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Synergetic effect in PdAu/CeO2 catalysts for the low-temperature oxidation of CO

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Abstract

Gold-palladium catalysts supported on cerium oxide were synthesized with the double complex salts. X-ray photoelectron spectroscopy (XPS) and other physicochemical methods (TEM, TPR) were used to demonstrate that synthesis of highly active palladium catalysts requires the oxidative treatment stimulating the formation of a catalytically active surface solid solution Pd x Ce1−x O2, which is responsible for the lowtemperature activity (LTA) in the reaction CO + O2. In the case of gold catalysts, active sites for the lowtemperature oxidation of CO are represented by gold nanoparticles and its cationic interface species. Simultaneous deposition of two metals increases the catalyst LTA due to interaction of both gold and palladium with the support surface to form a Pd1−x CexO2 solid solution and cationic interface species of palladium and gold on the boundary of Pd-Au alloy particles anchored on the solid solution surface.

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Authors and Affiliations

  1. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    R. V. Gulyaev, L. S. Kibis, O. A. Stonkus, A. S. Ivanova, E. M. Slavinskaya, V. I. Zaikovskii, I. G. Danilova, A. I. Boronin & V. A. Sobyanin

  2. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Zadesenets, P. E. Plyusnin, Yu. V. Shubin & S. V. Korenev

  3. Novosibirsk State University, Novosibirsk, Russia

    P. E. Plyusnin, Yu. V. Shubin, S. V. Korenev, A. I. Boronin & V. A. Sobyanin

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  1. R. V. Gulyaev
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  2. L. S. Kibis
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  3. O. A. Stonkus
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  4. A. V. Zadesenets
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  5. P. E. Plyusnin
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  7. S. V. Korenev
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  8. A. S. Ivanova
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  9. E. M. Slavinskaya
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  10. V. I. Zaikovskii
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  11. I. G. Danilova
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  12. A. I. Boronin
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  13. V. A. Sobyanin
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Corresponding author

Correspondence to A. I. Boronin.

Additional information

Original Russian Text Copyright © 2011 by R. V. Gulyaev, L. S. Kibis, O. A. Stonkus, A. V. Zadesenets, P. E. Plyusnin, Yu. V. Shubin, S. V. Korenev, A. S. Ivanova, E. M. Slavinskaya, V. I. Zaikovskii, I. G. Danilova, A. I. Boronin, and V. A. Sobyanin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 52, Supplement, pp. S126–S140, 2011.

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Gulyaev, R.V., Kibis, L.S., Stonkus, O.A. et al. Synergetic effect in PdAu/CeO2 catalysts for the low-temperature oxidation of CO. J Struct Chem 52 (Suppl 1), 123–136 (2011). https://doi.org/10.1134/S0022476611070171

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  • DOI: https://doi.org/10.1134/S0022476611070171

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