. 6, no. 7, p. 35.
Yudanov, I.V., J. Struct. Chem., 2007, vol. 48, no. 7, p. S111.
Protashchik, V.A., Novye zakonomernosti v topokhimii (Advanced Topochemistry), Moscow: Znanie, 1974.
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Original Russian Text © M.V. Nykypanchuk, M.O. Chernii, Z.M. Komarenskaya, 2016, published in Kinetika i Kataliz, 2016, Vol. 57, No. 3, pp. 370–375.
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Nykypanchuk, M.V., Chernii, M.O. & Komarenskaya, Z.M. The effect of reaction conditions on MoB activation in 1-octene epoxidation with tert-butyl hydroperoxide. Kinet Catal 57, 368–372 (2016). https://doi.org/10.1134/S0023158416030113
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DOI: https://doi.org/10.1134/S0023158416030113