Skip to main content
Log in

Low-temperature oxidation of carbon monoxide on Pd(Pt)/CeO2 catalysts prepared from complex salts

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

Catalysts containing cerium oxide as a support and platinum and palladium as active components for the low-temperature oxidation of carbon monoxide were studied. The catalysts were synthesized in accordance with original procedures with the use of palladium and platinum complex salts. Regardless of preparation procedure, the samples prepared with the use of only platinum precursors did not exhibit activity at a low temperature because only metal and oxide (PtO, PtO2) nanoparticles were formed on the surface of CeO2. Unlike platinum, palladium can be dispersed on the surface of CeO2 to a maximum extent up to an almost an ionic (atomic) state, and it forms mixed surface phases with cerium oxide. In a mixed palladium-platinum catalyst, the ability of platinum to undergo dispersion under the action of palladium also increased; as a result, a combined surface phase with the formula Pd x Pt y CeO2 − δ, which exhibits catalytic activity at low temperatures, was formed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Recent Progress in Catalysis by Ceria and Related Compounds, Bernal, S., Kaspar, J., and Trovarelly, A., Eds., Catal. Today, 1999, vol. 50, p. 173.

  2. Haruta, M., Chem. Rec., 2003, vol. 3, p. 75.

    Article  CAS  Google Scholar 

  3. Engler, B, Koberstein, E, Lindner, D, and Lox, E, in Catalysis and Automotive Pollution Control II, Crucq, A., Ed., Amsterdam: Elsevier, 1991, p. 641.

    Google Scholar 

  4. Trovarelli, A., Catal. Rev. Sci. Eng., 1996, vol. 38, p. 439.

    Article  CAS  Google Scholar 

  5. Colussi, S., Gayen, A., Camellone, M.F., Boaro, M., Llorca, J., Fabris, S., and Trovarelli, A., Angew. Chem., 2009, vol. 121, p. 8633.

    Article  Google Scholar 

  6. Pierre, D., Deng, W., and Flytzani-Stephanopoulos, M., Top. Catal., 2007, vol. 46, p. 363.

    Article  CAS  Google Scholar 

  7. Luo, J.-Y., Meng, M., Xian, H., Tu, Y.-B., Li, X.-G., and Ding, T., Catal. Lett., 2009, vol. 133, p. 328.

    Article  CAS  Google Scholar 

  8. Burton, P.D., Lavenson, D., Johnson, M., Gorm, D., Karim, A.M., Conant, T., Datye, A.K., Hernandez-Sanchez, B.A., and Boyle, T.J., Top. Catal., 2008, vol. 49, p. 227.

    Article  CAS  Google Scholar 

  9. Yang, Y., Saoud, K.M., Abdelsayed, V., Glaspell, G., Deevi, S., and El-Shall, M.S., Catal. Commun., 2006, vol. 7, p. 281.

    Article  CAS  Google Scholar 

  10. Bera, P., Patil, K.C., Jayram, V., Subbanna, G.N., and Hegde, M.S., J. Catal., 2000, vol. 196, p. 293.

    Article  CAS  Google Scholar 

  11. Bera, P., Gayen, A., Hegde, M.S., Lalla, N.P., Spadaro, L., Frusteri, F., and Arena, F., J. Phys. Chem. B, 2003, vol. 107, p. 6122.

    Article  CAS  Google Scholar 

  12. Bera, P., Priolkar, K.R., Gayen, A., Sarode, P.R., Hegde, M.S., Emura, S., Kumashiro, R., Jayaram, V., and Subbanna, G.N., Chem. Mater., 2003, vol. 15, p. 2049.

    Article  CAS  Google Scholar 

  13. Gayen, A., Priolkar, K.R., Sarode, P.R., Jayaram, V., Hegde, M.S., Subbanna, G.N., and Emura, S., Chem. Mater., 2004, vol. 16, p. 2317.

    Article  CAS  Google Scholar 

  14. Roy, S. and Hegde, M.S., Catal. Commun., 2008, vol. 9, p. 811.

    Article  CAS  Google Scholar 

  15. Sharma, S. and Hegde, M.S., J. Chem. Phys., 2009, vol. 130, p. 114706.

    Article  Google Scholar 

  16. Deganello, G., Giannici, F., Martorana, A., Pantaleo, G., and Prestianni, A., J. Phys. Chem. B, 2006, vol. 110, p. 8731.

