Skip to main content
SpringerLink
Log in

Catalytic activity of NASICON-type phosphates for ethanol dehydration and dehydrogenation

  • Published:
Inorganic Materials Aims and scope

Abstract

A1 ± x Zr2 − x M x (PO4)3 (A = H3O+, Li+; M = In, Nb; x = 0, 0.1, 0.2) NASICON-type materials have been prepared and characterized by X-ray diffraction, specific surface measurements (capillary condensation of nitrogen), and impedance spectroscopy. We have assessed their catalytic performance for ethanol dehydration and dehydrogenation. The results demonstrate that, when prepared with a large specific surface area, these materials are active catalysts for ethanol conversion to hydrocarbons.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Anantharamulu, N., Koteswara Rao, K., Rambabu, G., et al., A Wide-Ranging Review on Nasicon Type Materials, J. Mater. Sci., 2011, vol. 46, pp. 2821–2837.

    Article  CAS  Google Scholar 

  2. Agaskar, P.A., Grasselli, R.K., Buttrey, D.J., and White, B., Stud. Surf. Sci. Catal., 1997, vol. 110, pp. 219–226.

    Article  CAS  Google Scholar 

  3. Serghini, A., Brochu, R., Ziyad, M., and Vedrine, J.C., Behaviour of Copper-Zirconium Nasicon-Type Phosphate, CuIZr2(PO4)3, in the Decomposition of Isopropyl Alcohol, J. Chem. Soc., Faraday Trans., 1991, vol. 87, no. 15, pp. 2487–2491.

    Article  CAS  Google Scholar 

  4. Serghini, A., Brochu, R., Ziyad, M., and Vedrine, J.C., Synthesis, Characterization and Catalytic Behaviour of Cu0.5M2(PO4)3 (M = Zr, Sn, Ti), J. Alloys Compd., 1992, vol. 188, pp. 60–64.

    Article  CAS  Google Scholar 

  5. Brik, Y., Kacimi, M., Bozon-Verduraz, F., and Ziyad, M., Characterization of Active Sites on AgHf2(PO4)3 in Butan-2-ol Conversion, Microporous Mesoporous Mater., 2001, vol. 43, pp. 103–112.

    Article  CAS  Google Scholar 

  6. Sadykov, V.A., Pavlova, S.N., Zabolotnaya, G.V., et al., Mechanochemical Synthesis of Highly Dispersed Framework Lithium-Zirconium Phosphates, Khim. Interesakh Ustoich. Razvit., 2002, no. 10, pp. 227–235.

  7. Sukhanov, M.V., Ermilova, M.M., Orekhova, N.V., et al., Catalytic Properties of Zirconium Phosphate and Double Phosphates of Zirconium and Alkali Metals with a NaZr2(PO4)3 Structure, Russ. J. Appl. Chem., 2006, vol. 79, no. 4, pp. 614–618.

    Article  CAS  Google Scholar 

  8. Pet’kov, V.I., Sukhanov, M.V., Ermilova, M.M., et al., Development and Synthesis of Bulk and Membrane Catalysts Based on Framework Phosphates and Molybdates, Russ. J. Appl. Chem., 2010, vol. 83, no. 10, pp. 1731–1741.

    Article  Google Scholar 

  9. Subramanian, M.A., Subramanian, R., and Clearfield, A., Lithium Ion Conductors in the System AB(IV)2(PO4)3 (B = Ti, Zr, and Hf), Solid State Ionics, 1986, vols. 18–19, pp. 562–569.

    Article  Google Scholar 

  10. Aono, H., Sugimoto, E., Sadaoka, Y., et al., Ionic Conductivity of the Lithium Titanium Phosphate (Li1 + x Ti2 − x (PO4)3, M = Al, Se, Y, and La) Systems, J. Electrochem. Soc., 1989, vol. 136, no. 2, pp. 590–592.

    Article  CAS  Google Scholar 

  11. Hamdoune, S., Tran Qui, D., and Schouler, E.J.L., Ionic Conductivity and Crystal Structure of Li1 + x Ti2 − x InxP3O12, Solid State Ionics, 1986, vols. 18–19, pp. 587–591.

    Article  Google Scholar 

  12. Pinus, I.Yu., Arkhangel’skii, I.V., Zhuravlev, N.A., and Yaroslavtsev, A.B., Cation Mobility in Modified Li1 + x Ti2 − x Gax(PO4)3 Lithium Titanium NASICON Phosphates, Russ. J. Inorg. Chem., 2009, vol. 54, no. 8, pp. 1173–1176.

    Article  Google Scholar 

  13. Kakihana, M. and Yoshimura, M., Synthesis and Characterization of Complex Multicomponent Oxides Prepared by Polymer Complex Method, Bull. Chem. Soc. Jpn., 1999, vol. 72, pp. 1427–1443.

    Article  CAS  Google Scholar 

  14. Stenina, I.A., Kislitsyn, M.N., Pinus, I.Yu., et al., Phase Transformations and Cation Mobility in NASICON Lithium Zirconium Double Phosphates (Li1 ± x Zr2 − x Mx(PO4)3 (M = Sc, Y, In, Nb, Ta), Russ. J. Inorg. Chem., 2005, vol. 50, no. 6, pp. 906–911.

    Google Scholar 

  15. Svitan’ko, A.I., Novikova, S.A., Safronov, D.V., and Yaroslavtsev, A.B., Cation Mobility in Li1+x Ti2 − x Crx(PO4)3 NASICON-Type Phosphates, Inorg. Mater., 2011, vol. 47, no. 12, pp. 1391–1395.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. B. Il’in, S. A. Novikova & A. B. Yaroslavtsev

  2. Lobachevsky State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia

    M. V. Sukhanov

  3. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    M. M. Ermilova & N. V. Orekhova

Authors
  1. A. B. Il’in
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. A. Novikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. V. Sukhanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. M. Ermilova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. V. Orekhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. B. Yaroslavtsev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. B. Yaroslavtsev.

Additional information

Original Russian Text © A.B. Il’in, S.A. Novikova, M.V. Sukhanov, M.M. Ermilova, N.V. Orekhova, A.B. Yaroslavtsev, 2012, published in Neorganicheskie Materialy, 2012, Vol. 48, No. 4, pp. 466–471.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Il’in, A.B., Novikova, S.A., Sukhanov, M.V. et al. Catalytic activity of NASICON-type phosphates for ethanol dehydration and dehydrogenation. Inorg Mater 48, 397–401 (2012). https://doi.org/10.1134/S002016851204005X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S002016851204005X

Keywords

Search

Navigation