    Article  CAS  Google Scholar 

  17. Longo, A., Balerna, A., Acapito, F., D’Anca, F., Giannici, F., Liotta, L.F., Pantaleod, G., and Martorana, A., J. Synchrotron Radiat., 2005, vol. 12, p. 499.

    Article  CAS  Google Scholar 

  18. Damyanova, S. and Bueno, J.M.C., Appl. Catal., A, 2003, vol. 253, p. 135.

    Article  CAS  Google Scholar 

  19. Graf, P.O., de Vlieger, D.J.M., Mojet, B.L., and Lefferts, L., J. Catal., 2009, vol. 262, p. 181.

    Article  CAS  Google Scholar 

  20. Roth, D., Gelin, P., Primet, M., and Tena, E., Appl. Catal., A, 2000, vol. 203, p. 37.

    Article  CAS  Google Scholar 

  21. Yoshida, H., Nakajima, T., Yazawa, Y., and Hattori, T., Appl. Catal., B, 2007, vol. 71, p. 70.

    Article  CAS  Google Scholar 

  22. Le Normand, F., Hilaire, L., Kili, K., Krill, G., and Marie, G., J. Phys. Chem., 1988, vol. 92, p. 2561.

    Article  Google Scholar 

  23. RF Patent RU 2294240, Byull. Izobret., 2007, no. 6.

  24. Snytnikov, P.V., Yusenko, K.V., Korenev, S.V., Shubin, Yu.V., and Sobyanin, V.A., Kinet. Katal., 2007, vol. 48, p. 292 [Kinet. Catal. (Engl. Transl.), vol. 48, p. 276].

    Article  CAS  Google Scholar 

  25. Shubin, Yu.V. and Korenev, S.V., Katal. Prom-sti., 2008, special issue, p. 69.

  26. Chen, J.P. and Lim, L.L., Chemosphere, 2002, vol. 49, p. 363.

    Article  CAS  Google Scholar 

  27. Wu, S.-H. and Chen, D.-H., J. Colloid Interface Sci., 2003, vol. 259, p. 282.

    Article  CAS  Google Scholar 

  28. Wojcieszak, R., Zielinski, M., Monteverdi, S., and Bettahar, M.M., J. Colloid Interface Sci., 2006, vol. 299, p. 238.

    Article  CAS  Google Scholar 

  29. Wojcieszak, R., Zielinski, M., Monteverdi, S., and Bettahar, M.M., J. Colloid Interface Sci., 2008, vol. 317, p. 166.

    Article  CAS  Google Scholar 

  30. Kim, H.K., Lee, Y.B., Choi, E.Y., Park, H.C., and Park, S.S., Mater. Chem. Phys., 2004, vol. 86, p. 420.

    Article  CAS  Google Scholar 

  31. Wu, M.-Li., Chen, D.-H., and Huang, T.-C., J. Colloid Interface Sci., 2001, vol. 243, p. 102.

    Article  CAS  Google Scholar 

  32. Price, W.J., Analytical Atomic-Absorption Spectroscopy, London: Heyden, 1972.

    Google Scholar 

  33. Boehm, H.-P and Knozinger, H, in Catalysis Science and Technology, Anderson, J.R.. and Boudart, M., Eds., Berlin: Springer, 1983, p. 39.

    Google Scholar 

  34. Lowell, S., Shields, J.E., Thomas, M.A., and Thommes, M., Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density, Dordrecht: Kluwer, 2006.

    Google Scholar 

  35. Bensalem, A., Muller, J.C., and Bozon-Verduraz, F., J. Chem. Soc., Faraday Trans., 1992, vol. 85, p. 153.

    Article  Google Scholar 

  36. Rakai, A., Tessier, D., and Bozon-Verduraz, F., New J. Chem., 1992, vol. 16, p. 869.

    CAS  Google Scholar 

  37. Binet, C., Bardi, A., and Lavalley, J.C., J. Phys. Chem., 1994, vol. 98, p. 6392.

    Article  CAS  Google Scholar 

  38. Lietz, G., Lieske, H., Spindler, H., Hanke, W., and Völter, J., J. Catal., 1983, vol. 81, p. 17.

    Article  CAS  Google Scholar 

  39. Mason, W.R. and Gray, H.B., J. Am. Chem. Soc., 1968, vol. 90, p. 5721.

    Article  CAS  Google Scholar 

  40. Handbook of X-ray Photoelectron Spectroscopy, Moulder, J.F., Stickle, W.F., and Sobol, P.E., Eds., Eden Prairie. Minn.: Perkin-Elmer Corporation, Physical Electronics Division, 1992.

    Google Scholar 

  41. Brun, M., Berthet, A., and Bertolini, J.C., J. Electron Spectrosc. Relat. Phenom., 1999, vol. 104, p. 55.

    Article  CAS  Google Scholar 

  42. Suhonen, S., Valden, M., Pessa, M., Savimaki, A., Harkonen, M., Hietikko, M., Pursiainen, J., and Laitinen, R., Appl. Catal., 2001, vol. 207, p. 113.

    Article  CAS  Google Scholar 

  43. Slavinskaya, E.M., Boronin, A.I., Danilova, I.G., Amosov, Yu.I., Ivanova, A.S., Kuznetsov, P.A., Polukhina, I.A., Gulyaev, R.V., Stadnichenko, A.I., Koshcheev, S.V., Zaikovskii, V.I., and Noskov, A.S., Kinet. Katal., 2009, vol. 50, no. 6, p. 853 [Kinet. Catal. (Engl. Transl.), vol. 50, no. 6, p. 819].

    Article  Google Scholar 

  44. Boronin, A.I., Slavinskaya, E.M., Danilova, I.G., Gulyaev, R.V., Amosov, Yu.I., Kuznetsov, P.A., Polukhina, I.A., Koscheev, S.V., Zaikovskii, V.I., and Noskov, A.S., Catal. Today, 2009, vol. 144, p. 201.

    Article  CAS  Google Scholar 

  45. Boronin, A.I., Ivanova, A.S., Slavinskaya, E.M., Gulyaev, R.V., Danilova, I.G., Zaikovskii, V.I., and Noskov, A.S., Proc. 6th World Congr. on Oxidation Catalysis, Lille, France, 2009.

    Google Scholar 

  46. Fung, S.C., J. Catal., 1979, vol. 58, p. 454.

    Article  CAS  Google Scholar 

  47. Darby, J.B. and Myles, Jr.K.M., Metall. Trans. A, 1972, vol. 3, p. 653.

    Article  CAS  Google Scholar 

  48. Monti, D.A.M. and Baiker, A., J. Catal., 1983, vol. 83, p. 323.

    Article  CAS  Google Scholar 

  49. Jen, H.-W., Graham, G.W., Chun, W., McCabe, R.W., Cuif, J.-P., Deutsch, S.E., and Touret, O., Catal. Today, 1999, vol. 50, p. 309.

    Article  CAS  Google Scholar 

  50. Ivanova, A.S., Slavinskaya, E.M., Gulyaev, R.V., Zaikovskii, V.I., Stonkus, O.A., Danilova, I.G., Plyasova, L.M., Polukhina, I.A., and Boronin, A.I., Appl. Catal., B, 2010, vol. 97, p. 57.

    Article  CAS  Google Scholar 

  51. Bourane, A. and Bianchi, D., J. Catal., 2002, vol. 209, p. 126.

    Article  CAS  Google Scholar 

  52. Bourane, A. and Bianchi, D., J. Catal., 2003, vol. 218, p. 447.

    Article  CAS  Google Scholar 

  53. Mars, P. and van Krevelen, D.W., Chem. Eng. Sci., 1954, vol. 3, Suppl. 1, p. 41.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. M. Slavinskaya.

Additional information

Original Russian Text © E.M. Slavinskaya, R.V. Gulyaev, O.A. Stonkus, A.V. Zadesenets, P.E. Plyusnin, Yu.V. Shubin, S.V. Korenev, A.S. Ivanova, V.I. Zaikovskii, I.G. Danilova, A.I. Boronin, 2011, published in Kinetika i Kataliz, 2011, Vol. 52, No. 2, pp. 291–304.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Slavinskaya, E.M., Gulyaev, R.V., Stonkus, O.A. et al. Low-temperature oxidation of carbon monoxide on Pd(Pt)/CeO2 catalysts prepared from complex salts. Kinet Catal 52, 282–295 (2011). https://doi.org/10.1134/S0023158411020182

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158411020182

Keywords

Navigation